| CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES |
Prev
Next
|
|
|
Ultrafast proton transfer dynamics of 2-(2'-hydroxyphenyl)benzoxazole dye in different solvents |
| Simei Sun(孙四梅)1,†, Song Zhang(张嵩)2,‡, Jiao Song(宋娇)1, Xiaoshan Guo(郭小珊)1, Chao Jiang(江超)1, Jingyu Sun(孙静俞)3, and Saiyu Wang(王赛玉)1 |
1 Huangshi Key Laboratory of Photoelectric Technology and Materials, College of Physics and Electronic Science, Hubei Normal University, Huangshi 435002, China;
2 State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan 430071, China;
3 Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, College of Chemistry and Chemical Engineering, Hubei Normal University, Huangshi 435002, China |
|
|
|
|
Abstract The excited-state intramolecular proton transfer of 2-(2'-hydroxyphenyl)benzoxazole dye in different solvents is investigated using ultrafast femtosecond transient absorption spectroscopy combined with quantum chemical calculations. Conformational conversion from the syn-enol configuration to the keto configuration is proposed as the mechanism of excited-state intramolecular proton transfer. The duration of excited-state intramolecular proton transfer is measured to range from 50 fs to 200 fs in different solvents. This time is strongly dependent on the calculated energy gap between the N-S0 and T-S1 structures in the S1 state. Along the proton transfer reaction coordinate, the vibrational relaxation process on the S1 state potential surface is observed. The duration of the vibrational relaxation process is determined to be from 8.7 ps to 35 ps dependent on the excess vibrational energy.
|
Received: 29 July 2021
Revised: 15 October 2021
Accepted manuscript online: 06 November 2021
|
|
PACS:
|
78.47.J-
|
(Ultrafast spectroscopy (<1 psec))
|
| |
82.53.Ps
|
(Femtosecond probing of biological molecules)
|
| |
82.53.Uv
|
(Femtosecond probes of molecules in liquids)
|
| |
87.15.ag
|
(Quantum calculations)
|
|
| Fund: Project supported by the Natural Science Foundation of Hubei Province, China (Grant No. 2020CFB468), the Guiding Project of Scientific Research Plan of Department of Education of Hubei Province, China (Grant No. B2020136), and the National Key Research and Development Program of China (Grant No. 2019YFA0307700), and the National Natural Science Foundation of China (Grant Nos. 11974381, 11674355, and 21507027). |
Corresponding Authors:
Simei Sun, Song Zhang
E-mail: simeisun@hbnu.edu.cn;zhangsong@wipm.ac.cn
|
Cite this article:
Simei Sun(孙四梅), Song Zhang(张嵩), Jiao Song(宋娇), Xiaoshan Guo(郭小珊), Chao Jiang(江超), Jingyu Sun(孙静俞), and Saiyu Wang(王赛玉) Ultrafast proton transfer dynamics of 2-(2'-hydroxyphenyl)benzoxazole dye in different solvents 2022 Chin. Phys. B 31 027803
|
[1] Formosinho S J and Arnaut L G 1993 J. Photoch. Photobio. A 75 21
[2] Chen W, Wright B D and Pang Y 2012 Chem. Commun. 48 3824
[3] Patil V S, Padalkar V S, Tathe A B and Sekar N 2013 Dyes Pigm. 98 507
[4] Kim S, Seo J, Jung H K, Kim J J and Park S Y 2005 Adv. Mater. 17 2077
[5] Park S, Kim S, Seo J and Park S Y 2008 Macromol. Res. 16 385
[6] Park S, Seo J, Kim S H and Park S Y 2008 Adv. Funct. Mater. 18 726
[7] Wu J, Liu W, Ge J, Zhang H and Wang P 2011 Chem. Soc. Rev. 40 3483
[8] Zhao J, Ji S, Chen Y, Guo H and Yang P 2012 Phys. Chem. Chem. Phys. 14 8803
[9] Rodembusch F S, Leusin F P, da Costa Medina L F, Brandelli A and Stefani V 2005 Photoch. Photobio. Sci. 4 254
[10] Abou-Zied O K 2012 Phys. Chem. Chem. Phys. 14 2832
[11] Sastre R and Costela A 1995 Adv. Mater. 7 198
[12] Costela A, Garcia-Moreno I, Figuera J M, Amat-Guerri F and Sastre R 1996 Appl. Phys. Lett. 68 593
[13] Fluegge A P, Waiblinger F, Stein M, Keck J, Kramer H E A, Fischer P, Wood M G, DeBellis A D, Ravichandran R and Leppard D 2007 J. Phys. Chem. A 111 9733
[14] Lim S J, Seo J and Park S Y 2006 J. Am. Chem. Soc. 128 14542
[15] Mutai T, Tomoda H, Ohkawa T, Yabe Y and Araki K 2008 Angew. Chem. Int. Ed. Engl. 47 9522
[16] You Y, Seo J, Kim S H, Kim K S, Ahn T K, Kim D and Park S Y 2008 Inorg. Chem. 47 1476
[17] Park S, Kwon J E, Kim S H, Seo J, Chung K, Park S Y, Jang D J, Medina B M, Gierschner J and Park S Y 2009 J. Am. Chem. Soc. 131 14043
