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Effect of crystalline microstructure on the photophysical performance of polymer/perylene composite films
Feng Wei (封伟), Xu You-Long (徐友龙), Yi Wen-Hui (易文辉), Zhou Feng (周峰), Wang Xiao-Gong (王晓工), Yoshino Katsumi (吉野勝美)
Chinese Physics, 2003, 12 (4):
426-432.
DOI: 10.1088/1009-1963/12/4/315
To obtain high carrier mobility, better charge injection capability, and high photovoltaic device conversion efficiency, a powerful strategy is to improve the morphology of the polymer/dye composite films. Conjugated conducting polymer (CP) thin films doped with perylene derivative (PV) of various concentrations were prepared by spin-casting method, and their morphology and photovoltaic characteristics were examined. The change in morphology and molecular reorientation occurring in CP-PV composite films upon annealing at different temperatures was investigated using scanning electron microscopy, x-ray diffraction, Fourier transform infrared and UV-vis absorption. By changing the annealing temperature, PV microcrystallines of 8-10μm in size lying parallel to the substrate surface can be obtained. Annealing effect improved the photovoltaic performance of ITO/CP-PV/Al Schottky-type solar cells, which can be attributed to the formation of an electron conducting PV crystal network. Preliminary studies indicate that the morphological structure in CP-PV composite films has an important influence to their photovoltaic properties.
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