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Structure, conductivity, and ion emission properties of RbAg4I5 solid electrolyte film prepared by pulsed laser deposition |
| Jun-Lian Chen(陈军联)1,2, Wen-Bin Zuo(左文彬)2, Xian-Wen Ke(柯贤文)1, Alexander B Tolstoguzov3, Can-Xin Tian(田灿鑫)4, Neena Devi1,5, Ranjana Jha5, Gennady N Panin6, De-Jun Fu(付德君)2 |
1 School of Printing and Packaging, Wuhan University, Wuhan 430072, China;
2 Shenzhen Institute of Wuhan University, A302 Research Bldg., No.6 Aoxin 2nd Rd., Nanshan Hitech Zone, Shenzhen 518057, China;
3 Ryazan State Radio Engineering University, Gagarin Str. 59/1, 390005 Ryazan, Russia;
4 School of Physics and Technology, Lingnan Normal University, Zhanjiang 524048, China;
5 Department of Physics, Netaji Subhas Institute of Technology, University of Delhi, Dwarka Sector-3, New Delhi 110078, India;
6 Institute of Microelectronics Technology, Russian Academy of Sciences, Chernogolovka, Moscow 142432, Russia |
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Abstract We fabricated a silver ion emitter based on the solid state electrolyte film of RbAg4I5 prepared by pulsed laser deposition. The RbAg4I5 target for PLD process was mechano-chemically synthesized by high-energy ball milling in Ar atmosphere using β-AgI and RbI as raw materials. The ion-conducting properties of RbAg4I5 were studied by alternating current (AC) impedance spectroscopy and the ionic conductivity at room temperature was estimated 0.21 S/m. The structure, morphology, and elemental composition of the RbAg4I5 film were investigated. The Ag+ ion-conducting property of the prepared superioni-conductor film was exploited for ion-beam generation. The temperature and accelerating voltage dependences of the ion current were studied. Few nA current was obtained at the temperature of 196 ℃ and the accelerating voltage of 10 kV.
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Received: 14 February 2019
Revised: 18 March 2019
Accepted manuscript online:
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PACS:
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07.77.Ka
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(Charged-particle beam sources and detectors)
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| Fund: Project supported by the National Natural Science Foundation of China (Grant No. 11875210), China Postdoctoral Science Foundation (Grant No. 2018M640724), the International Cooperation Program of Guangdong Provincial Science and Technology Plan Project (Grant No. 2018A050506082), and the Talent Project of Lingnan Normal University, China (Grant No. ZL1931). |
Corresponding Authors:
De-Jun Fu
E-mail: djfu@whu.edu.cn
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Cite this article:
Jun-Lian Chen(陈军联), Wen-Bin Zuo(左文彬), Xian-Wen Ke(柯贤文), Alexander B Tolstoguzov, Can-Xin Tian(田灿鑫), Neena Devi, Ranjana Jha, Gennady N Panin, De-Jun Fu(付德君) Structure, conductivity, and ion emission properties of RbAg4I5 solid electrolyte film prepared by pulsed laser deposition 2019 Chin. Phys. B 28 060705
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