Investigation of energy transfer from pyrromethene dye to cresyl violet 670 in ethanol

doi:10.1088/1674-1056/22/12/123402

Abstract In this paper, radiative and nonradiative energy transfer from laser dye pyrromethene 567 (PM567) and pyrromethene 580 (PM580) as donors to cresyl violet 670 (CV670) as acceptor in ethanol are investigated by using the steady-state emission measurement and the second harmonic generation (532 nm, ～ 13 ns) of a Q-switched Nd:YAG laser as the pumping source. The fluorescence intensity of the acceptor is improved due to the introduction of the donors, and the largest enhancement is obtained to be 128% in the PM567:CV670 dye mixture system. Energy transfer parameters, including the radiative and nonradiative energy transfer rate constants (K_R and K_NR), critical distance (R₀), and half quenching concentration ([A]_1/2) are investigated using the Stern–Volmer plots, and the acceptor concentration dependencies of radiative and nonradiative transfer efficiencies are also obtained. The values of K_R for PM567:CV670 and PM580:CV670 systems are 2032.0×10⁹ L·mol^-1·s^-1 and 2790.4×10⁹ L·mol^-1·s^-1, respectively, and the values of corresponding K_NR are 3.3×10⁹ L·mol^-1·s^-1 and 4.2×10⁹ L·mol^-1·s^-1, respectively. The results indicate that the dominant mechanism responsible for the energy transfer in the dye mixture systems is of the radiative type.

Keywords: energy transfer dye mixture Stern– Volmer plot steady-state emission

Received: 27 February 2013
Revised: 21 May 2013
Accepted manuscript online:

PACS:	34.50.Ez	(Rotational and vibrational energy transfer)
	33.50.-j	(Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion))
	42.55.Mv	(Dye lasers)

Fund: Project supported by the National Natural Science Foundation of China (Grant No. 61275127).

Corresponding Authors: Li Xiao-Hui, Chen De-Ying
E-mail: lixiaohuihit@163.com;dychen@hit.edu.cn

Cite this article:

Li Xiao-Hui (李晓晖), Fan Rong-Wei (樊荣伟), Yu Xin (于欣), Chen De-Ying (陈德应) Investigation of energy transfer from pyrromethene dye to cresyl violet 670 in ethanol 2013 Chin. Phys. B 22 123402

[1]	Urisu T and Kajiyama K 1976 J. Appl. Phys. 47 3563
[2]	Ali M and Ahmed S 1989 J. Chem. Phys. 90 1484
[3]	Taneja L, Sharma A and Singh R 1994 Opt. Commun. 111 463
[4]	Azim S A, Ghazy R, Shaheen M and El-Mekawey F 2000 J. Photoch. Photobio. A 133 185
[5]	Kumar G A and Unnikrishnan N V 2001 J. Photoch. Photobio. A 144 107
[6]	Kumar G A, Thomas V, Jose G, Unnikrishnan N V and Nampoori V P N 2002 J. Photoch. Photobio. A 153 145
[7]	Sahare P D, Sharma V K, Mohan D and Rupasov A A 2008 Spectrochim. Acta A 69 1257
[8]	Nhung T H, Canva M, Chaput F, Goudket H, Roger G, Brun A, Manh D D, Hung N D and Boilot J P 2004 Opt. Commun. 232 343
[9]	Yang Y, Lin G, Zou J, Wang Z, Wang M and Qian G 2007 Opt. Commun. 277 138
[10]	Ghazy R, Zim S A, Shaheen M and El-Mekawey F 2002 Opt. Laser Technol. 34 99
[11]	Ghazy R, Zim S, Shaheen M and El-Mekawey F 2004 Opt. Laser Technol. 36 463
[12]	Alvarez M, Amat-Guerri F, Costela A, Garcia-Moreno I, Liras M and Sastre R 2006 Opt. Commun. 267 469
[13]	Sailaja R and Bisht P B 2007 Org. Electron. 8 175
[14]	Xu D, Ye L, Xi J, Li L and Wang Q 2008 Acta Phys. Sin. 57 3267 (in Chinese)
[15]	Wu C, Liu P, Hou L and Li Y 2008 Acta Phys. Sin. 57 7317 (in Chinese)
[16]	Saito Y, Shimodaira K, Nomura A and Kano T 1995 Appl. Opt. 34 432
[17]	Ahamed M B, Ramalingam A and Palanisamy P K 2003 J. Lumin. 105 9
[18]	Lin C and Dienes A 1973 J. Appl. Phys. 44 5050
[19]	Oh C H and Hwang I H 1990 J. Appl. Phys. 67 1602
[20]	Dai G, Li H, Pan Y, Dai X and Xie Q 2005 Chin. Phys. 14 2590
[21]	Pavlopoulos T G, Shah M and Boyer J H 1989 Opt. Commun. 70 425
[22]	Hermes R E, Allik T H, Chandra S and Hutchinson J A 1993 Appl. Phys. Lett. 63 877
[23]	Ahmad M, Rahn M D and King T A 1999 Appl. Opt. 38 6337
[24]	Costela A, Garcia-Moreno I, Gomez C, Garcia O and Sastre R 2003 Chem. Phys. Lett. 369 656

