Enhanced microwave absorption performance of MOF-derived hollow Zn-Co/C anchored on reduced graphene oxide

doi:10.1088/1674-1056/abd770

Abstract Composite materials assembled by metal/carbon nanoparticles and 2D layered flakes can provide abundant interfaces, which are beneficial for high-performance microwave absorbers. Herein, Zn-Co/C/RGO composites, composed of Zn-Co metal-organic framework-derived Zn-Co/C nanoparticles and reduced graphene oxide (RGO), were obtained through a facile method. The multilayer structure was due to the introduction of hollow Zn-Co/C nanoparticles in the RGO sheets. Zn-Co/C nanoparticles provided abundant polarization and dipole centers on the RGO surface, which enhanced the microwave absorption abilities. Different concentrations of RGO were introduced to optimize impedance matching. The minimum reflection loss (R_L) of Zn-Co/C/RGO with a thickness of 1.5 mm reached -32.56 dB with the bandwidth corresponding to R_L at -10 dB, which can reach 3.92 GHz, while a minimum R_L of -47.15 dB at 11.2 GHz was also obtained at a thickness of 2.0 mm. The electromagnetic data demonstrate that Zn-Co/C/RGO presented excellent absorption performance and has potential for application in the microwave absorption field.

Keywords: microwave absorption metal nanoparticles metal-organic framework (MOF) reduced graphene oxide

Received: 08 December 2020
Revised: 23 December 2020
Accepted manuscript online: 30 December 2020

PACS:

78.30.Jw

(Organic compounds, polymers)

Fund: Project supported by the National Key R&D Program of China (Grant No. 2016YFA0202302), the National Natural Science Foundation of China (Grant Nos. 61527817, 61875236, 61905010, and 61975007), and Beijing Natural Science Foundation, China (Grant No. Z190006).

Corresponding Authors: Dawei He
E-mail: dwhe@bjtu.edu.cn

Cite this article:

Yue Wang(王玥), Dawei He(何大伟), and Yongsheng Wang(王永生) Enhanced microwave absorption performance of MOF-derived hollow Zn-Co/C anchored on reduced graphene oxide 2021 Chin. Phys. B 30 067804

