A-site ordered quadruple perovskite oxides AA3'B4O12

doi:10.1088/1674-1056/25/7/078108

Abstract

The A-site ordered perovskite oxides with chemical formula AA₃'B₄O₁₂ display many intriguing physical properties due to the introduction of transition metals at both A' and B sites. Here, research on the recently discovered intermetallic charge transfer occurring between A'-site Cu and B-site Fe ions in LaCu₃Fe₄O₁₂ and its analogues is reviewed, along with work on the magnetoelectric multiferroicity observed in LaMn₃Cr₄O₁₂ with cubic perovskite structure. The Cu-Fe intermetallic charge transfer (LaCuLaCu₃³⁺Fe₄³⁺O₁₂→LaCu₃²⁺Fe₄^3.75+O₁₂) leads to a first-order isostructural phase transition accompanied by drastic variations in magnetism and electrical transport properties. The LaMn₃Cr₄O₁₂ is a novel spindriven multiferroic system with strong magnetoelectric coupling effects. The compound is the first example of cubic perovskite multiferroics to be found. It opens up a new arena for studying unexpected multiferroic mechanisms.

Keywords: high-pressure synthesis A-site ordered perovskite charge transfer multiferroicity

Received: 18 August 2015
Revised: 30 September 2015
Accepted manuscript online:

PACS:	81.40.Vw	(Pressure treatment)
	71.27.+a	(Strongly correlated electron systems; heavy fermions)
	75.30.-m	(Intrinsic properties of magnetically ordered materials)
	77.84.-s	(Dielectric, piezoelectric, ferroelectric, and antiferroelectric materials)

Fund:

Project supported by the National Basic Research Program of China (Grant No. 2014CB921500), the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB07030300), and the National Natural Science Foundation of China (Grant No. 11574378).

Corresponding Authors: Youwen Long
E-mail: ywlong@iphy.ac.cn

Cite this article:

Youwen Long(龙有文) A-site ordered quadruple perovskite oxides AA₃'B₄O₁₂ 2016 Chin. Phys. B 25 078108

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A-site ordered quadruple perovskite oxides AA3'B4O12

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A-site ordered quadruple perovskite oxides AA₃'B₄O₁₂