[1]	How graph features decipher the soot assisted pigmental energy transport in leaves? A laser-assisted thermal lens study in nanobiophotonics S Sankararaman. Chin. Phys. B, 2022, 31(8): 088201.
[2]	Luminescent characteristics of Tm³⁺/Tb³⁺/Eu³⁺ tri-doped Na₅Y₉F₃₂ single crystals for white emission with high thermal stability Lizhi Fang(方立志), Xiong Zhou(周雄), Zhiwei Zhao(赵志伟), Biao Zheng(郑标), Haiping Xia(夏海平), Jun Wang(王军), Hongwei Song(宋宏伟), and Baojiu Chen(陈宝玖). Chin. Phys. B, 2022, 31(12): 127802.
[3]	Investigation of fluorescence resonance energy transfer ultrafast dynamics in electrostatically repulsed and attracted exciton-plasmon systems Hong-Yu Tu(屠宏宇), Ji-Chao Cheng(程基超), Gen-Cai Pan(潘根才), Lu Han(韩露), Bin Duan(段彬), Hai-Yu Wang(王海宇), Qi-Dai Chen(陈岐岱), Shu-Ping Xu(徐抒平), Zhen-Wen Dai(戴振文), and Ling-Yun Pan(潘凌云). Chin. Phys. B, 2021, 30(2): 027802.
[4]	Tuning energy transfer efficiency in quantum dots mixture by controling donor/acceptor ratio Chang Liu(刘畅), Jing Liang(梁晶), Fangfang Wang(王芳芳), Chaojie Ma(马超杰), Kehai Liu(刘科海), Can Liu(刘灿), Hao Hong(洪浩), Huaibin Shen(申怀彬), Kaihui Liu(刘开辉), and Enge Wang(王恩哥). Chin. Phys. B, 2021, 30(12): 127802.
[5]	The effects of Er^{3 +} ion concentration on 2.0-μ m emission performance in Ho^{3 +}/Tm^{3 +} co-doped Na₅Y₉F₃₂ single crystal under 800-nm excitation Benli Ding(丁本利), Xiong Zhou(周雄), Jianli Zhang(章践立), Haiping Xia(夏海平), Hongwei Song(宋宏伟), and Baojiu Chen(陈宝玖). Chin. Phys. B, 2021, 30(1): 017801.
[6]	Energy transfer, luminescence properties, and thermal stability of color tunable barium pyrophosphate phosphors Meng-Jiao Xu(徐梦姣), Su-Xia Li(李素霞), Chen-Chen Ji(季辰辰), Wan-Xia Luo(雒晚霞), Lu-Xiang Wang(王鲁香). Chin. Phys. B, 2020, 29(6): 063301.
[7]	Substitution priority of Eu²⁺ in multi-cation compound Sr_0.8Ca_0.2Al₂Si₂O₈ and energy transfer Zhi-Ping Yang(杨志平), Zhen-Ling Li(李振玲), Zhi-Jun Wang(王志军), Pan-Lai Li(李盼来), Miao-Miao Tian(田苗苗), Jin-Ge Cheng(程金阁), Chao Wang(王超). Chin. Phys. B, 2018, 27(1): 017802.
[8]	Vibration-assisted coherent excitation energy transfer in a detuned dimer Xin Wang(王信), Hao Chen(陈浩), Chen-yu Li(李晨宇), Hong-rong Li(李宏荣). Chin. Phys. B, 2017, 26(3): 037105.
