Ca2BO3Cl:Ce3+, Tb3+: A novel tunable emitting phosphor for white light-emitting diode

doi:10.1088/1674-1056/21/12/127804

Abstract Ca₂BO₃Cl:Ce³⁺, Ca₂BO₃Cl:Tb³⁺, and Ca₂BO₃Cl:Ce³⁺, Tb³⁺ phosphors are synthesized by a high temperature solid-state reaction. The emission intensity of Ce³⁺ or Tb³⁺ in Ca₂BO₃Cl is influenced by the Ce³⁺ or Tb³⁺ doping content, and the optimum concentrations of Ce³⁺ and Tb³⁺ are 0.03 mol and 0.05 mol, respectively. The concentration quenching effect of Ce³⁺ or Tb³⁺ in Ca₂BO₃Cl occurs, and the concentration quenching mechanism is d-d interaction for either Ce³⁺ or Tb³⁺. The Ca₂BO₃Cl:Ce³⁺, Tb³⁺ can produce colour emission from blue to green by properly tuning the relative ratio between Ce³⁺ and Tb³⁺, and the emission intensity of Tb³⁺ in Ca₂BO₃Cl can be enhanced by the energy transfer from Ce³⁺ to Tb³⁺. The results indicate that Ca₂BO₃Cl:Ce³⁺, Tb³⁺ may be a promising double emission phosphor for UV-based white light emitting diode.

Keywords: luminescence phosphor Ca₂BO₃Cl：Ce³⁺ Tb³⁺ energy transfer

Received: 17 April 2012
Revised: 08 May 2012
Accepted manuscript online:

PACS:	78.55.-m	(Photoluminescence, properties and materials)
	33.50.Dq	(Fluorescence and phosphorescence spectra)
	33.20.Kf	(Visible spectra)

Fund: Project supported by the National Basic Research Program of China (Grant No. 2010CB327704), the National Natural Science Foundation for Distinguished Young Scholars of China (Grant No. 60825407), the New Century Excellent Talents in University (Grant No. NCET-10-0220), the National Natural Science Foundation of China (Grant Nos. 10974013, 60978060, 10804006, and 50902042)

Corresponding Authors: Wang Yong-Sheng, Xu Zheng
E-mail: yshwang@bjtu.edu.cn;zhengxu@bjtu.edu.cn

Cite this article:

Li Pan-Lai (李盼来), Wang Yong-Sheng (王永生), Zhao Su-Ling (赵谡玲), Zhang Fu-Jun (张福俊), Xu Zheng (徐征) Ca₂BO₃Cl:Ce³⁺, Tb³⁺: A novel tunable emitting phosphor for white light-emitting diode 2012 Chin. Phys. B 21 127804

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Ca2BO3Cl:Ce3+, Tb3+: A novel tunable emitting phosphor for white light-emitting diode

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Ca₂BO₃Cl:Ce³⁺, Tb³⁺: A novel tunable emitting phosphor for white light-emitting diode