XPS and Raman studies of electron irradiated sodium silicate glass

doi:10.1088/1674-1056/22/12/126101

Abstract The microstructure modifications of sodium silicate glass induced by 1.2-MeV electron irradiation are studied by x-ray photoelectron spectroscopy and Raman spectroscopy. Depth profile analyses are also performed on the irradiated glass at 10⁹ Gy. A sodium-depleted layer with a thickness of a few tens of nanometers and the corresponding increase of network polymerization on the top surface are observed after electron bombardment, while the polymerization in the subsurface region has a negligible variation with the irradiation dose. Moreover, the formation of molecular oxygen after electron irradiation is evidenced, which is mainly aggregated in the first two-micron-thick irradiated glass surface. These modifications are correlated to the network relaxation process as a consequence of the diffusion and desorption of sodium species during electron irradiation.

Keywords: silicate glass electron irradiation network polymerization oxygen molecule

Received: 03 January 2013
Revised: 31 May 2013
Accepted manuscript online:

PACS:	61.43.Fs	(Glasses)
	61.80.Fe	(Electron and positron radiation effects)

Corresponding Authors: Wang Tie-Shan
E-mail: tswang@lzu.edu.cn

Cite this article:

Chen Liang (陈亮), Wang Tie-Shan (王铁山), Zhang Gen-Fa (张根发), Yang Kun-Jie (杨坤杰), Peng Hai-Bo (彭海波), Zhang Li-Min (张利民) XPS and Raman studies of electron irradiated sodium silicate glass 2013 Chin. Phys. B 22 126101

[1]	Shelby J E 2005 Introduction to Glass Science and Technology (London: The Royal Society of Chemistry)
[2]	Li C R, Xu W, Dong B, Li S F, Ding J H, Cheng Y Q and Yin H T 2010 Chin. Phys. B 19 047801
[3]	Tian H, Liu J W, Qiu K, Song J and Wang D J 2012 Chin. Phys. B 21 098504
[4]	Lee S K 2005 Geochim. Cosmochim. Acta 69 3695
[5]	Weber W J, Ewing R C, Angell C A, Arnold G W, Cormack A N, Delaye J M, Griscom D L, Hobbs L W, Navrotsky A, Price D L, Stoneham A M and Weinberg M C 1997 J. Mater. Res. 12 1946
[6]	Boizot B, Petite G, Ghaleb D and Calas G 1998 Nucl. Instrum. Method B 141 580
[7]	Malchukova E, Boizot B, Petite G and Ghaleb D 2007 Phys. Stat. Sol. 4 1280
[8]	Boizot B, Petite G, Ghaleb D, Reynard B and Calas G 1999 J. Non-Crystal Solids 243 268
[9]	Ollier N, Boizot B, Reynard B, Ghaleb D and Petite G 2005 J. Nucl. Mater. 340 209
[10]	Ollier N, Rizza G, Boizot B and Petite G 2006 J. Appl. Phys. 99 073511
[11]	Sun K, Wang L M, Ewing R C and Weber W J 2005 Philos. Mag. 85 597
[12]	Jiang N and Silcox J 2002 J. Appl. Phys. 92 2310
[13]	Ohuchi F and Holloway P H 1982 J. Vac. Sci. Technol. 20 863
[14]	Miotello A, Cinque G, Mazzoldi P and Pantano C G 1991 Phys. Rev. B 43 3831
[15]	Gedeon O, Jurek K and Hulinsky V 1999 J. Non-Crystal Solids 246 1
[16]	http://physics.nist.gov/PhysRefData/Star/Text/ESTAR.html
[17]	Gedeon O and Zemek J 2003 J. Non-Crystal Solids 320 177
[18]	Mekki A, Holland D, McConville C F and Salim M 1996 J. Non-Crystal Solids 208 267
[19]	Brow R K 1988 J. Non-Crystal Solids 107 1
[20]	Bonfils J D, Peuget S, Panczer G, Ligny D D, Henry S, Noël P Y, Chenet A and Champagnon B 2010 J. Non-Crystal Solids 356 388
[21]	Miura Y, Kusano H, Nanba T and Matsumoto S 2001 J. Non-Crystal Solids 290 1
[22]	Henderson D O, George M A, Tung Y S, Mu R, Burger A, Morgan S H and Collins W E 1995 J. Vac. Sci. Technol. A 13 1254
[23]	Cazaux J 1986 J. Appl. Phys. 59 1418
[24]	Zhao S L and Bertrand P 2011 Chin. Phys. B 20 037901
[25]	Ramsier R D and Yates J T 1991 Surf. Sci. Rep. 12 243
[26]	Czanderna A W, Madey T E and Powell C J 2002 Beam Effects, Surface Topography, and Depth Profiling in Surface Analysis (New York: Kluwer Academic)
[27]	Miotello A and Toigo F 1987 Nucl. Instrum. Method B 19/20 934
[28]	Manara D, GranDjean A and Neuville D R 2009 Am. Mineral. 94 777
[29]	Umesaki N, Takahashi M, Tatsumisago M and Minami T 1996 J. Non-Crystal Solids 205–207 225
[30]	Wang M, Cheng J, Li M and He F 2011 Physica B 406 3865
[31]	Zemek J, Jiricek P, Gedeon O, Lesiak B and Jozwik A 2005 J. Non-Crystal Solids 351 1665