[1] Green M and Chen X 2019 Journal of Materiomics 5 503
[2] Liu L, Wang L, Li Q, Yu X, Shi X, Ding J, You W, Yang L, Zhang Y and Che R 2019 ChemNanoMat 5 558
[3] Zhao Z, Xu S, Du Z, Jiang C and Huang X 2019 ACS Sustainable Chem. Eng. 7 7183
[4] Liu H, Li L, Wang X, Cui G and Lv X 2020 Materials 13 4527
[5] Sun Q, Cai Y, Sun L, Ye W, Long X, Xu S, Ji Y and Wang R 2020 Journal of Materials Science 56 1492
[6] Uddin W, Rehman S U, Aslam M A, Rehman S U, Wu M and Zhu M 2020 Materials Research Bulletin 130 110943
[7] Wang H, Shi P, Rui M, Zhu A, Liu R and Zhang C 2020 Progress in Organic Coatings 139 105476
[8] Wang S, Jiao Q, Liu X, Xu Y, Shi Q, Yue S, Zhao Y, Liu H, Feng C and Shi D 2019 ACS Sustainable Chem. Eng. 7 7004
[9] Liu J, Che R, Chen H, Zhang F, Xia F, Wu Q and Wang M 2012 Small 8 1214
[10] Liu Q, Cao Q, Bi H, Liang C, Yuan K, She W, Yang Y and Che R 2016 Adv. Mater. 28 486
[11] You W, Bi H, She W, Zhang Y and Che R 2017 Small 13 1602779
[12] Wang X, Huang L, Li J, Du Y, Wang Q, He X and Yuan Y 2020 J. Appl. Phys. 127 205102
[13] Ma J, Li W, Fan Y, Yang J, Yang Q, Wang J, Luo W, Zhou W, Nomura N, Wang L and Jiang W 2019 ACS Appl. Mater. Interfaces 11 46386
[14] Zhou E, Xi J, Guo Y, Liu Y, Xu Z, Peng L, Gao W, Ying J, Chen Z and Gao C 2018 Carbon 133 316
[15] Zhao H, Yeow Seow J Z, Cheng Y, Xu Z J and Ji G 2020 Ceramics International 46 15447
[16] Yan L, Zhang M, Zhao S, Sun T, Zhang B, Cao M and Qin Y 2020 Chemical Engineering Journal 382 122860
[17] Che R C, Peng L M, Duan X F, Chen Q and Liang X L 2004 Adv. Mater. 16 401
[18] Che R C, Zhi C Y, Liang C Y and Zhou X G 2006 Appl. Phys. Lett. 88 033105
[19] Yan F, Guo D, Zhang S, Li C, Zhu C, Zhang X and Chen Y 2018 Nanoscale 10 2697
[20] Fu C, He D, Wang Y and Zhao X 2019 Synthetic Metals 257 116187
[21] Bai Y W, Shi G, Gao J and Shi F N 2020 Journal of Solid State Chemistry 288 121401
[22] Sun H, Che R, You X, Jiang Y, Yang Z, Deng J, Qiu L and Peng H 2014 Adv. Mater. 26 8120
[23] Wu Z, Pei K, Xing L, Yu X, You W and Che R 2019 Advanced Functional Materials 29 1901448
[24] Zong H, Yang H, Dong J, Ma L, Lin Y, Qiu Y and Wen B 2020 J. Mater. Sci: Mater. Electron. 31 18590
[25] Wu Z, Huang T, Li T and Li L 2019 Langmuir 35 3688
[26] Kang Y, Yuan B, Ma T, Chu Z Y and Zhang Z J 2018 J. Inorg. Mater. 33 1259
[27] Yu W Q, Qiu Y C, Xiao H J, Yang H T and Wang G M 2019 Chin. Phys. B 28 108103
[28] Wanga X, Lua Y, Zhua T, Changa S and Wang W 2020 Chemical Engineering Journal 388 124317
[29] Wang Y, Suo B, Shi Y, Yuan H, Zhu C and Chen Y 2020 ACS Appl. Mater. Inter. 12 40692
