Please wait a minute...
Chin. Phys. B, 2012, Vol. 21(2): 027305    DOI: 10.1088/1674-1056/21/2/027305
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES Prev   Next  

A high mobility C60 field-effect transistor with an ultrathin pentacene passivation layer and bathophenanthroline/metal bilayer electrodes

Zhou Jian-Lin(周建林)a)b)†, Yu Jun-Sheng(于军胜)a)‡, Yu Xin-Ge(于欣格)a), and Cai Xin-Yang(蔡欣洋)a)
a. State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Optoelectronic Information, University of Electronic Science and Technology of China, Chengdu 610054, China;
b. Department of Electronic Engineering, College of Communication and Electronics, Chongqing University, Chongqing 400044, China
Abstract  C60 field-effect transistor (OFET) with a mobility as high as 5.17 cm2/V·s is fabricated. In our experiment, an ultrathin pentacene passivation layer on poly-(methyl methacrylate) (PMMA) insulator and a bathophenanthroline (Bphen)/Ag bilayer electrode are prepared. The OFET shows a significant enhancement of electron mobility compared with the corresponding device with a single PMMA insultor and an Ag electrode. By analysing the C60 film with atomic force microscopy and X-ray diffraction techniques, it is shown that the pentacene passivation layer can contribute to C60 film growth with the large grain size and significantly improve crystallinity. Moreover, the Bphen buffer layer can reduce the electron contact barrier from Ag electrodes to C60 film efficiently.
Keywords:  organic field-effect transistors      C60      Bphen      passivation layer  
Received:  24 July 2011      Revised:  03 November 2011      Accepted manuscript online: 
PACS:  73.61.Wp (Fullerenes and related materials)  
  85.30.Tv (Field effect devices)  
  88.30.rf (Organics)  
Fund: Project supported by the National Science Foundation for Post-Doctoral Scientists of China (Grant No. 20100471667), the Natural Science Foundation of Chongqing Science and Technology Commission (CQ CSTC) (Grant No. 2011jjA40020), the National Natural Science Foundation of China (Grant Nos. 60736005 and 61021061), and the Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education of China (Grant No. GGRYJJ08-05).
Corresponding Authors:  Zhou Jian-Lin,zjl4062002@163.com;Yu Jun-Sheng,jsyu@uestc.edu.cn     E-mail:  zjl4062002@163.com;jsyu@uestc.edu.cn

Cite this article: 

Zhou Jian-Lin(周建林), Yu Jun-Sheng(于军胜), Yu Xin-Ge(于欣格), and Cai Xin-Yang(蔡欣洋) A high mobility C60 field-effect transistor with an ultrathin pentacene passivation layer and bathophenanthroline/metal bilayer electrodes 2012 Chin. Phys. B 21 027305

