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Chinese Physics, 2007, Vol. 16(11): 3319-3322    DOI: 10.1088/1009-1963/16/11/029
ATOMIC AND MOLECULAR PHYSICS Prev   Next  

Collision-induced absorption in the v2 fundamental band of 12CH4

Yang Ze-Jin(杨则金), Cheng Xin-Lu(程新路), and Yang Xiang-Dong(杨向东)
Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China
Abstract  The integrated intensities of the collision-induced absorption of the $\nu _{2}$ band of $^{12}$CH$_{4}$ perturbed by Ar have been calculated  theoretically using the ab initio calculations, and the value of the quadrupole transition moment we obtained is $\langle {0| Q |\nu _2 } \rangle  =5.226ea_0^2 $. The corresponding experimental value obtained from $^{12}$CH$_{4}$--Ar spectra is $| {\langle {0| Q |\nu _2 } \rangle } |=4.931ea_0^2 $. Ignoring vibration--rotation interaction and Coriolis interaction, and considering both the theoretical approximations and experimental uncertainties, the agreement can be regarded as good, thus confirming that the enhancement is due to the quadrupole collision-induced mechanism. 
Keywords:  collision-induced absorption      $\nu_2$ fundamental band      quadrupole transition moment  
Accepted manuscript online: 
PACS:  31.15.A- (Ab initio calculations)  
  33.15.Kr (Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility)  
  33.20.Vq (Vibration-rotation analysis)  
  34.50.-s (Scattering of atoms and molecules)  

Cite this article: 

Yang Ze-Jin(杨则金), Cheng Xin-Lu(程新路), and Yang Xiang-Dong(杨向东) Collision-induced absorption in the v2 fundamental band of 12CH4 2007 Chinese Physics 16 3319

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