Effect of metal fluorides on chromium ions doped bismuth borate glasses for optical applications

doi:10.1088/1674-1056/28/3/038101

Abstract

Fluoride based glasses with composition CaF₂-ZnF₂-Bi₂O₃-B₂O₃ doped with chromium ions have been investigated using physical, optical, electron paramagnetic resonance (EPR), Fourier-transform infrared spectroscopy (FTIR), and Raman studies. The amorphous nature of samples was confirmed from x-ray diffraction spectra. The density is evaluated from the Archimedes principle and the values of optical band gap and Urbach energy values were evaluated from the optical absorption spectra. Thus, molar volume, refractive index, etc., were also evaluated. The observed decrease in density and the optical band gap with CaF₂ is explained using the crystalline density of metal fluorides and the ionicity of fluorine ions, respectively. The three peaks near 450 nm, 606 nm, and 720 nm, which are shown in the absorption spectra, are accredited to ⁴A_2g→⁴T_1g, ⁴A_2g→→⁴T_2g, ⁴A_2g→²E transitions, respectively. Resonance signals at g≈ 4.82 and g≈ 1.99 were observed in EPR spectra which are assigned. FTIR and Raman analysis were carried out to examine the impact of metal fluorides on the structure of bismuth borate glasses.

Keywords: glasses x-ray diffraction electron paramagnetic resonance Fourier-transform infrared spectroscopy (FTIR) Raman spectra

Received: 13 September 2018
Revised: 29 November 2018
Accepted manuscript online:

PACS:	81.05.Kf	(Glasses (including metallic glasses))
	76.30.-v	(Electron paramagnetic resonance and relaxation)
	78.30.-j	(Infrared and Raman spectra)

Corresponding Authors: K Chandra Sekhar
E-mail: chandu9417@gmail.com

Cite this article:

L Haritha, K Chandra Sekhar, R Nagaraju, G Ramadevudu, Vasanth G Sathe, Md. Shareefuddin Effect of metal fluorides on chromium ions doped bismuth borate glasses for optical applications 2019 Chin. Phys. B 28 038101

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Effect of metal fluorides on chromium ions doped bismuth borate glasses for optical applications

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