|
The second dissociation threshold bound levels of hydrogen molecule
Zhang Yan-Peng(张彦鹏), Song Jian-Ping(宋建平), Gan Chen-Li(甘琛利), Yan Xiang-An(严祥安), Nie Zhi-Qiang(聂志强), Jiang Tong(姜彤), Li Ling(李岭), Du Kai(杜凯), Zhang Xiang-Chen(张相臣), Lu Ke-Qing(卢克清), and E.E. Eyler
Chinese Physics, 2006, 15 (10):
2288-2296.
DOI: 10.1088/1009-1963/15/10/017
The near-threshold highly bound states of all three stable isotopic variants of molecular hydrogen have been studied. Numerous perturbations and unexpected transitions are observed as far as 1cm-1 just below the second dissociation threshold. This complex structure may arise from a combination of nonadiabatic coupling between B, B', C electronic states, perturbations due to fine and hyperfine interactions, and strong shape resonances. The perturbed near-threshold states and vibrational continuum exhibit finegrained structure, differing greatly between isotopes because of varying nonadiabatic coupling.
|