CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES |
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Pressure-dependent terahertz optical characterization of heptafluoropropane |
Leng Wen-Xiu (冷文秀)a b, Ge Li-Na (戈立娜)c, Xu Shan-Sen (徐山森)d, Zhan Hong-Lei (詹洪磊)c, Zhao Kun (赵昆)a b c |
a State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China; b Key Laboratory of Oil and Gas Terahertz Spectroscopy and Photoelectric Detection, China Petroleum and Chemical Industry Federation (CPCIF), Beijing 100723, China; c Beijing Key Laboratory of Optical Detection Technology for Oil and Gas, China University of Petroleum, Beijing 102249, China; d Xi'an Polytechnic University, Xi'an 710048, China |
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Abstract Heptafluoropropane (HFP), as the best alternative to halon fire-suppression agents, is now a widely used fire extinguishing agent. The current studies of HFP, concentrating on the extinguishing mechanisms of flames and decomposition products, in general deal with the destructive and high temperature cases. In this paper, terahertz time-domain spectra are used to characterize HFP at different pressures. Optical parameters of HFP, such as absorption coefficient, refractive index, and relative permittivity, and their relationship with concentration of samples, are discussed. The absorption peak of HFP at 0.3 THz depends strongly on the applied pressure, and the corresponding parameters increase almost linearly with increasing HFP concentration. The present study lays a foundation for future extensive applications.
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Received: 11 July 2014
Revised: 20 August 2014
Accepted manuscript online:
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PACS:
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78.47.D-
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(Time resolved spectroscopy (>1 psec))
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42.87.-d
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(Optical testing techniques)
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78.20.Ci
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(Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity))
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Fund: Project supported by the National Key Basic Research Program of China (Grant No. 2014CB744300), the Specially Funded Program on National Key Scientific Instruments and Equipment Development, China (Grant No. 2012YQ140005), and the Beijing Natural Science Foundation (Grant No. 4122064). |
Corresponding Authors:
Zhao Kun
E-mail: zhk@cup.edu.cn
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About author: 78.47.D-; 42.87.-d; 78.20.Ci |
Cite this article:
Leng Wen-Xiu (冷文秀), Ge Li-Na (戈立娜), Xu Shan-Sen (徐山森), Zhan Hong-Lei (詹洪磊), Zhao Kun (赵昆) Pressure-dependent terahertz optical characterization of heptafluoropropane 2014 Chin. Phys. B 23 107804
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| [1] | Miziolek A W and Tsang W 1995 ACS Symposium Series (Washington DC: American Chemical Society) p. 388
|
|
| [2] | Sheinson R S and Penner-Hahn J E 1989 Fire Safety J. 15 437
|
|
| [3] | Nyden M R and Linteris G T 1994 J. Res. Natl. Inst. Stan. 861 467
|
|
| [4] | Durlka S K and Biswas P 1998 Environ. Sci. Technol. 32 2301
|
|
| [5] | Wang J, Levendis Y A and Riegter H 2001 Environ. Sci. Technol. 35 3541
|
|
| [6] | Rossi M, Camino G and Luda M 2001 Polym. Degrad. Stabil. 74 507
|
|
| [7] | Wirbser H, Bräuning G, Gürtner J and Ernst G 1992 J. Chem. Thermodyn. 24 761
|
|
| [8] | Scalabrin G, Piazza L and Richon D 2002 Fluid Phase Equilibr. 199 33
|
|
| [9] | Defibaugh D R and Moldover M R 1997 J. Chem. Eng. Data 42 160
|
|
| [10] | Lee C, Yang W and Parr R G 1988 Phys. Rev. B 37 785
|
|
| [11] | Westmoreland P R 1994 Twenty-Fifth Symposium (International) on Combustion 1505
|
|
| [12] | Burgess Jr 1996 Prog. Energy Combust. Sci. 21 453
|
|
| [13] | The current NIST HFC mechanism may be downloaded from
|
|
| [14] | Lucarini V and Saarinen J J 2005 Kramers-Kronig Relations in Optical Materials Research (Berlin: Springer)
|
|
| [15] | Zhao H, Zhao K and Bao R M 2012 J. Infrared Milli. Terahz Waves 33 522
|
|
| [16] | Watanabe Y 2004 Opt. Commun. 234 125
|
|
| [17] | Chen Y 2011 J. Appl. Phys. 110 044902
|
|
| [18] | Choi D H 2012 J. Chem. Phys. 137 175101
|
|
| [19] | Fukunaga K and Picollo M 2010 Appl. Phys. A 100 591
|
|
| [20] | Jiang C 2014 Energ. Fuels 28 483
|
|
| [21] | Jin W J 2013 Appl. Geophys. 10 496
|
|
| [22] | Bao R M 2013 Sci. China: Phys. Mech. Astron. 56 1603
|
|
| [23] | Zhao H 2012 Sci. China: Phys. Mech. Astron. 55 195
|
|
| [24] | Tian L 2009 Sci. China: Series G: Phys. Mech. Astron. 39 1938
|
|
| [25] | Naftaly M 2007 Proc. IEEE 95 1658
|
|
| [26] | Exter M V 1989 Opt. Lett. 14 1128
|
|
| [27] | Wang H and Zhao G Z 2010 Acta Photonica Sinica 39 1185
|
|
| [28] | Liu X M and Shao M 2004 Acta Scientiae Circumstantiae 24 185
|
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