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Synthesis and nitrogen content regulation of diamond in a high-pressure hydrogen-rich environment |
| Guofeng Huang(黄国锋)1, Liangchao Chen(陈良超)2,†, and Chao Fang(房超)2,‡ |
1 Inner Mongolia Key Laboratory of High-pressure Phase Functional Materials, Chifeng University, Chifeng 024000, China;
2 Key Laboratory of Material Physics of Ministry of Education, School of Physics and Microelectronics, Zhengzhou University, Zhengzhou 450052, China |
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Abstract The regulating nitrogen content of diamond in a hydrogen-rich high-temperature and high-pressure (HPHT) growth environment was systematically investigated in this work by developing three growth systems, namely, "FeNi$+$Ti", "FeNi$+$C$_{3}$N$_{6}$H$_{6}$", and "FeNi$+$Ti$+$C$_{3}$N$_{6}$H$_{6}$". Optical microscopy, infrared spectroscopy, and photoluminescence (PL) spectroscopy measurements were conducted to analyze the spectroscopic characteristics of diamonds grown in these three systems. From our analysis, it was demonstrated that the presence of hydrogen in the sp$^{3}$ hybrid C-H does not directly affect the color of the diamond and facilitates the increase of the nitrogen-vacancy (NV) center concentration in a high-nitrogen-content diamond. In addition, titanium plays an important role in nitrogen removal, while its impact on hydrogen doping within the diamond lattice is insignificant. Most importantly, by regulating the ratio of nitrogen impurities that coexist in the nitrogen and hydrogen HPHT environment, the production of hydrogenous IIa-type diamond, hydrogenous Ib-type diamond, and hydrogenous high-nitrogen-type diamonds was achieved with a nitrogen content of less than 1ppm to 1600ppm.
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Received: 25 November 2023
Revised: 04 February 2024
Accepted manuscript online: 19 February 2024
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PACS:
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81.05.ug
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(Diamond)
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81.05.uj
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(Diamond/nanocarbon composites)
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07.35.+k
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(High-pressure apparatus; shock tubes; diamond anvil cells)
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81.10.-h
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(Methods of crystal growth; physics and chemistry of crystal growth, crystal morphology, and orientation)
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| Fund: The project was supported by the National Natural Science Foundation of China (Grant Nos. 12274373 and 12004341), the Open Project of Inner Mongolia Key Laboratory of High-pressure Phase Functional Materials, Chifeng University (Grant No. cfxygy202301), the Science and Technology Project of Xilinguole Province (Grant No. 202209), and the Natural Science Foundation of Henan Province (Grant No. 242300421155). |
Corresponding Authors:
Liangchao Chen, Chao Fang
E-mail: chenlc@zzu.edu.cn;fangchao1989@zzu.edu.cn
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Cite this article:
Guofeng Huang(黄国锋), Liangchao Chen(陈良超), and Chao Fang(房超) Synthesis and nitrogen content regulation of diamond in a high-pressure hydrogen-rich environment 2024 Chin. Phys. B 33 068102
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