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Chin. Phys. B, 2011, Vol. 20(5): 050701    DOI: 10.1088/1674-1056/20/5/050701
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Adsorption-controlled transition of the electrical properties realized in Hematite (alpha-Fe2O3) nanorods ethanol sensing

Wang Chong(王翀)a)†, Wang Fei-Fei(王菲菲)b), Fu Xing-Qiu(付星球)c), Zhang En-Di(张恩迪)d), and Xu Zhi(许志) d)
a School of Opto-electronic Information Science and Technology, Yantai University, Yantai 264005, China; b School of Physics, Ludong University, Yantai 264025, China; c Mathematics and Physics Department, North China Electric Power University, Beijing 102206, China; d Micro-Nano Technologies Research Center, Hunan University, Changsha 410082, China
Abstract  Alpha-Fe2O3 nanorods are synthesized through a hydrothermal method with no surfactant introduced and ethanol sensors are fabricated from these nanorods. The device can respond to ethanol vapour in a concentration range from 1 to 1500 parts per million and shows both p-type and n-type responding characteristics during the investigation of the ethanol sensing. The sensor displays a p-type characteristic when the ethanol concentration is low and converted into an n-type characteristic as the concentration exceeds a certain value. Such a phenomenon is attributed to the chemisorbed oxygen, which leads to different modifications of the energy band at the surface, namely, depletion layer or inversion layer.
Keywords:  adsorption      sensing      depletion      oxygen  
Received:  16 October 2010      Revised:  16 December 2010      Accepted manuscript online: 
PACS:  07.07.Df (Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing)  
  73.63.Bd (Nanocrystalline materials)  
  81.07.Bc (Nanocrystalline materials)  
Fund: Project supported by the National Basic Research Program of China (Grant No. 2007CB310500), the National Natural Science Foundation of China (Grant No. 90606009), the Funds for Doctor of Yantai University, China (Grant No. WL08B8), the Funds for Doctor of Ludong University, China (Grant No. LY20082802), and the Natural Science Foundation of Hunan Province, China (Grant No. 10JJ1011).

Cite this article: 

Wang Chong(王翀), Wang Fei-Fei(王菲菲), Fu Xing-Qiu(付星球), Zhang En-Di(张恩迪), and Xu Zhi(许志) Adsorption-controlled transition of the electrical properties realized in Hematite (alpha-Fe2O3) nanorods ethanol sensing 2011 Chin. Phys. B 20 050701

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