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Chin. Phys. B, 2018, Vol. 27(10): 107702    DOI: 10.1088/1674-1056/27/10/107702

Low-temperature green synthesis of boron carbide using aloe vera

H V SarithaDevi1, M S Swapna1, G Ambadas2, S Sankararaman1
1 Department of Optoelectronics and Department of Nanoscience and Nanotechnology, University of Kerala, Kariavattom, Thiruvananthapuram-695581, Kerala, India;
2 Government Victoria College, Palakkad, Kerala, India

The unique structural and physical properties of boron carbide, which make it suitable for a wide range of applications, demands the development of low-cost and green synthesis method. In the present work, the commonly available leaves of aloe vera are hydrothermally treated to form the carbon precursor for the synthesis of boron carbide. The morphological characterization reveals the porous nature of the precursor turning into a tubular structure upon boron carbide formation. The structural characterization by x-ray diffraction and other spectroscopic techniques such as Fourier transform infrared, Raman, photoluminescence and uv-visible near-infrared spectroscopy confirm the formation of boron carbide. The thermogravimetric analysis of the sample is found to exhibit good thermal stability above 500℃. When the sample is annealed to 600℃, boron carbide with phase purity is obtained, which is confirmed through XRD and FTIR analyses. The optical emission properties of the sample are studied through CIE plot and power spectrum. Compared with other natural precursors for boron carbide, the aloe vera is found to give a good yield above 50%.

Keywords:  aloe vera      boric acid      boron carbide      hydrothermal method  
Received:  07 June 2018      Revised:  15 July 2018      Accepted manuscript online: 
PACS:  77.84.Bw (Elements, oxides, nitrides, borides, carbides, chalcogenides, etc.)  
  81.05.Je (Ceramics and refractories (including borides, carbides, hydrides, nitrides, oxides, and silicides))  
  81.05.Rm (Porous materials; granular materials)  
  81.05.U- (Carbon/carbon-based materials)  
Corresponding Authors:  G Ambadas, S Sankararaman     E-mail:;

Cite this article: 

H V SarithaDevi, M S Swapna, G Ambadas, S Sankararaman Low-temperature green synthesis of boron carbide using aloe vera 2018 Chin. Phys. B 27 107702

[1] Kosolopova T Y 1971 Carbides:Properties, Production and Applications (NewYork:Plenum Press)
[2] Pierson H O 1996 Handbook of refractory carbides and nitrides:Properties, Characteristics, Processing and Applications (USA:Noyes Publications)
[3] Avciata O, Ergun C, Erden I, Ustundag C, Yilmaz S and Cihangir S 2008 ICC2 Proceedings on Global Roadmap for Ceramics, Verona
[4] Mondal S and Banthia A K 2005 J. Eur. Ceram. Soc. 25 287
[5] Sun J, Ling H, Pan W J, Xu N, Ying Z F, Shen W D and Wu J D 2004 TriBiology Letters 17 99
[6] Sariyer D, Kucer R and Kucer N 2015 Procedia Soc. Behavioral Sci. 195 1752
[7] Kakiage M, Tahara N, Yanase I and Kobayashi H 2011 Mater. Lett. 65 1839
[8] Tallant D R, Aselage T L, Campbell A N and Emin D 1989 Phys. Rev. B 40 5649
[9] Ektarawong A, Simak S I and Alling B 2016 Phys. Rev. B 94 054104
[10] Yanase I, Ogawara R and Kobayashi H 2009 Mater. Lett. 63 91
[11] Swapna M S, Saritha Devi H V, Riya S, Ambadas G and Sankararaman S 2017 Mater. Res. Express 4 125602
[12] Hamman J H 2008 Molecules 13 1599
[13] Karnan M, Subramani K, Sudhan N, Ilayaraja N and Sathish M 2016 Appl. Mater. Interfaces 8 35191
[14] Cheng S, Panthapulakkal S, Sain M and Asiri A 2014 J. Appl. Polym. Sci. 131 40592
[15] Pinkowska H, Wolak P and Zlocinska A 2012 Chem. Eng. J. 187 410
[16] Saritha Devi H V, Swapna M S, Vimal R, Ambadas G and Sankararaman S 2018 Mater. Res. Express 5 015603
[17] Saritha Devi H V, Swapna M S, Ambadas G and Sankararaman S 2018 Appl. Phys. A 124 297
[18] Romanos J, Beckner M, Stalla D, Tekeei A, Suppes G, Jalisatgi S, Lee M, Hawthorne F, Robrtson J D, Firlej L, Kuchta B, Wexler C, Yu P and Pfeifer P 2013 Carbon 54 208
[19] Fan M, Dai D and Huang B 2012 Fourier transform infrared spectroscopy for natural fibers, Mohammed S ed., Chapter 3 in Fourier Transform-Materials Analysis, INTECH 45
[20] Mortensen M W, Sorensen P G, Bjorkdahl O, Jensen M R, Gundersen H J G and Bjornholm T 2006 Appl. Radiat. Isot. 64 315
[21] Zhuang D W, Dai H B and Wang P 2013 RSC Adv. 3 23810
[22] Domnich V, Reynaud S, Haber R A and Chhowalla M 2011 J. Am. Ceram. Soc. 94 3605
[23] Zorzi J E, Perottoni C A and Jornada J A H D 2005 Mater. Lett. 59 2932
[24] Wang J Z, He Y, Xie Z F, Chen C L, Yang Q B, Zhang C L, Wang B Y, Zhan Y Q and Zhao T H 2017 Polym. Adv. Technol. 29 757
[25] Ahmed M Z, El-Sheikh M, Ewais M M, Abd-Allah A and Sayed A 2017 JMEPEG 26 1444
[26] Yan X Q, Li W J, Goto T and Chen M W 2006 Appl. Phy. Lett. 88 131905
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