Flexible rGO/Fe3O4 NPs/polyurethane film with excellent electromagnetic properties

doi:10.1088/1674-1056/ab4041

Abstract Large-area and flexible reduced graphene oxide (rGO)/Fe₃O₄ NPs/polyurethane (PU) composite films are fabricated by a facile solution-processable method. The monolayer assembly of Fe₃O₄ nanoparticles with a high particle-stacking density on the graphene oxide (GO) sheets is achieved by mixing two immiscible solutions of Fe₃O₄ nanoparticles in hexane and GO in dimethylformide (DMF) by a mild sonication. The x-ray diffraction and Raman spectrum confirm the reduced process of rGO by a simple thermal treatment. The permittivity value of the composite in a frequency range of 0.1 GHz-18 GHz increases with annealing temperature of GO increasing. For 5-wt% rGO/Fe₃O₄ NPs/PU, the maximum refection loss (RL) of over -35 dB appears at 4.5 GHz when the thickness of film increases to 5 mm. The rGO/Fe₃O₄ NPs/PU film, exhibiting good electromagnetic properties over GHz frequency range, could be a potential candidate as one of microwave absorption materials in flexible electronic devices.

Keywords: graphene oxide magnetic nanoparticles flexible film electromagnetic properties

Received: 21 July 2019
Revised: 24 August 2019
Accepted manuscript online:

PACS:	81.05.ue	(Graphene)
	75.75.-c	(Magnetic properties of nanostructures)
	67.80.dm	(Films)
	92.60.Ta	(Electromagnetic wave propagation)

Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 11274370, 51471185, and 11704288) and the National Key Research and Development Program of China (Grant Nos. 2016YFJC020013 and 2018FYA0305800).

Corresponding Authors: Hong-Jun Xiao, Ge-Ming Wang
E-mail: xiaohj@nanoctr.cn;wanggemingwit@163.com

Cite this article:

Wei-Qi Yu(余维琪), Yi-Chen Qiu(邱怡宸), Hong-Jun Xiao(肖红君), Hai-Tao Yang(杨海涛), Ge-Ming Wang(王戈明) Flexible rGO/Fe₃O₄ NPs/polyurethane film with excellent electromagnetic properties 2019 Chin. Phys. B 28 108103

