Synergistic influences of titanium, boron, and oxygen on large-size single-crystal diamond growth at high pressure and high temperature

doi:10.1088/1674-1056/ac4650

Abstract The synergistic influences of boron, oxygen, and titanium on growing large single-crystal diamonds are studied using different concentrations of B₂O₃ in a solvent-carbon system under 5.5 GPa-5.7 GPa and 1300 ℃-1500 ℃. It is found that the boron atoms are difficult to enter into the crystal when boron and oxygen impurities are doped using B₂O₃ without the addition of Ti atoms. However, high boron content is achieved in the doped diamonds that were synthesized with the addition of Ti. Additionally, boron-oxygen complexes are found on the surface of the crystal, and oxygen-related impurities appear in the crystal interior when Ti atoms are added into the FeNi-C system. The results show that the introduction of Ti atoms into the synthesis cavity can effectively control the number of boron atoms and the number of oxygen atoms in the crystal. This has important scientific significance not only for understanding the synergistic influence of boron, oxygen, and titanium atoms on the growth of diamond in the earth, but also for preparing the high-concentration boron or oxygen containing semiconductor diamond technologies.

Keywords: high pressure and high temperature (HPHT) diamond B₂O₃ Ti

Received: 29 November 2021
Revised: 22 December 2021
Accepted manuscript online: 24 December 2021

PACS:	81.05.ug	(Diamond)
	61.50.Ah	(Theory of crystal structure, crystal symmetry; calculations and modeling)
	81.10.Fq	(Growth from melts; zone melting and refining)
	81.05.uf	(Graphite)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 11804305, 12004341, 11704340, and 12004342), the Key Research Project of Higher Education Institution of Henan Province, China (Grant No. 19A140006), the Scientific and Technological Project in Henan Province, China (Grant No. 202102210198), the Natural Science Foundation of Chongqing, China (Grant No. cstc2019jcyjmsxmX0391), and the Science and Technology Research Program of Chongqing Municipal Education Commission, China (Grant No. KJQN201901405).

Corresponding Authors: Chao Fang, Liang-Chao Chen
E-mail: fangchao1989@zzu.edu.cn;chenlc@zzu.edu.cn

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Guang-Tong Zhou(周广通), Yu-Hu Mu(穆玉虎), Yuan-Wen Song(宋元文), Zhuang-Fei Zhang(张壮飞), Yue-Wen Zhang(张跃文), Wei-Xia Shen(沈维霞), Qian-Qian Wang(王倩倩), Biao Wan(万彪), Chao Fang(房超), Liang-Chao Chen(陈良超), Ya-Dong Li(李亚东), and Xiao-Peng Jia(贾晓鹏) Synergistic influences of titanium, boron, and oxygen on large-size single-crystal diamond growth at high pressure and high temperature 2022 Chin. Phys. B 31 068103

[1] Wilks J and Wilks E 1991 Butterworth-Heinemann
[2] Vorobiev Y V, Zakharchenko R V, Semenova G N, et al. 1996 Semiconducting & Semi-insulating Materials Conference, IEEE
[3] Poferl D J, Gardner N C and Angus J C 1973 J. Appl. Phys. 44 1428
[4] Li S S, Ma H A, Li X L, et al. 2011 Chin. Phys. B 20 028103
[5] Xiao H Y, Liu L N, Qin Y K, Zhang D M, Zhang Y S, Sui Y M, et al. 2016 Acta Phys. Sin. 65 070701 (in Chinese)
[6] Fang C, Zhang Y, Shen W, Sun S, Zhang Z, et al. 2017 CrystEngComm 19 5727
[7] Liu X, Chen X, Singh D J, Stern R A, Wu J, et al. 2019 Proceedings of the National Academy of Sciences 116 7703
[8] Prikhodko D, Pavlov S, Tarelkin S, Bormashov V, Kuznetsov M, et al. 2020 Phys. Rev. B 102 155204
[9] Wang Y and Kanda H 1998 Diamond and Related Mater. 7 57
[10] Strong H and Chrenko R 1971 J. Phys. Chem. 75 1838
[11] Wentorf R Jr 1971 J. Phys. Chem. 75 1833
[12] Strong H and Wentorf R 1972 Naturwissenschaften 59 1
[13] Kanda H 2000 Brazilian Journal of Physics 30 482
[14] Collins A and Woods G 1982 Philosophical Magazine B 46 77
[15] Woods G, Van Wyk J and Collins A 1990 Philosophical Magazine B 62 589
[16] Kaiser W and Bond W 1959 Phys. Rev. 115 857
[17] Huang G F, Jia X P, Li Y, Hu M H, Li Z C, Yan B M and Ma H A 2011 Chin. Phys. B 20 078103
[18] Sumiya H and Satoh S 1996 Diamond and Related Materials 5 1359
[19] Chevallier J, Lusson A, Ballutaud D, Theys B, Jomard F, et al. 2001 Diamond and related materials 10 399
[20] Chepurov A, Yelisseyev A, Zhimulev E, Sonin V, Fedorov I and Chepurov A 2008 Inorganic Materials 44 377
[21] Inushima T, Mamin R F and Shiomi H 2009 Phys. Rev. B 79 045210
[22] D'Haenens-Johansson U F, Katrusha A, Johnson P and Wang W 2015 Gems & Gemology 51 260
[23] Chrenko R 1973 Phys. Rev. B 7 4560
[24] Chen L, Miao X, He X, Guo L, Fang S, et al. 2018 J. Cryst. Growth 498 67
[25] Chepugov A, Ivakhnenko S and Garashchenko V 2014 Physica Status Solidi (c) 11 1431
[26] Mortet V, Pernot J, Jomard F, Soltani A, Remes Z, et al. 2015 Diamond and Related Materials 53 29
[27] Wagner J, Wild C and Koidl P 1991 Appl. Phys. Lett. 59 779
[28] Etou Y, Tai T, Sugiyama T and Sugino T 2002 Diamond and Related Materials 11 985
[29] Lu XH, Liu W, Ouyang J and Tian Y 2014 Appl. Surf. Sci. 311 749
[30] Petit T, Pflüger M, Tolksdorf D, Xiao J and Aziz E F 2015 Nanoscale 7 2987
[31] Benndorf C, Hadenfeldt S, Luithardt W and Zhukov A 1996 Diamond and Related M 5 784
[32] Vetrone J, Fan J and Trenary M 1994 Surf. Sci. 314 315
[33] Jung C H, Lee M J and Kim C J 2004 Mater. Lett. 58 609
[34] Baba K and Hatada R 2001 Surface and Coatings Technology 136 192
[35] Bhaumik S, Divakar C, Singh A K and Upadhyaya G 2000 Mater. Sci. Eng. A 279 275

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Synergistic influences of titanium, boron, and oxygen on large-size single-crystal diamond growth at high pressure and high temperature

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