[9]	Phonon-assisted excitation energy transfer in photosynthetic systems Hao Chen(陈浩), Xin Wang(王信), Ai-Ping Fang(方爱平), Hong-Rong Li(李宏荣). Chin. Phys. B, 2016, 25(9): 098201.
[10]	2.0-μm emission and energy transfer of Ho³⁺/Yb³⁺ co-doped LiYF₄ single crystal excited by 980 nm Yang Shuo (杨硕), Xia Hai-Ping (夏海平), Jiang Yong-Zhang (姜永章), Zhang Jia-Zhong (张加忠), Jiang Dong-Sheng (江东升), Wang Cheng (王成), Feng Zhi-Gang (冯治刚), Zhang Jian (张健), Gu Xue-Mei (谷雪梅), Zhang Jian-Li (章践立), Jiang Hao-Chuan (江浩川), Chen Bao-Jiu (陈宝玖). Chin. Phys. B, 2015, 24(6): 067802.
[11]	Energy transfer ultraviolet photodetector with 8-hydroxyquinoline derivative-metal complexes as acceptors Wu Shuang-Hong (吴双红), Li Wen-Lian (李文连), Chen Zhi (陈志), Li Shi-Bin (李世彬), Wang Xiao-Hui (王晓晖), Wei Xiong-Bang (魏雄邦). Chin. Phys. B, 2015, 24(2): 028505.
[12]	Concentration effect of the near-infrared quantum cutting of 1788-nm luminescence of Tm³⁺ ion in (Y_1-xTm_x)₃Al₅O₁₂ powder phosphor Chen Xiao-Bo (陈晓波), Li Song (李崧), Ding Xian-Lin (丁贤林), Yang Xiao-Dong (杨小冬), Liu Quan-Lin (刘泉林), Gao Yan (高燕), Sun Ping (孙萍), Yang Guo-Jian (杨国建). Chin. Phys. B, 2014, 23(8): 087809.
[13]	Photoluminescence properties and energy transfer in Y₂O₃：Eu³⁺ nanophosphors Cui Hang (崔航), Zhu Pei-Fen (朱培芬), Zhu Hong-Yang (祝洪洋), Li Hong-Dong (李红东), Cui Qi-Liang (崔啟良). Chin. Phys. B, 2014, 23(5): 057801.
[14]	Spectroscopic properties and mechanism of Tm³⁺/Er³⁺/Yb³⁺ co-doped oxyfluorogermanate glass ceramics containing BaF₂ nanocrystals Hu Yue-Bo (胡曰博), Qiu Jian-Bei (邱建备), Zhou Da-Cheng (周大成), Song Zhi-Guo (宋志国), Yang Zheng-Wen (杨正文), Wang Rong-Fei (王荣飞), Jiao Qing (焦清), Zhou Da-Li (周大利). Chin. Phys. B, 2014, 23(2): 024205.
[15]	A novel strong green phosphor：K₃Gd(PO₄)₂：Ce³⁺, Tb³⁺ for a UV-excited white light-emitting-diode Jiang Ting-Ming (姜庭明), Yu Xue (余雪), Xu Xu-Hui (徐旭辉), Zhou Da-Cheng (周大成), Yu Hong-Ling (余红玲), Yang Peng-Hui (杨鹏辉), Qiu Jian-Bei (邱建备). Chin. Phys. B, 2014, 23(2): 028505.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Metrics
Related Articles

Investigation of energy transfer from pyrromethene dye to cresyl violet 670 in ethanol

Cite this article:

Online attention