[30] Zhang X, Yan F, Zhang S, Yuan H, Zhu C, Zhang X and Chen Y 2018 Appl. Mater. Inter. 10 24920
[31] Zhang X, Xu J, Yuan H, Zhang S, Ouyang Q, Zhu C, Zhang X and Chen Y 2019 Appl. Mater. Inter. 11 39100
[32] Li Q, Zhao Y, Li X, Wang L, Li X, Zhang J and Che R 2020 Small 16 2003905
[33] Huo J, Wang L and Yu H 2009 Journal of Materials Science 44 3917
[34] Ruan W, Mu C, Wang B, Nie A, Zhang C, Du X, Xiang J, Wen F and Liu Z 2018 Nanotechnology 29 405703
[35] Wang L, Wen B, Yang H, Qiu Y and He N 2020 Compos Part A: Appl. S. 135 135958
[36] Zhang Y, Zhang H B, Wu X, Deng Z, Zhou E and Yu Z Z 2019 ACS Applied Nano Materials 2 2325
[37] Liu D, Du Y, Wang F, Wang Y, Cui L, Zhao H and Han X 2020 Carbon 157 478
[38] Liu W, Shao Q, Ji G, Liang X, Cheng Y, Quan B and Du Y 2017 Chemical Engineering Journal 313 734
[39] Gupta S, Chang C, Anbalagan A K, Lee C H and Tai N H 2020 Composites Science and Technology 188 107994
[40] Hu Q, Qi X, Cai H, Xie R, Long L, Bai Z, Jiang Y, Qin S, Zhong W and Du Y 2017 Sci. Rep. 7 11213
[41] Li X, Wang L, Li X, Zhang J, Wang M and Che R 2021 Carbon 172 15
[42] Wang Y, Di X, Gao X and Wu X 2020 Nanotechnology 31 395710
[43] Wang Y, Di X, Wu X and Li X 2020 J. Alloys Compd. 20 156215
[44] Xu J, Zhang X, Yuan H, Zhang S, Zhu C, Zhang X and Chen Y 2020 Carbon 159 357
[45] Zhang X, Xu J, Liu X, Zhang S, Yuan H, Zhu C, Zhang X and Chen Y 2019 Carbon 155 233
[46] Zhang X, Zhang X, Wang D, Yuan H, Zhang S, Zhu C, Zhang X and Chen Y 2019 Journal of Materials Chemistry C 7 11868
[47] Zhang X, Zhang X, Yuan H, Li K, Ouyang Q, Zhub C, Zhanga S and Chen Y 2020 Chemical Engineering Journal 383 123208
[48] Hummers W S Jr. and Offema R E 1958 J. Am. Chem. Soc. 80 1339
[49] Guan B Y, Kushima A, Yu L, Li S, Li J and Lou X W D 2017 Adv. Mater. 29 17
[50] Atamny E, Baiker A, Muhr H J and Nesper R 1995 Fresenius J. Anal. Chem. 353 433
[51] Fan X, Zhang A, Li M, Xu H, Xue J, Ye F and Cheng L 2020 Journal of Materials Science: Materials in Electronics 31 11774
[52] Sun Y, Jia H, Liu J, Yu H and Jiang X 2020 Journal of Materials Science: Materials in Electronics 31 11700
[53] Miao P, Cao J, Kong J, Li J, Wang T and Chen K J 2020 Nanoscale 12 13311
[54] Peng C, Zhang Y and Zhang B 2020 J. Alloys Compd. 826 154203
[55] Lu Y, Wang Y, Li H, Lin Y, Jiang Z, Xie Z, Kuang Q and Zheng L 2015 ACS Appl. Mater. Interfaces 7 13604
[56] Ding D, Wang Y, Li X, Qiang R, Xu P, Chu W, Han X and Du Y 2017 Carbon 111 722
[57] Ma T, Cui Y, Sha Y, Liu L, Ge J, Meng F and Wang F 2020 Synthetic Metals 265 116407

