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The concentration quenching and crystallographic sites of Eu2+ in Ca2BO3Cl |
Li Pan-Lai(李盼来)a)b)c), Xu Zheng(徐征)a)b)†, Zhao Su-Ling(赵谡玲)a)b), Wang Yong-Sheng(王永生)a)b), and Zhang Fu-Jun(张福俊)a)b) |
a. Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing 100044, China;
b. Institute of Optoelectronics Technology, Beijing Jiaotong University, Beijing 100044, China;
c. College of Physics Science & Technology, Hebei University, Baoding 071002, China |
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Abstract A yellow phosphor, Ca2BO3Cl:Eu2+, is prepared by the high-temperature solid-state method. Under the condition of excitation sources ranging from ultraviolet to visible light, efficient yellow emission can be observed. The emission spectrum shows an asymmetrical single intensive band centred at 573 nm, which corresponds to the 4f,65d1→4f,7 transition of Eu2+. Eu2+ ions occupy two types of Ca2+ sites in the Ca2BO3Cl lattice and form two corresponding emission centres, respectively, which lead to the asymmetrical emission of Eu2+ in Ca2BO3Cl. The emission intensity of Eu2+ in Ca2BO3Cl is influenced by the Eu2+ doping concentration. Concentration quenching is discovered, and its mechanism is verified to be a dipole-dipole interaction. The value of the critical transfer distance is calculated to be 2.166 nm, which is in good agreement with the 2.120 nm value derived from the experimental data.
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Received: 25 August 2011
Revised: 09 October 2011
Accepted manuscript online:
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PACS:
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78.55.-m
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(Photoluminescence, properties and materials)
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33.50.Dq
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(Fluorescence and phosphorescence spectra)
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33.20.Kf
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(Visible spectra)
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Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 10974013, 60978060, and 10804006), the Research Fund for the Doctoral Program of Higher Education, China (Grant No. 20090009110027), the Beijing Municipal Natural Science Foundation, China (Grant No. 1102028), the National Basic Research Program of China (Grant No. 2010CB327704), the National Natural Science Foundation for Distinguished Young Scholars (Grant No. 60825407), the Beijing Municipal Science and Technology Commission, China (Grant No. Z090803044009001), the Science Fund of the Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Ministry of Education, China (Grant No. 2010LOI12), and the Excellent Doctor’s Science and Technology Innovation Foundation of Beijing Jiaotong University, China (Grant No. 2011YJS073). |
Corresponding Authors:
Xu Zheng,zhengxu@bjtu.edu.cn
E-mail: zhengxu@bjtu.edu.cn
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Cite this article:
Li Pan-Lai(李盼来), Xu Zheng(徐征), Zhao Su-Ling(赵谡玲), Wang Yong-Sheng(王永生), and Zhang Fu-Jun(张福俊) The concentration quenching and crystallographic sites of Eu2+ in Ca2BO3Cl 2012 Chin. Phys. B 21 047803
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[1] |
Lin H W, Lu Y J, Chen H Y, Lee H M and Gwo S 2010 Appl. Phys. Lett. 97 073101
|
[2] |
Kim T G, Lee H S, Lin C C, Kim T, Liu R S, Chan T S and Im S J 2010 Appl. Phys. Lett. 96 061904
|
[3] |
Tang H X and Lü S C 2011 Acta Phys. Sin. 60 037805 (in Chinese)
|
[4] |
Yu R J, Wang J, Zhang J H and Su Q 2011 J. Electrochem. Soc. 158 J86
|
[5] |
Zhang Z, Wang J, Zhang M, Zhang Q and Su Q 2008 Appl. Phys. B 91 529
|
[6] |
Guo C, Luan L, Ding X, Zhang F, Shi F G, Gao F and Liang L 2009 Appl. Phys. B 95 779
|
[7] |
Yu J, Guo C F, Ren Z Y and Bai J T 2011 Opt. & Laser Tech. 43 762
|
[8] |
Du H, Sun J, Xia Z and Sun J 2009 Appl. Phys. B 96 459
|
[9] |
Sivakumar V and Varadaraju V 2009 J. Electrochem. Soc. 156 J179
|
[10] |
Ding W J, Wang J, Liu Z M, Zhang M, Su Q and Tang J K 2008 J. Electrochem. Soc. 155 J122
|
[11] |
Song Y H, Jia G, Yang M, Huang Y J, Hou H P and Zhang H J 2009 Appl. Phys. Lett. 94 091902
|
[12] |
Tang Y S, Hu S F, Ke W C, Lin C C, Bagkar N C and Liu R S 2008 Appl. Phys. Lett. 93 131114
|
[13] |
Zhang X M, Park B, Kim J, Lee J and Choi J 2010 J. Lumin. 130 117
|
[14] |
Ding X, Xu Y and Guo C F 2010 Acta Phys. Sin. 59 6632 (in Chinese)
|
[15] |
Guo C F, Xu Y, Ding X, Li M, Yu J, Ren Z Y and Bai J T 2011 J. Alloys Compd. 509 L38
|
[16] |
Xia Z G, Du H Y, Sun J Y, Chen D M and Wang X F 2010 Mater. Chem. Phys. 119 7
|
[17] |
Yang Z P, Wang S L, Yang G W, Tian J, Li P L and Li X 2007 Mater. Lett. 61 5258
|
[18] |
Guo C F, Luan L, Shi F G and Ding X 2009 J. Electrochem. Soc. 156 J125
|
[19] |
Xiao F, Xue Y N and Zhang Q Y 2009 Physica B: Condensed Matter 404 3743
|
[20] |
Guo C F, Luan L, Shi L and Seo H J 2010 Electrochem. Solid-State Lett. 13 J28
|
[21] |
Wang Z J, Yang Z P, Guo Q L, Li P L and Fu G S 2009 Chin. Phys. B 18 2068
|
[22] |
Blasse G 1986 J. Solid State Chem. 62 207
|
[23] |
Dexter D L 1953 J. Chem. Phys. 21 836
|
[24] |
Van Uitert L G 1967 J. Electrochem. Soc. 114 1048
|
[25] |
Ozawa L and Jaffe P M 1971 J. Electrochem. Soc. 118 1678
|
[26] |
Zak Z and Hanic F 1976 Acta Cryst. Sect. B 32 1784
|
[27] |
Huang Z P, Jing X P and Yu H 1986 Chem. J. Chin. Univer. 7 759 (in Chinese)
|
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