Thermal expansion properties of Lu2-x FexMo3O12

doi:10.1088/1674-1056/21/11/116102

Abstract Structures and thermal expansion properties of Lu_2-xFe_xMo₃O₁₂ have been investigated by X-ray diffraction (XRD). XRD patterns at room temperature indicate that compounds Lu_2-xFe_xMo₃O₁₂ with x≤ 1.3 exhibit orthorhombic structure with space group Pnca; compounds with x=1.5 and 1.7 have monoclinic structure with space group P2₁/a. Studies on thermal expansion properties show that the linear thermal expansion coefficients of orthorhombic phase vary from negative to positive with increasing Fe content. Attempts to make zero thermal expansion materials indicate that zero thermal expansion can be observed in Lu_1.3Fe_0.7Mo₃O₁₂ in the temperature range of 200-400 ℃.

Keywords: X-ray diffraction thermal expansion crystal structure

Received: 21 February 2012
Revised: 15 March 2012
Accepted manuscript online:

PACS:	61.05.cp	(X-ray diffraction)
	65.40.De	(Thermal expansion; thermomechanical effects)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 10905095, 11105159, and 11075220) and the National Basic Research Program of China (Grant No. 2010CB833101).

Corresponding Authors: Wu Mei-Mei
E-mail: mmwu@ciae.ac.cn

Cite this article:

Wu Mei-Mei (武梅梅), Peng Jie (彭杰), Zu Yong (祖勇), Liu Rong-Deng (刘荣灯), Hu Zhong-Bo (胡中波), Liu Yun-Tao (刘蕴韬), Chen Dong-Feng (陈东风 ) Thermal expansion properties of Lu_2-x Fe_xMo₃O₁₂ 2012 Chin. Phys. B 21 116102

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Thermal expansion properties of Lu_2-x Fe_xMo₃O₁₂