Novel copper redox-based cathode materials for room-temperature sodium-ion batteries

doi:10.1088/1674-1056/23/11/118202

Abstract

Layered oxides of P2-type Na_0.68Cu_0.34Mn_0.66O₂, P2-type Na_0.68Cu_0.34Mn_0.50Ti_0.16O₂, and O'3-type NaCu_0.67Sb_0.33O₂ were synthesized and evaluated as cathode materials for room-temperature sodium-ion batteries. The first two materials can deliver a capacity of around 70 mAh/g. The Cu²⁺ is oxidized to Cu³⁺ during charging, and the Cu³⁺ goes back to Cu²⁺ upon discharging. This is the first demonstration of the highly reversible change of the redox couple of Cu²⁺/Cu³⁺ with high storage potential in secondary batteries.

Keywords: energy storage sodium-ion battery cathode copper redox

Received: 22 September 2014
Revised: 29 September 2014
Accepted manuscript online:

PACS:	82.45.Yz	(Nanostructured materials in electrochemistry)
	82.47.Aa	(Lithium-ion batteries)
	82.47.Cb	(Lead-acid, nickel-metal hydride and other batteries)
	84.60.-h	(Direct energy conversion and storage)

Corresponding Authors: Hu Yong-Sheng
E-mail: yshu@aphy.iphy.ac.cn

Cite this article:

Xu Shu-Yin (徐淑银), Wu Xiao-Yan (吴晓燕), Li Yun-Ming (李云明), Hu Yong-Sheng (胡勇胜), Chen Li-Quan (陈立泉) Novel copper redox-based cathode materials for room-temperature sodium-ion batteries 2014 Chin. Phys. B 23 118202

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Novel copper redox-based cathode materials for room-temperature sodium-ion batteries

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