[1] Sekitani T, Zschieschang U, Klauk H and Someya T 2010 Nat. Mater. 12 1015
[2] Guo Y L, Yu G and Liu Y Q 2010 Adv. Mater. 22 4427
[3] Hsu B B Y, Namdas E B, Yuen J D, Cho S, Samuel I D W and Heeger A J 2010 Adv. Mater. 22 4649
[4] Drury C J, Mutsaers C M J, Hart C M, Matters M and de Leeuw D M 1998 Appl. Phys. Lett. 73 108
[5] Crone B K, Dodabalapur A, Lin Y Y, Filas R W, Bao Z, laDuca A, Sarpeshkar R, Katz H E and Li W 2000 Nature 403 521
[6] Minari T, Nemoto T and Isoda S 2006 J. Appl. Phys. 99 034506
[7] Braga D, Campione M, Borghesi A and Horowitz G 2010 Adv. Mater. 22 424
[8] Zhou L, Wanga A, Wu S C, Sun J, Park S and Jackson T N 2006 Appl. Phys. Lett. 88 083502
[9] Kao C, Lin P, Lee C C, Wang Y K, Ho J C and Shen Y Y 2007 Appl. Phys. Lett. 91 212101
[10] Wang S D, Minari T, Miyadera T, Tsukagoshi K and Aoyagi Y 2007 Appl. Phys. Lett. 91 203508
[11] Liu Z H, Kobayashi M, Paul B C, Bao Z N and Nishil Y 2010 Phys. Rev. B 82 035311
[12] Horiuchi K, Nakada K, Uchino S, Hashii S, Hashimoto A, Aoki N, Ochiai N and Shimizu M 2002 Appl. Phys. Lett. 81 1911
[13] Zhang X H, Domercq B and Kippelen B 2007 Appl. Phys. Lett. 91 092114
[14] Ito Y, Virkar A A, Mannsfeld S, Oh J H, Toney M, Locklin J and Bao Z N 2009 J. Am. Chem. Soc. 131 9396
[15] Steudel S, Vusser S D, Jonge S D, Janssen D, Verlaak S, Genoe J and Heremans P 2004 Appl. Phys. Lett. 85 4400
[16] Kumaki D, Ando S, Shimono S, Yamashita Y, Umeda T and Tokito S 2007 Appl. Phys. Lett. 90 053506
[17] Tian X Y, Su L X, Zheng Z, Jiang F Z, Fu J J, Quan J C, Yu F X and Gong W 2011 Acta Phy. Sin. 60 027201 (in Chinese)
[18] Yu H Z, Zhou X M and Deng J Y 2011 Acta Phys. Sin. 60 077206 (in Chinese)
[19] Wei Z M, Hong W, Geng H, Wang C L, Liu Y L, Li R J, Xu W, Shuai Z G, Hu W P, Wang Q R and Zhu D B 2010 Adv. Mater. 22 1
[20] Kageyama H, Ohishi H, Tanaka M, Ohmori Y and Shirota Y 2009 Appl. Phys Lett. 94 063304
[21] Huang J, Yu J S, Guan Z Q and Jiang Y D 2010 Appl. Phys. Lett. 97 143301
[22] Wang N N, Yu J S, Zang Y, Huang J and Jiang Y D 2010 Sol. Energy Mater. Sol. Cells 94 263
[23] Eiji K, Haruka K, Takayuki N, Toshio T and Yoshihiro K 2005 Chem. Phys. Lett. 413 379
[24] Itaka K, Yamashiro M, Yamaguchi J, Haemori M, Yaginuma S, Matsumoto Y, Kondo M and Koinuma H 2006 Adv. Mater. 18 1713
[25] Shin K, Yang S Y, Yang C, Jeon H and Park C E 2007 Organic Electronics 8 336
[26] Kalb W, Lang P, Mottaghi M, Aubin H, Horowitz G and Wuttig M 2004 Synthetic Metals 146 279
[27] Sun Q J, Xu Z, Zhao S L, Zhang F J, Gao L Y and Wang Y S 2010 Synthetic Metals 160 2239
[28] Peumans P, Yakimov A and Forrest S R 2003 J. Appl. Phys. 93 3693
[29] Chen F C, Kung L J, Chen H T H and Lin Y S 2007 Appl. Phys. Lett. 90 073504
[1] Controllable preparation and disorder-dependent photoluminescence of morphologically different C60 microcrystals
Wen Cui(崔雯), De-Jun Li(李德军), Jin-Liang Guo(郭金良), Lang-Huan Zhao(赵琅嬛), Bing-Bing Liu(刘冰冰), and Shi-Shuai Sun(孙士帅). Chin. Phys. B, 2021, 30(8): 086101.
[2] Effect of C60 nanoparticles on elasticity of small unilamellar vesicles composed of DPPC bilayers
