a Key Laboratory of Photoelectronic Materials, Ningbo University, Ningbo 315211, China; b Ningbo Institute of Materials Technology and Engineering, the Chinese Academy of Sciences, Ningbo 315211, China; c Department of Physics, Dalian Maritime University, Dalian 116026, China
Abstract Ho3+/Yb3+ co-doped LiYF4 single crystals with various Yb3+ concentrations and ～ 0.98 mol% Ho3+ concentration are grown by the Bridgman method under the conditions of taking LiF and YF3 as raw materials and a temperature gradient (40 ℃/cm–50 ℃/cm) for the solid–liquid interface. The luminescent performances of the crystals are investigated through emission spectra, infrared transmittance spectrum, emission cross section, and decay curves under excitation by 980 nm. Compared with the Ho3+ single-doped LiYF4 crystal, the Ho3+/Yb3+ co-doped LiYF4 single crystal has an obviously enhanced emission band from 1850 nm to 2150 nm observed when excited by a 980-nm diode laser. The energy transfer from Yb3+ to Ho3+ and the optimum fluorescence emission around 2.0 μm of Ho3+ ions are investigated. The maximum emission cross section of the above sample at 2.0 μm is calculated to be 1.08× 10-20 cm2 for the LiYF4 single crystal of 1-mol% Ho3+ and 6-mol% Yb3+ according to the measured absorption spectrum. The high energy transfer efficiency of 88.9% from Yb3+ to Ho3+ ion in the sample co-doped by Ho3+ (1 mol%) and Yb3+ (8 mol%) demonstrates that the Yb3+ ions can efficiently sensitize the Ho3+ ions.
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51472125 and 51272109 ) and the K.C. Wong Magna Fund in Ningbo University, China (Grant No. NBUWC001).
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