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Chin. Phys. B, 2017, Vol. 26(6): 068202    DOI: 10.1088/1674-1056/26/6/068202
INTERDISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY Prev   Next  

Synthesis and characterization of NaAlSi2O6 jadeite under 3.5 GPa

Gang Li(李刚), Jian Wang(王健), Ya-Dong Li(李亚东), Ning Chen(陈宁), Liang-Chao Chen(陈良超), Long-Suo Guo(郭龙锁), Liang Zhao(赵亮), Xin-Yuan Miao(苗辛原), Hong-An Ma(马红安), Xiao-Peng Jia(贾晓鹏)
National Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China
Abstract  The high pressure and high temperature (HPHT) method is successfully used to synthesize jadeite in a temperature range of 1000℃-1400℃ under a pressure of 3.5 GPa. The initial raw materials are Na2SiO3·9H2O and Al2(SiO3)3. Through the HPHT method, the amorphous glass material is entirely converted into crystalline jadeite. We can obtain the good-quality jadeite by optimizing the reaction pressure and temperature. The measurements of x-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) and Raman scattering indicate that the properties of synthesized jadeite at 1260℃ under 3.5 GPa are extremely similar to those of the natural jadeite. What is more, the results will be valuable for understanding the formation process of natural jadeite. This work also reveals the mechanism for metamorphism of magma in the earth.
Keywords:  synthetic jadeite      structural properties      HPHT  
Received:  02 January 2017      Revised:  16 February 2017      Accepted manuscript online: 
PACS:  82.75.Fq (Synthesis, structure determination, structure modeling)  
  91.60.-x (Physical properties of rocks and minerals)  
  62.50.-p (High-pressure effects in solids and liquids)  
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51172089 and 51171070) and the Graduate Innovation Fund of Jilin University, China (Grant No. 2016065).
Corresponding Authors:  Hong-An Ma, Xiao-Peng Jia     E-mail:  maha@jlu.edu.cn;jiaxp@jlu.edu.cn

Cite this article: 

Gang Li(李刚), Jian Wang(王健), Ya-Dong Li(李亚东), Ning Chen(陈宁), Liang-Chao Chen(陈良超), Long-Suo Guo(郭龙锁), Liang Zhao(赵亮), Xin-Yuan Miao(苗辛原), Hong-An Ma(马红安), Xiao-Peng Jia(贾晓鹏) Synthesis and characterization of NaAlSi2O6 jadeite under 3.5 GPa 2017 Chin. Phys. B 26 068202

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