Effects of Cu and Co additions on the crystallization and magnetic properties of FeNbB alloy

doi:10.1088/1674-1056/acd525

Abstract The nanocrystalline-forming element Cu and magnetic element Co are commonly used as additive elements to tune the structure and improve the properties of alloys. In this study, four kinds of amorphous alloys, Fe₇₂Nb₁₂B₁₆, Fe₇₂Nb₁₂B₁₅Cu₁, Fe₃₆Co₃₆Nb₁₂B₁₆, and Fe₃₆Co₃₆Nb₁₂B₁₅Cu₁, were prepared by melt-spinning and annealed at various temperatures to investigate the effects of Cu and Co additions, individually and in combination, on the crystallization and magnetic properties of Fe₇₂Nb₁₂B₁₆ alloy. The four kinds of alloys exhibited different crystallization behaviors with different primary crystallization phases observed. For the Fe₇₂Nb₁₂B₁₆ alloy, only the α-Mn-type metastable phase formed after annealing. The addition of 1 at.% Cu and 36 at.% Co led to the observation of the α-Mn-type and β-Mn-type metastable phases, respectively, and a reduction in the crystallization volume fraction in the metastable phase. The Fe₃₆Co₃₆Nb₁₂B₁₅Cu₁ alloy only exhibited α-Fe(Co) phase as a primary phase, and the addition of both Cu and Co completely inhibited the precipitation of the metastable phase. Cu clusters were found in energy dispersive spectroscopy elemental maps. Compared with other alloys, Fe₃₆Co₃₆Nb₁₂B₁₅Cu₁ alloy with both Cu and Co exhibited a lower coercivity (H_c) below 973 K.

Keywords: alloys nanocrystalline Cu addition Co addition

Received: 07 March 2023
Revised: 23 April 2023
Accepted manuscript online: 12 May 2023

PACS:

81.07.-b

(Nanoscale materials and structures: fabrication and characterization)

Fund: Project supported by the National Natural Science Foundation of China (Grant No.21905110), the Natural Science Foundation of Jilin Province of China(Grant No.YDZJ202201ZYTS319), and the Sinoma Institute of Materials Research Co., Ltd. of Guangzhou Province of China.

Corresponding Authors: Wan-Qiu Yu
E-mail: yuwanqiu2004@126.com

Cite this article:

Wan-Qiu Yu(于万秋), Bo Tian(田博), Ping-Li Zhang(张平丽), Jia-Hui Wang(王佳慧), and Zhong Hua(华中) Effects of Cu and Co additions on the crystallization and magnetic properties of FeNbB alloy 2023 Chin. Phys. B 32 088102

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Effects of Cu and Co additions on the crystallization and magnetic properties of FeNbB alloy

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