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Chin. Phys. B, 2024, Vol. 33(6): 066801    DOI: 10.1088/1674-1056/ad39d5
CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES Prev   Next  

Influences of divalent ion substitution on the magnetic and dielectric properties of W-type barium ferrite

Shiyue He(何诗悦)1,2,3, Ruoshui Liu(刘若水)3, Xujie Liu(刘煦婕)3, Xianping Ye(叶先平)3, Lichen Wang(王利晨)3,†, and Baogen Shen(沈保根)1,2,3,4,‡
1 School of Rare Earths, University of Science and Technology of China, Hefei 230026, China;
2 Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341119, China;
3 Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China;
4 Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
Abstract  Saturation magnetization, magneto-crystalline anisotropy field, and dielectric properties are closely related to microwave devices applied at different frequencies. For regulating the magnetic and dielectric properties of W-type barium ferrites, single-phase Ba$Me_{2}$Fe$_{16}$O$_{27}$ ($Me= {\rm Fe}$, Mn, Zn, Ni, Co) with different \textit{Me} ions were synthesized by the high-temperature solid-state method. The saturation magnetization ($M_{\rm s}$) range from 47.77emu/g to 95.34emu/g and the magnetic anisotropy field ($H_{\rm a}$) range from 10700.60Oe (1Oe=79.5775A$\cdot$m$^{-1}$) to 13739.57Oe, depending on the type of cation substitution in the hexagonal lattice. The dielectric permittivity and dielectric loss decrease with increasing frequency of the AC electric field in the low-frequency region, while they almost remain constant in the high-frequency region. The characteristics of easy regulation and preparation make it a potential candidate for use in microwave device applications.
Keywords:  W-type hexaferrite      Raman spectra      magnetic properties      dielectric properties  
Received:  17 February 2024      Revised:  03 April 2024      Accepted manuscript online:  03 April 2024
PACS:  68.55.Ln (Defects and impurities: doping, implantation, distribution, concentration, etc.)  
  75.30.Gw (Magnetic anisotropy)  
  75.47.Lx (Magnetic oxides)  
  87.64.kp (Raman)  
Fund: Project supported by the National Natural Science Foundation of China (Grant No. 52088101), the Kunpeng Plan of Zhejiang Province, and Ningbo Top Talent Program.
Corresponding Authors:  Lichen Wang, Baogen Shen     E-mail:  wanglichen@nimte.ac.cn;shenbaogen@nimte.ac.cn

Cite this article: 

Shiyue He(何诗悦), Ruoshui Liu(刘若水), Xujie Liu(刘煦婕), Xianping Ye(叶先平), Lichen Wang(王利晨), and Baogen Shen(沈保根) Influences of divalent ion substitution on the magnetic and dielectric properties of W-type barium ferrite 2024 Chin. Phys. B 33 066801

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