Substitution priority of Eu2+ in multi-cation compound Sr0.8Ca0.2Al2Si2O8 and energy transfer

doi:10.1088/1674-1056/27/1/017802

Abstract A blue phosphor was obtained by doping Eu²⁺ into a multi-cation host Sr_0.8Ca_0.2Al₂Si₂O₈ through high temperature solid state reaction. The emission spectra show a continuous red-shift behavior from 413 nm to 435 nm with Eu²⁺ concentration increasing. The substitution priority of Eu²⁺ in Sr_0.8Ca_0.2Al₂Si₂O₈ was investigated via x-ray diffraction (XRD) and temperature properties in detail:the Ca²⁺ ions are preferentially substituted by Eu²⁺at lower doping, and with the Eu²⁺ concentration increasing, the probability of substitution for Sr²⁺ is greater than that of replacing Ca²⁺. Accordingly, we propose the underlying method of thermal property to determine the substitution of Eu²⁺ in the multi-cation hosts. Moreover, the abnormal increase of emission intensity with increasing temperature was studied by the thermoluminescence spectra. The energy transfer mechanism between the Eu²⁺ ions occupying different cation sites was studied by the lifetime decay curves. A series of warm white light emitting diodes were successfully fabricated using the blue phosphors Sr_0.8Ca_0.2Al₂Si₂O₈:Eu²⁺ with commercial red phosphor (Ca Sr)SiAlN₃:Eu²⁺ and green phosphor (Y Lu)₃Al₅O₁₂:Ce³⁺, and the luminescent efficiency can reach 45 lm/W.

Keywords: luminescence phosphors energy transfer substitution priority

Received: 24 July 2017
Revised: 09 October 2017
Accepted manuscript online:

PACS:	78.55.-m	(Photoluminescence, properties and materials)
	33.50.Dq	(Fluorescence and phosphorescence spectra)
	33.20.Kf	(Visible spectra)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51672066 and 50902042), Funds for Distinguished Young Scientists of Hebei Province, China (Grant No. A2015201129), and Personnel Training Project of Hebei Province, China (Grant No. A2016002013).

Corresponding Authors: Zhi-Jun Wang, Pan-Lai Li
E-mail: wangzj1998@126.com;li_panlai@126.com

Cite this article:

Zhi-Ping Yang(杨志平), Zhen-Ling Li(李振玲), Zhi-Jun Wang(王志军), Pan-Lai Li(李盼来), Miao-Miao Tian(田苗苗), Jin-Ge Cheng(程金阁), Chao Wang(王超) Substitution priority of Eu²⁺ in multi-cation compound Sr_0.8Ca_0.2Al₂Si₂O₈ and energy transfer 2018 Chin. Phys. B 27 017802

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Substitution priority of Eu2+ in multi-cation compound Sr0.8Ca0.2Al2Si2O8 and energy transfer

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Substitution priority of Eu²⁺ in multi-cation compound Sr_0.8Ca_0.2Al₂Si₂O₈ and energy transfer