[1]	Kong L B, Li Z W, Liu L, Huang R, Abshinova M, Yang Z H, Tang C B, Tan P K, Deng C R and Matitsine S 2013 Int. Mater. Rev. 58 203
[2]	Chakraborty U, Chatterjee S, Chowdhury S K and Sarkar P P 2011 Prog. Electromagn. Res. C 18 211
[3]	Sun X, He J P, Li G X, Tang J, Wang T, Guo Y X and Xue H R 2013 J. Mater. Chem. C 1 765
[4]	Yang Z H, Li Z W, Yang Y H and Xu Z C 2014 ACS Appl. Mater. Interfaces 6 21911
[5]	Lv H L, Zhang H Q, Ji G G and Xu Z C 2016 ACS Appl. Mater. Interfaces 8 6529
[6]	Sebastian M T and Jantunen H 2008 Int. Mater. Rev. 53 57
[7]	Buerkle A, Sarabandi K and Mosallaei H 2005 IEEE Trans. Anten. Propag. 53 1020
[8]	Truong V T, Riddell S Z and Muscat R F 1998 J. Mater. Sci. 33 4971
[9]	Kim J, Khoh W H, Wee B H and Hong J D 2015 RSC Adv. 5 9904
[10]	Quan B, Shi W H, Ong S J H, Lu X C, Wang P L Y, Ji G B, Guo Y F, Zheng L R and Xu Z C 2019 Adv. Funct. Mater. 29 1901236
[11]	Li Q, Zhang Z, Qi L P, Liao Q L, Kang Z and Zhang Y 2019 Adv. Sci. 6 8
[12]	Zhang Y, Huang Y, Zhang T, Chang H, Xiao P, Chen H, Huang Z and Chen Y 2015 Adv. Mater. 27 2049
[13]	Chen D Z, Wang G S, He S, Liu J, Guo L and Cao M S 2013 J. Mater. Chem. A 1 5996
[14]	Wang T, Li Y, Wang, Liu L C, Geng S, Jia X, Yang F, Zhang L, Liu L, You B, Ren X and Yang H T 2015 RSC Adv. 5 60114
[15]	Zhang X J, Wang G S, Cao W Q, Wei Y Z, Cao M S and Guo L 2014 RSC Adv. 4 19594
[16]	Han M, Yin X, Kong L, Li M, Duan W, Zhang L and Cheng L 2014 J. Mater. Chem. A 2 16403
[17]	Huang J, Cheng S P, Chen Y X, Chen Z L, Luo H, Xia X H and Liu H B 2019 J. Mater. Chem. A 7 16720
[18]	Li C, Fu Y S, Wu Z, Xia J W and Wang X 2019 Nanoscale 11 12997
[19]	Li X, Lu S Y, Xiong Z G, Hu Y, Ma D, Lou W Q, Peng C, Shen M W and Shi X Y 2019 Adv. Sci. 08 August
[20]	Zhang L, Wan X N, Duan W J, Qiu H, Hou J Q, Wang X R, Li H and Du X Y 2019 J. Nanosci. Nanotechnol. 19 7664
[21]	Mahmudzadeh M, Yari H, Ramezanzadeh B and Mahdavian M 2019 J. Indus. Engi. Chem. 78 125
[22]	Pena-Bahamonde J, San-Miguel V, Baselga J, Fernandez-Blazquez J P, Gedler G, Ozisik R and Cabanelas J C 2019 Carbon 151 84
[23]	Song N N, Yang H T, Ren X, Li Z A, Luo Y, Shen J, Dai W, Zhang X Q and Cheng Z H 2013 Nanoscale 5 2804
[24]	Hummers W S and Offeman R E 1958 J. Am. Chem. Soc. 80 1339
[25]	Liang Y, Wu D, Feng X and Müllen K 2009 Adv. Mater. 21 1679
[26]	Guo S J and Sun S H 2012 J. Am. Chem. Soc. 134 2492
[27]	Ma R S, Huan Q, Wu L M, Yan J H, Zhang Y Y, Bao L H, Liu Y Q, Du S X and Gao H J 2017 Chin. Phys. B 26 066801
[28]	Guo H, Wang X Y, Bao D L, Lu H L, Zhang Y Y, Li G, Wang Y L, Du S X and Gao H J 2019 Chin. Phys. B 28 078103
[29]	Tung V C, Allen M J, Yang Y and Kaner R B 2009 Nat. Nano 4 25
[30]	Song N N, Yang H T, Liu H L, Ren X, Ding H F, Zhang X Q and Cheng Z H 2013 Sci. Rep. 3 3161
[31]	Naito Y and Suetake K 1971 IEEE Trans. Microwave Theory Tech. 19 65
[32]	Davalos A L and Zanette A 1999 Fundamentals of Electromagnetism
[33]	Kong L, Yin X, Zhang Y, Yuan X, Li Q, Ye F, Cheng L and Zhang L 2013 J. Phys. Chem. C 117 19701
[34]	Xue D S, Li F S, Fan X L and Wen F S 2008 Chin. Phys. Lett. 25 4128
[35]	Li X P, Deng Z M, Li Y, Zhang H B, Zhao S, Zhang Y, Wu X Y and Yu Z Z 2019 Carbon 147 172
[36]	Tang J M, Liang N, Wang L, Li J, Tian G, Zhang D, Feng S H and Yue H J 2019 Carbon 152 575