[18] Zhao J, Chen J, Liu J and Hoffmann M R 2015 Phys. Chem. Chem. Phys. 17 11990
[19] Zhao J, Dong H and Zheng Y 2018 J. Lumin. 195 228
[20] štacko P, Kistemaker J C M, van Leeuwen T, Chang M C, Otten E and Feringa B L 2017 Science 356 964
[21] Ríos Vázquez S, Ríos Rodríguez M C, Mosquera M and Rodríguez-Prieto F 2007 J. Phys. Chem. A 111 1814
[22] Duarte L, Germino J C, Braga C A, Barboza C A, Atvars T D Z, Santos F D S and Rodembusch F S 2018 Photoch. Photobio. Sci. 17 231
[23] Liu Y H, Wang S M, Zhu C and Lin S H 2017 New J. Chem. 41 8437
[24] Yang D, Zhao J, Yang G, Song N, Zheng R and Wang Y 2017 J. Mol. Liq. 241 1003
[25] Zhao J, Dong H and Zheng Y 2018 J. Phys. Chem. A 122 1200
[26] Yang D, Zhao J, Yang G, Song N, Zheng R and Wang Y 2017 Org. Chem. Front. 4 1935
[27] Krishnamurthy M and Dogra S K 1986 J. Photochem. 32 235
[28] Chen W H and Pang Y 2010 Tetrahedron Lett. 51 1914
[29] Barbatti M, Aquino A J, Lischka H, Schriever C, Lochbrunner S and Riedle E 2009 Phys. Chem. Chem. Phys. 11 1406
[30] Kungwan N, Plasser F, Aquino A J, Barbatti M, Wolschann P and Lischka H 2012 Phys. Chem. Chem. Phys. 14 9016
[31] Walter J L and Freiser H 1953 Anal. Chem. 25 127
[32] Roberts E L, Dey J and Warner I M 1997 J. Phys. Chem. A 101 5296
[33] Ohshima A, Momotake A, Nagahata R and Arai T 2005 J. Phys. Chem. A 109 9731
[34] Abou-Zied O K 2007 Chem. Phys. 337 1
[35] Daengngern R and Kungwan N 2014 Chem. Phys. Lett. 609 147
[36] Ormson S M and Brown R G 1994 Prog. React. Kinet. 19 45
[37] Ríos Vázquez S, Ríos Rodríguez M C, Mosquera M and Rodríguez-Prieto F 2008 J. Phys. Chem. A 112 376
[38] Abou-Zied O K, Jimenez R, Thompson E H Z, Millar D P and Romesberg F E 2002 J. Phys. Chem. A 106 3665
[39] Zhong D, Douhal A and Zewail A H 2000 Proc. Natl. Acad. Sci. USA 97 14056
[40] Taki M, Wolford J L and O'Halloran T V 2004 J. Am. Chem. Soc. 126 712
[41] Padalkar V S, Ramasami P and Sekar N 2014 J. Lumin. 146 527
[42] Ogawa A K, Abou-Zied O K, Tsui V, Jimenez R, Case D A and Romesberg F E 2000 J. Am. Chem. Soc. 122 9917
[43] Zhang G, Wang H, Yu Y, Xiong F, Tang G and Chen W 2003 Appl. Phys. B 76 677
[44] Alarcos N, Gutierrez M, Liras M, Sanchez F, Moreno M and Douhal A 2015 Phys. Chem. Chem. Phys. 17 14569
[45] Alarcos N, Gutierrez M, Liras M, Sanchez F and Douhal A 2015 Phys. Chem. Chem. Phys. 17 16257
[46] Lu X, Zhai Y, Song P and Zhang M 2018 Struct. Chem. 29 1655
[47] Kim C H, Park J, Seo J, Park S Y and Joo T 2010 J. Phys. Chem. A 114 5618
[48] Azarias C, Budzak S, Laurent A D, Ulrich G and Jacquemin D 2016 Chem. Sci. 7 3763
[49] Alarcos N, Gutierrez M, Liras M, Sanchez F and Douhal A 2015 Photoch. Photobio. Sci. 14 1306
[50] Wang H, Zhang H, Abou-Zied O K, Yu C, Romesberg F E and Glasbeek M 2003 Chem. Phys. Lett. 367 599
[51] Corbellini V A, Scroferneker M L, Carissimi M, Rodembusch F S and Stefani V 2010 J. Photoch. Photobio. B 99 126
[52] Rodembusch F S, Leusin F P, Campo L F and Stefani V 2007 J. Lumin. 126 728
[53] Zhang S, Sun S, Zhou M, Wang L and Zhang B 2017 Sci. Rep. 7 43419
[54] Sun S, Qin C, Liu H and Jiang C 2020 Spectrochim. Acta A 234 118200
[55] Frisch M J, Trucks G W, Schlegel H B, et al. 2016 Gaussian 16, Revision A.03, Gaussian, Inc., Wallingford CT.
[56] Tian L 2019 Molclus program, Version 1.8.9 (accessed 2019-Sep-28) |
| No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
Altmetric
|
|
blogs
Facebook pages
Wikipedia page
Google+ users
|
Online attention
Altmetric calculates a score based on the online attention an article receives. Each coloured thread in the circle represents a different type of online attention. The number in the centre is the Altmetric score. Social media and mainstream news media are the main sources that calculate the score. Reference managers such as Mendeley are also tracked but do not contribute to the score. Older articles often score higher because they have had more time to get noticed. To account for this, Altmetric has included the context data for other articles of a similar age.
View more on Altmetrics
|
|
|
