The low-temperature sintering and microwave dielectric properties of (Zn0.7Mg0.3)TiO3 ceramics with H3BO3

doi:10.1088/1674-1056/22/8/087801

Abstract The effects of the addition of H₃BO₃ on the microstructure, phase formation, and microwave dielectric properties of (Zn_0.7Mg_0.3)TiO₃ ceramics sintered at temperatures ranging from 890 ℃ to 950 ℃ are investigated. H₃BO₃ as a sintering agent can effectively lower the sintering temperature of ZMT ceramics below 950 ℃ due to the liquid-phase effect. The microwave dielectric properties are found to strongly correlate with the amount of H₃BO₃. With the increase in H₃BO₃ content, the dielectric constant (ε_r) monotonically increases, but the quality factor (Q×f) reaches a maximum at 1 wt% H₃BO₃, and the apparent density of ZMT ceramics with H₃BO₃ ≥ 1 wt% gradually decreases. At 950 ℃, the ZMT ceramics with 1% H₃BO₃ exhibit excellent microwave dielectric properties: ε_r=19.8, and Q×f=43800 GHz (8.94 GHz).

Keywords: ZMT ceramics LTCC H₃BO₃

Received: 07 November 2012
Revised: 07 January 2013
Accepted manuscript online:

PACS:

78.20.Ci

(Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity))

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 61171047, 51132003, 51072029, and 61271038), the Program for New Century Excellent Talents in University, and the Fund from the Science and Technology Department of Sichuan Province, China.

Corresponding Authors: Su Hua
E-mail: uestcsh@163.com

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Shen Guo-Ce (沈国策), Su Hua (苏桦), Zhang Huai-Wu (张怀武), Jing Yu-Lan (荆玉兰), Tang Xiao-Li (唐晓莉) The low-temperature sintering and microwave dielectric properties of (Zn_0.7Mg_0.3)TiO₃ ceramics with H₃BO₃ 2013 Chin. Phys. B 22 087801

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The low-temperature sintering and microwave dielectric properties of (Zn0.7Mg0.3)TiO3 ceramics with H3BO3

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The low-temperature sintering and microwave dielectric properties of (Zn_0.7Mg_0.3)TiO₃ ceramics with H₃BO₃