[1]	Adsorption dynamics of double-stranded DNA on a graphene oxide surface with both large unoxidized and oxidized regions Mengjiao Wu(吴梦娇), Huishu Ma(马慧姝), Haiping Fang(方海平), Li Yang(阳丽), and Xiaoling Lei(雷晓玲). Chin. Phys. B, 2023, 32(1): 018701.
[2]	Photoelectrochemical activity of ZnO:Ag/rGO photo-anodes synthesized by two-steps sol-gel method D Ben Jemia, M Karyaoui, M A Wederni, A Bardaoui, M V Martinez-Huerta, M Amlouk, and R Chtourou. Chin. Phys. B, 2022, 31(5): 058201.
[3]	Thermoelectric characteristics of flexible reduced graphene oxide/silver selenide nanowire composites prepared by a facile vacuum filtration process Zuo Xiao(肖佐), Yong Du(杜永), Qiufeng Meng(孟秋风), and Lei Wang(王磊). Chin. Phys. B, 2022, 31(2): 028103.
[4]	Enhanced microwave absorption performance of MOF-derived hollow Zn-Co/C anchored on reduced graphene oxide Yue Wang(王玥), Dawei He(何大伟), and Yongsheng Wang(王永生). Chin. Phys. B, 2021, 30(6): 067804.
[5]	Enhanced hyperthermia performance in hard-soft magnetic mixed Zn_0.5Co_xFe_2.5-xO₄/SiO₂ composite magnetic nanoparticles Xiang Yu(俞翔, Li-Chen Wang(王利晨, Zheng-Rui Li(李峥睿, Yan Mi(米岩), Di-An Wu(吴迪安), and Shu-Li He(贺淑莉). Chin. Phys. B, 2021, 30(3): 036201.
[6]	Effects of dipolar interactions on the magnetic hyperthermia of Zn_0.3Fe_2.7O₄ nanoparticles with different sizes Xiang Yu(俞翔), Yan Mi(米岩), Li-Chen Wang(王利晨), Zheng-Rui Li(李峥睿), Di-An Wu(吴迪安), Ruo-Shui Liu(刘若水), and Shu-Li He(贺淑莉). Chin. Phys. B, 2021, 30(1): 017503.
[7]	Functionalized magnetic nanoparticles for drug delivery in tumor therapy Ruo-Nan Li(李若男), Xian-Hong Da(达先鸿), Xiang Li (李翔), Yun-Shu Lu(陆云姝), Fen-Fen Gu(顾芬芬), and Yan Liu(刘艳). Chin. Phys. B, 2021, 30(1): 017502.
[8]	Effect of deposition temperature on SrFe₁₂O₁₉@carbonyl iron core-shell composites as high-performance microwave absorbers Yuan Liu(刘渊), Rong Li(李茸), Ying Jia(贾瑛), Zhen-Xin He(何祯鑫). Chin. Phys. B, 2020, 29(6): 067701.
[9]	Second harmonic magnetoacoustic responses of magnetic nanoparticles in magnetoacoustic tomography with magnetic induction Gepu Guo(郭各朴), Ya Gao(高雅), Yuzhi Li(李禹志), Qingyu Ma(马青玉), Juan Tu(屠娟), Dong Zhang(章东). Chin. Phys. B, 2020, 29(3): 034302.
[10]	High sensitive pressure sensors based on multiple coating technique Rizwan Zahoor, Chang Liu(刘畅), Muhammad Rizwan Anwar, Fu-Yan Lin(林付艳), An-Qi Hu(胡安琪), Xia Guo(郭霞). Chin. Phys. B, 2020, 29(2): 028102.
[11]	First-principles insight into Li and Na ion storage in graphene oxide Shu-Ying Zhong(钟淑英), Jing Shi(石晶), Wen-Wei Luo(罗文崴), Xue-Ling Lei(雷雪玲). Chin. Phys. B, 2019, 28(7): 078201.
[12]	Improved dielectric and electro-optical parameters of nematic liquid crystal doped with magnetic nanoparticles Geeta Yadav, Govind Pathak, Kaushlendra Agrahari, Mahendra Kumar, Mohd Sajid Khan, V S Chandel, Rajiv Manohar. Chin. Phys. B, 2019, 28(3): 034209.
[13]	Effect of particle size distribution on magnetic behavior of nanoparticles with uniaxial anisotropy S Rizwan Ali, Farah Naz, Humaira Akber, M Naeem, S Imran Ali, S Abdul Basit, M Sarim, Sadaf Qaseem. Chin. Phys. B, 2018, 27(9): 097503.
[14]	Reduced graphene oxide as saturable absorbers for erbium-doped passively mode-locked fiber laser Zhen-Dong Chen(陈振东), Yong-Gang Wang(王勇刚), Lu Li(李璐), Rui-Dong Lv(吕瑞东), Liang-Lei Wei(韦良雷), Si-Cong Liu(刘思聪), Jiang Wang(王江), Xi Wang(王茜). Chin. Phys. B, 2018, 27(8): 084206.
[15]	Free-standing, curled and partially reduced graphene oxide network as sulfur host for high-performance lithium-sulfur batteries Hui-Liang Chen(陈辉亮), Zhuo-Jian Xiao(肖卓建), Nan Zhang(张楠), Shi-Qi Xiao(肖仕奇), Xiao-Gang Xia(夏晓刚), Wei Xi(席薇), Yan-Chun Wang(王艳春), Wei-Ya Zhou(周维亚), Si-Shen Xie(解思深). Chin. Phys. B, 2018, 27(6): 068101.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Metrics
Related Articles

Flexible rGO/Fe3O4 NPs/polyurethane film with excellent electromagnetic properties

Cite this article:

Online attention

Flexible rGO/Fe₃O₄ NPs/polyurethane film with excellent electromagnetic properties