Effects of FeNi-phosphorus-carbon system on crystal growth of diamond under high pressure and high temperature conditions

doi:10.1088/1674-1056/24/3/038101

Abstract This paper reports the crystal growth of diamond from the FeNi-Carbon system with additive phosphorus at high pressures and high temperatures of 5.4-5.8 GPa and 1280-1360℃. Attributed to the presence of additive phosphorus, the pressure and temperature condition, morphology, and color of diamond crystals change obviously. The pressure and temperature condition of diamond growth increases evidently with the increase of additive phosphorus content and results in the moving up of the V-shape region. The surfaces of the diamonds also become coarse as the additive phosphorus added in the growth system. Raman spectra indicate that diamonds grown from the FeNi-phosphorus-carbon system have more crystal defects and impurities. This work provides a new way to enrich the doping of diamond and improve the experimental exploration for future material applications.

Keywords: diamond high pressure and high temperature additive phosphorus

Received: 06 July 2014
Revised: 28 September 2014
Accepted manuscript online:

PACS:	81.05.ug	(Diamond)
	81.10.-h	(Methods of crystal growth; physics and chemistry of crystal growth, crystal morphology, and orientation)
	61.72.-y	(Defects and impurities in crystals; microstructure)

Fund: Project supported by the Doctoral Fund of Henan Polytechnic University, China (Grant Nos. B2013-013 and B2013-044) and the Research Projects of Science and Technology of the Education Department of Henan Province, China (Grant Nos. 14B430026 and 12A430010).

Corresponding Authors: Hu Mei-Hua
E-mail: humh@hpu.edu.cn

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Hu Mei-Hua (胡美华), Bi Ning (毕宁), Li Shang-Sheng (李尚升), Su Tai-Chao (宿太超), Zhou Ai-Guo (周爱国), Hu Qiang (胡强), Jia Xiao-Peng (贾晓鹏), Ma Hong-An (马红安) Effects of FeNi-phosphorus-carbon system on crystal growth of diamond under high pressure and high temperature conditions 2015 Chin. Phys. B 24 038101

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Effects of FeNi-phosphorus-carbon system on crystal growth of diamond under high pressure and high temperature conditions

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