1. 2021-067804-SI.pdf(266KB)

[1]	Electromagnetic wave absorption properties of Ba(CoTi)_xFe_12-2xO₁₉@BiFeO₃ in hundreds of megahertz band Zhi-Biao Xu(徐志彪), Zhao-Hui Qi(齐照辉), Guo-Wu Wang(王国武), Chang Liu(刘畅), Jing-Hao Cui(崔晶浩), Wen-Liang Li(李文梁), and Tao Wang(王涛). Chin. Phys. B, 2022, 31(8): 087504.
[2]	Photoelectrochemical activity of ZnO:Ag/rGO photo-anodes synthesized by two-steps sol-gel method D Ben Jemia, M Karyaoui, M A Wederni, A Bardaoui, M V Martinez-Huerta, M Amlouk, and R Chtourou. Chin. Phys. B, 2022, 31(5): 058201.
[3]	Thermoelectric characteristics of flexible reduced graphene oxide/silver selenide nanowire composites prepared by a facile vacuum filtration process Zuo Xiao(肖佐), Yong Du(杜永), Qiufeng Meng(孟秋风), and Lei Wang(王磊). Chin. Phys. B, 2022, 31(2): 028103.
[4]	Microwave absorption properties regulation and bandwidth formula of oriented Y₂Fe₁₇N_3-δ@SiO₂/PU composite synthesized by reduction-diffusion method Hao Wang(王浩), Liang Qiao(乔亮), Zu-Ying Zheng(郑祖应), Hong-Bo Hao(郝宏波), Tao Wang(王涛), Zheng Yang(杨正), and Fa-Shen Li(李发伸). Chin. Phys. B, 2022, 31(11): 114206.
[5]	Lattice plasmon mode excitation via near-field coupling Yun Lin(林蕴), Shuo Shen(申烁), Xiang Gao(高祥), and Liancheng Wang(汪炼成). Chin. Phys. B, 2022, 31(1): 014214.
[6]	Effect of deposition temperature on SrFe₁₂O₁₉@carbonyl iron core-shell composites as high-performance microwave absorbers Yuan Liu(刘渊), Rong Li(李茸), Ying Jia(贾瑛), Zhen-Xin He(何祯鑫). Chin. Phys. B, 2020, 29(6): 067701.
[7]	High sensitive pressure sensors based on multiple coating technique Rizwan Zahoor, Chang Liu(刘畅), Muhammad Rizwan Anwar, Fu-Yan Lin(林付艳), An-Qi Hu(胡安琪), Xia Guo(郭霞). Chin. Phys. B, 2020, 29(2): 028102.
[8]	Reduced graphene oxide as saturable absorbers for erbium-doped passively mode-locked fiber laser Zhen-Dong Chen(陈振东), Yong-Gang Wang(王勇刚), Lu Li(李璐), Rui-Dong Lv(吕瑞东), Liang-Lei Wei(韦良雷), Si-Cong Liu(刘思聪), Jiang Wang(王江), Xi Wang(王茜). Chin. Phys. B, 2018, 27(8): 084206.
[9]	Free-standing, curled and partially reduced graphene oxide network as sulfur host for high-performance lithium-sulfur batteries Hui-Liang Chen(陈辉亮), Zhuo-Jian Xiao(肖卓建), Nan Zhang(张楠), Shi-Qi Xiao(肖仕奇), Xiao-Gang Xia(夏晓刚), Wei Xi(席薇), Yan-Chun Wang(王艳春), Wei-Ya Zhou(周维亚), Si-Shen Xie(解思深). Chin. Phys. B, 2018, 27(6): 068101.
[10]	Multiferroic and enhanced microwave absorption induced by complex oxide interfaces Cuimei Cao(曹翠梅), Chunhui Dong(董春晖), Jinli Yao(幺金丽), Changjun Jiang(蒋长军). Chin. Phys. B, 2018, 27(1): 017503.
[11]	Structural and optical properties of thermally reduced graphene oxide for energy devices Ayesha Jamil, Faiza Mustafa, Samia Aslam, Usman Arshad, Muhammad Ashfaq Ahmad. Chin. Phys. B, 2017, 26(8): 086501.
[12]	Graphene resistive random memory–the promising memory device in next generation Xue-Feng Wang(王雪峰), Hai-Ming Zhao(赵海明), Yi Yang(杨轶), Tian-Ling Ren(任天令). Chin. Phys. B, 2017, 26(3): 038501.
[13]	Microwave absorption properties of Ag naowires/carbon black composites Hai-Long Huang(黄海龙), Hui Xia(夏辉), Zhi-Bo Guo(郭智博), Yu Chen(陈羽), Hong-Jian Li(李宏建). Chin. Phys. B, 2017, 26(2): 025207.
[14]	Theoretical calculation and experiment of microwave electromagnetic property of Ni(C) nanocapsules Dan-Feng Zhang(张丹枫), Zhi-Feng Hao(郝志峰), Bi Zeng(曾碧), Yan-Nan Qian(钱艳楠), Ying-Xin Huang(黄颖欣), Zhen-Da Yang(杨振大). Chin. Phys. B, 2016, 25(4): 040201.
[15]	Second harmonic generation of metal nanoparticles under tightly focused illumination Jing-Wei Sun(孙经纬), Xiang-Hui Wang(王湘晖), Sheng-Jiang Chang(常胜江),Ming Zeng(曾明), Na Zhang(张娜). Chin. Phys. B, 2016, 25(3): 037803.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Metrics
Related Articles

Enhanced microwave absorption performance of MOF-derived hollow Zn-Co/C anchored on reduced graphene oxide

Cite this article:

Online attention