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Chin. Phys. B, 2012, Vol. 21(4): 045101    DOI: 10.1088/1674-1056/21/4/045101
PHYSICS OF GASES, PLASMAS, AND ELECTRIC DISCHARGES Prev   Next  

Transport properties of a binary mixture of CO2–N2 from the pair potential energy functions based on a semi-empirical inversion method

Song Bo(宋渤), Wang Xiao-Po(王晓坡), Yang Fu-Xin(杨富鑫), and Liu Zhi-Gang(刘志刚)
Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education, Xi'an Jiaotong University, Xi'an 710049, China
Abstract  The potential energy surface of a CO2-N2 mixture is determined by using an inversion method, together with a new collision integral correlation [J. Phys. Chem. Ref. Data 19 1179 (1990)]. With the new invert potential, the transport properties of CO2-N2 mixture are presented in a temperature range from 273.15 K to 3273.15 K at low density by employing the Chapman-Enskog scheme and the Wang Chang-Uhlenbeck-de Boer theory, consisting of a viscosity coefficient, a thermal conductivity coefficient, a binary diffusion coefficient, and a thermal diffusion factor. The accuracy of the predicted results is estimated to be 2% for viscosity, 5% for thermal conductivity, and 10% for binary diffusion coefficient.
Keywords:  inversion method      potential energy surface      CO2-N2 mixture      transport property  
Received:  07 July 2011      Revised:  26 July 2011      Accepted manuscript online: 
PACS:  51.10.+y (Kinetic and transport theory of gases)  
  52.25.Fi (Transport properties)  
  31.50.-x (Potential energy surfaces)  
  34.20.-b (Interatomic and intermolecular potentials and forces, potential energy surfaces for collisions)  
Fund: Project supported by the National Natural Science Foundation of China (Grant No. 51006083), the China Postdoctoral Science Foundation (Grant No. 20110491658), and the Fundamental Research Funds for the Central Universities.
Corresponding Authors:  Wang Xiao-Po,wangxp@mail.xjtu.edu.cn     E-mail:  wangxp@mail.xjtu.edu.cn

Cite this article: 

Song Bo(宋渤), Wang Xiao-Po(王晓坡), Yang Fu-Xin(杨富鑫), and Liu Zhi-Gang(刘志刚) Transport properties of a binary mixture of CO2–N2 from the pair potential energy functions based on a semi-empirical inversion method 2012 Chin. Phys. B 21 045101

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