Abstract Based on the independent-particle-approximation and the multiple-scattering self-consistent-field theory, we have systematically calculated the electronic struc-tures of sodium molecular Rydberg series, analysed the quantum defect $\mu$ and the electronic-vibrational interaction (i.e. d$\mu$ /dR). The influences of double excitation configuration on the Rydberg series have been discussed. The electronic structures of Rydberg states and related dynamic behavior in a sodium molecule have been eluci-dated. Our theoretical results are in fair agreement with the available experimental measurements.
Received: 01 July 1992
Accepted manuscript online:
Fund: Project supported by the National Natural Science Foundation of China, Chinese Academy of Sciences LMTZ-1298 and Chinese Association for Atomic and Molecular Data.
Cite this article:
PAN YONG-LE (潘永乐), FAN ZHUANG (范戆), LI JIA-MING (李家明) MULTIPLE-SCATTERING THEORETICAL CALCULATIONS AND ANALYSIS FOR THE ELECTRONIC STRUCTRURES OF RYDBERG STATES IN A SODIUM MOLECULE 1993 Acta Physica Sinica (Overseas Edition) 2 500
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