Measurement scheme to detect α relaxation time of glass-forming liquid

doi:10.1088/1674-1056/28/8/086601

Abstract A measurement scheme for detecting the α relaxation time (τ) of glass-forming liquid is proposed, which is based on the measured ionic conductivity of the liquid doped with probing ions by low- and middle-frequency dielectric spectroscopy and according to the Nernst-Einstein, Stokes-Einstein, and Maxwell equations. The obtained τ values of glycerol and propylene carbonate by the scheme are consistent with those obtained by traditional dielectric spectroscopy, which confirms its reliability and accuracy. Moreover, the τ of 1,2-propanediol in a larger temperature range is compared with existing data.

Keywords: α relaxation ionic conductivity glass-forming liquid dielectric spectroscopy

Received: 25 April 2019
Revised: 18 May 2019
Accepted manuscript online:

PACS:	66.10.-x	(Diffusion and ionic conduction in liquids)
	77.22.Gm	(Dielectric loss and relaxation)
	64.70.P-	(Glass transitions of specific systems)
	82.56.Na	(Relaxation)

Fund: Project supported by the National Natural Science Foundation of China (Grant No. 11664042).

Corresponding Authors: Yi-Neng Huang
E-mail: ynhuang@nju.edu.cn

Cite this article:

Xing-Yu Zhao(赵兴宇), Li-Na Wang(王丽娜), Hong-Mei Yin(尹红梅), Heng-Wei Zhou(周恒为), Yi-Neng Huang(黄以能) Measurement scheme to detect α relaxation time of glass-forming liquid 2019 Chin. Phys. B 28 086601

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