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Chin. Phys. B, 2010, Vol. 19(1): 013102    DOI: 10.1088/1674-1056/19/1/013102
ATOMIC AND MOLECULAR PHYSICS Prev   Next  

Solvent effects on the S0S2 absorption spectra of $\beta$-carotene

Liu Wei-Long(刘伟龙)a), Wang De-Min(王德敏)a), Zheng Zhi-Ren(郑植仁)a)† , Li Ai-Hua(李艾华)a), and Su Wen-Hui(苏文辉)a)b)
a Center for Condensed-Matter Science and Technology, Harbin Institute of Technology, Harbin 150001, China; b International Center for Materials Physics, Chinese Academy of Sciences, Shenyang 110015, China
Abstract  Absorption spectra of $\beta$ -carotene in 31 solvents are measured in ambient conditions. Solvent effects on the 0--0 band energy, the bandwidth, and the transition moment of the S0S2 transition are analysed. The discrepancies between published results of the solvent effects on the 0--0 band energy are explained by taking into account microscopic solute-solvent interactions. The contributions of polarity and polarizability of solvents to 0--0 band energy and bandwidth are quantitatively distinguished. The 0--0 transition energy of the S2 state at the gas phase is predicted to locate between 23000 and 23600 cm-1.
Keywords:  solvent effects       absorption spectra       $\beta$-carotene  
Received:  25 May 2009      Revised:  08 July 2009      Accepted manuscript online: 
PACS:  78.40.Dw (Liquids)  
  61.25.Em (Molecular liquids)  
Fund: Project supported by the National Natural Science Foundation of China (Grant No. 10774034).

Cite this article: 

Liu Wei-Long(刘伟龙), Wang De-Min(王德敏), Zheng Zhi-Ren(郑植仁), Li Ai-Hua(李艾华), and Su Wen-Hui(苏文辉) Solvent effects on the S0S2 absorption spectra of $\beta$-carotene 2010 Chin. Phys. B 19 013102

[1] Cramer C J and Trular D G 1999 Chem. Rev. 99 2161
[2] Li X Y and Fu K X 2005 J. Theo. & Comp. Chem. 4 907
[3] Han Q Z, Geng C Y, Zhao Y H, Qi C S and Wen H 2008 Acta Phys. Sin. 57 96 (in Chinese)
[4] Onsager L 1936 J. Am. Chem. Soc. 58 1486
[5] Guo Y H, Sun Y H, Tao L M, Zhao K and Wang C K 2005 Chin. Phys. 14 2202
[6] Bayliss N S 1950 J. Chem. Phys. 18 292
[7] Polívka T and Sundstr?m V 2004 Chem. Rev. 104 2021
[8] Zhao X H, Ma F, Wu Y S, Ai X C and Zhang J P 2008 Acta Phys. Sin. 57 298 (in Chinese)
[9] Liu W M, Liu Y, Liu K J, Yan Y L, Guo L J, Xu C H and Qian S X 2006 Chin. Phys. 15 1725
[10] Andersson P O, Gillbro T, Ferrguson L and Cogdell R J 1991 Photochem. Photobiol. 54 353
[11] Kuki M, Nagae H, Cogdell R J, Shimada K and Koyama Y 1994 Photochem. Photobiol. 59 116
[12] Nagae H, Kuki M, Cogdell R J and Koyama Y 1994 J. Chem. Phys. 101 6750
[13] Reng I, Grondelle R V and Dekker J P 1996 J. Photochem. Photobiol. A 96 109
[14] Laurence C, Nicolet P, Dalati M T, Abboud J L M and Notario R 1994 J. Phys. Chem. 98 5807
[15] Abe T, Abboud J L M, Belio F, Bosch E, Garcia J I, Mayoral J A, Notario R, Ortega J and Rosés M 1998 J. Phys. Org. Chem. 11 193
[16] Chen Z G, Lee C, Lenzer T and Oum K 2006 J. Phys. Chem. A 110 11291
[17] Torii H and Tasumi M 1993 J. Chem. Phys. 98 3697
[18] Frank H A, Bautista J A, Josue J, Pendon Z, Hiller R G, Sharples F P, Gosztola D and Wasielewski M R 2000 J. Phys. Chem. B 104 4569
[19] Christensen R L and Kohler B E 1973 Photochem. Photobiol. 18] 293
[20] Christensen R L, Goyette M, Gallagher L, Duncan J, DeCoster B, Lugtenburg J, Jansen F J and van der Hoef I 1999 J. Phys. Chem. A 103 2399
[21] Liu W L, Zheng Z R, Zhu R B, Liu Z G, Xu D P, Yu H M, Wu W Z, Li A H, Yang Y Q and Su W H 2007 J. Phys. Chem. A 111 10044
[22] Liu W L, Zheng Z R, Dai Z F, Liu Z G, Zhu R B, Wu W Z, Li A H, Yang Y Q and Su W H 2008 J. Chem. Phys. 128 124501-1
[23] Craft N E and Soares J H 1992 J. Agric. Food. Chem. 40 431
[24] Yang X Z, Li P, Dai S H, Wu D C, Li R X, Yang J H and Xiao H B 2005 Spectrosc. Spectr. Anal. 25 1830 (in Chinese)
[25] Dai S H, Li P, Yang, X Z, Wu D C, Li R X, Yang J H and Xiao H B 2006 Acta Opt. Sin. 26 141 (in Chinese)
[26] Wang P, Nakamura R, Kanematsu Y, Koyama Y, Nagae H, Nishio T, Hashimoto H and Zhang J P 2005 Chem. Phys. Lett. 410 108
[27] Mukamel S, Abe S, Yan Y J and Islampour R 1985 J. Phys. Chem. 89 201
[28] Yan Y J and Mukamel S 1986 J. Chem. Phys. 85 5908
[29] Torii H and Tasumi M 1990 J. Phys. Chem. 94 227
[30] Nicol M, Swain J, Shum Y Y, Merin R and Chen R H H 1968 J. Chem. Phys. 48 3587
[31] Myers A B and Birge R R 1980 J. Chem. Phys. 73 5314
[32] Macpherson A N and Gillbro T 1998 J. Phys. Chem. A 102 5049
[33] Wang C K, Xing X J, Huang X M and Gao Y 2007 Chin. Phys. 16 3323
[34] Mchale J L 2001 Acc. Chem. Res. 34 265
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