[1]	Irradiation behavior and recovery effect of ferroelectric properties of PZT thin films Yu Zhao(赵瑜), Wen-Yue Zhao(赵文悦), Dan-Dan Ju(琚丹丹), Yue-Yue Yao(姚月月), Hao Wang(王豪), Cheng-Yue Sun(孙承月), Ya-Zhou Peng(彭亚洲), Yi-Yong Wu(吴宜勇), and Wei-Dong Fei(费维栋). Chin. Phys. B, 2021, 30(10): 107702.
[2]	Improved electrical properties of NO-nitrided SiC/SiO₂ interface after electron irradiation Ji-Long Hao(郝继龙), Yun Bai(白云), Xin-Yu Liu(刘新宇), Cheng-Zhan Li(李诚瞻), Yi-Dan Tang(汤益丹), Hong Chen(陈宏), Xiao-Li Tian(田晓丽), Jiang Lu(陆江), Sheng-Kai Wang(王盛凯). Chin. Phys. B, 2020, 29(9): 097301.
[3]	Molecular opacities of low-lying states of oxygen molecule Gui-Ying Liang(梁桂颖), Yi-Geng Peng(彭裔耕), Rui Li(李瑞), Yong Wu(吴勇), Jian-Guo Wang(王建国). Chin. Phys. B, 2020, 29(2): 023101.
[4]	A synthetic semi-empirical physical model of secondary electron yield of metals under E-beam irradiation Guo-Bao Feng(封国宝), Wan-Zhao Cui(崔万照), Na Zhang(张娜), Meng Cao(曹猛), Chun-Liang Liu(刘纯亮). Chin. Phys. B, 2017, 26(9): 097901.
[5]	Non-ionizing energy loss calculations for modeling electron-induced degradation of Cu(In, Ga)Se₂ thin-film solar cells Ming Lu(鲁明), Jing Xu(徐晶), Jian-Wei Huang(黄建微). Chin. Phys. B, 2016, 25(9): 098402.
[6]	Photocarrier radiometry for noncontact evaluation of space monocrystalline silicon solar cell under low-energy electron irradiation Liu Jun-Yan (刘俊岩), Song Peng (宋鹏), Wang Fei (王飞), Wang Yang (王扬). Chin. Phys. B, 2015, 24(9): 097801.
[7]	Visible to deep ultraviolet range optical absorption of electron irradiated borosilicate glass Wang Tie-Shan (王铁山), Duan Bing-Huang (段丙皇), Tian Feng (田丰), Peng Hai-Bo (彭海波), Chen Liang (陈亮), Zhang Li-Min (张利民), Yuan Wei (袁伟). Chin. Phys. B, 2015, 24(7): 076102.
[8]	Characteristics of charge and discharge of PMMA samples due to electron irradiation Feng Guo-Bao (封国宝), Wang Fang (王芳), Hu Tian-Cun (胡天存), Cao Meng (曹猛). Chin. Phys. B, 2015, 24(11): 117901.
[9]	Electron irradiation-induced change of structure and damage mechanisms in multi-walled carbon nanotubes Yang Jian-Qun (杨剑群), Li Xing-Ji (李兴冀), Liu Chao-Ming (刘超铭), Ma Guo-Liang (马国亮), Gao Feng (高峰). Chin. Phys. B, 2015, 24(11): 116103.
[10]	Color-converted remote phosphor prototype of multiwavelength excitable borosilicate glass for white light-emitting diodes Tian Hua (田华), Liu Ji-Wen (刘技文), Qiu Kun (仇坤), Song Jun (宋俊), Wang Da-Jian (王达健). Chin. Phys. B, 2012, 21(9): 098504.
[11]	Charging dynamics of polymer due to electron irradiation: A simultaneous scattering-transport model and preliminary results Cao Meng (曹猛), Wang Fang (王芳), Liu Jing (刘婧), Zhang Hai-Bo (张海波). Chin. Phys. B, 2012, 21(12): 127901.
[12]	Optical parameters of Nd³⁺:Er³⁺:Yb³⁺ co-doped borosilicate glasses and their energy transfers at high temperature Li Cheng-Ren(李成仁), Li Shu-Feng(李淑凤), Dong Bin(董斌), Cheng Yu-Qi(程宇琪), Yin Hai-Tao(殷海涛), Yang Jing(杨静), and Chen Yu(陈宇). Chin. Phys. B, 2011, 20(1): 017803.
[13]	Up-conversion photoluminescence characteristics of Yb³⁺:Er³⁺:Tm³⁺ co-doped borosilicate glasses Li Cheng-Ren(李成仁),Xu Wei(徐伟),Dong Bin(董斌), Li Shu-Feng(李淑凤),Ding Jian-Hua(丁建华), Cheng Yu-Qi(程宇琪), and Yin Hai-Tao(殷海涛). Chin. Phys. B, 2010, 19(4): 047801.
[14]	Infrared studies of oxygen-related complexes in electron-irradiated Cz-Si Chen Gui-Feng(陈贵锋), Yan Wen-Bo(阎文博), Chen Hong-Jian(陈洪建), Cui Hui-Ying(崔会英), and Li Yang-Xian(李养贤). Chin. Phys. B, 2009, 18(7): 2988-2991.
[15]	Dynamic Ni gettered by PSG from S-MIC poly-Si and its TFTs Meng Zhi-Guo(孟志国), Li Yang(李阳), Wu Chun-Ya(吴春亚), Zhao Shu-Yun(赵淑芸), Li Juan(李娟), Man Wong(王文), Hoi Sing-Kwok(郭海诚), and Xiong Shao-Zhen(熊绍珍). Chin. Phys. B, 2008, 17(4): 1415-1420.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Metrics
Related Articles

XPS and Raman studies of electron irradiated sodium silicate glass

Cite this article:

Online attention