Tanlin Wei(魏坦琳), Lei Zhang(张蕾), Yong Zhang(张勇). Chin. Phys. B, 2020, 29(4): 048702.
[3] Thermodynamic and structural properties of polystyrene/C60 composites: A molecular dynamics study
Junsheng Yang(杨俊升), Ziliang Zhu(朱子亮), Duohui Huang(黄多辉), Qilong Cao(曹启龙). Chin. Phys. B, 2020, 29(2): 023104.
[4] High pressure and high temperature induced polymerization of C60 quantum dots
Shi-Hao Ruan(阮世豪), Chun-Miao Han(韩春淼), Fu-Lu Li(李福禄), Bing Li(李冰), Bing-Bing Liu(刘冰冰). Chin. Phys. B, 2020, 29(2): 026402.
[5] The effect of Mn-doped ZnSe passivation layer on the performance of CdS/CdSe quantum dot-sensitized solar cells
Yun-Long Deng(邓云龙), Zhi-Yuan Xu(徐知源), Kai Cai(蔡凯), Fei Ma(马飞), Juan Hou(侯娟), Shang-Long Peng(彭尚龙). Chin. Phys. B, 2019, 28(9): 098802.
[6] Hunting down the ohmic contact of organic field-effect transistor
M Micjan, M Novota, P Telek, M Donoval, M Weis. Chin. Phys. B, 2019, 28(11): 118501.
[7] Intermediate sp-hybridization for chemical bonds in nonplanar covalent molecules of carbon
Cao Ze-Xian (曹则贤). Chin. Phys. B, 2014, 23(6): 063102.
[8] In situ electrical resistance and activation energy of solid C60 under high pressure
Yang Jie (杨洁), Liu Cai-Long (刘才龙), Gao Chun-Xiao (高春晓). Chin. Phys. B, 2013, 22(9): 096202.
[9] Preferred orientations of encapsulated C60 molecules inside single wall carbon nanotubes
Yao Zhen (姚震), Liu Ran (刘然), Ma Feng-Xian (马凤仙), Lu Shuang-Chen (路双臣), Tian Fu-Bo (田夫波), Duan De-Fang (段德芳), Cui Tian (崔田), Liu Bing-Bing (刘冰冰). Chin. Phys. B, 2013, 22(7): 076101.
[10] Structural modification of C60 films induced by 300-keV Xe-ion irradiation
Yao Cun-Feng (姚存峰), Jin Yun-Fan(金运范), Wang Zhi-Guang(王志光), Pang Li-Long(庞立龙), Shen Tie-Long(申铁龙), and Zhu Ya-Bin(朱亚滨). Chin. Phys. B, 2011, 20(7): 076105.
[11] Properties of C60 thin film transistor based on polystyrene
Zhou Jian-Lin (周建林), Niu Qiao-Li (牛巧利). Chin. Phys. B, 2010, 19(7): 077305.
[12] The density functional calculations on the structural and electronic properties of the endohedral fullerene dimer (N2@C60)2
Gao Hong(高虹), Zhu Wei-Hua(朱卫华), Tang Chun-Mei(唐春梅), Geng Fang-Fang(耿芳芳), Yao Chang-Da(姚长达), Xu Yun-Ling(徐云玲), and Deng Kai-Ming(邓开明). Chin. Phys. B, 2010, 19(11): 113602.
[13] Thickness dependence of surface morphology and charge carrier mobility in organic field-effect transistors
Tian Xue-Yan(田雪雁), Xu Zheng(徐征), Zhao Su-Ling(赵谡玲), Zhang Fu-Jun(张福俊), Yuan Guang-Cai(袁广才),Li Jing(李婧), Sun Qin-Jun(孙钦军),Wang Yun(王赟), and Xu Xu-Rong(徐叙瑢). Chin. Phys. B, 2010, 19(1): 018103.
[14] Nucleation of diamond on silicon wafers using C60 in the hot filament chemical vapour deposition system
Fei Yun-Jie (费允杰), Wang Xue (王学), Wang Xue-Jin(王学进), Zhou Yu-Qing (周玉清), Xiong Yan-Yun (熊艳云), Feng Ke-An (冯克安). Chin. Phys. B, 2002, 11(3): 298-301.
[15] ELECTRICAL PROPERTIES, EQUATIONS OF STATE AND PHASE TRANSITION IN SOLID C60 AT HIGH PRESSURE
Bao Zhong-xing (鲍忠兴), V. H. Schmidt , N. S. Dalal , C. S. Tu , N. J. Pinto, Liu Cui-xia(柳翠霞), Li Yu-liang(李玉良), Zhu Dao-ben(朱道本). Chin. Phys. B, 2000, 9(9): 676-679.
No Suggested Reading articles found!