Effect of Mn-doping on the growth mechanism and electromagnetic properties of chrysanthemum-like ZnO nanowire clusters

doi:10.1088/1674-1056/20/4/048102

Abstract Chrysanthemum-like ZnO nanowire clusters with different Mn-doping concentrations are prepared by a hydrothermal process. The microstructure, morphology and electromagnetic properties are characterized by x-ray diffractometer high-resolution transmission electron microscopy (HRTEM), a field emission environment scanning electron microscope (FEESEM) and a microwave vector network analyser respectively. The experimental results indicate that the as-prepared products are Mn-doped ZnO single crystalline with a hexagonal wurtzite structure, that the growth habit changes due to Mn-doping and that a good magnetic loss property is found in the Mn-doped ZnO products, and the average magnetic loss tangent tan$\delta$_m is up to 0.170099 for 3% Mn-doping, while the dielectric loss tangent tanδ_e is weakened, owing to the fact that ions Mn²⁺enter the crystal lattice of ZnO.

Keywords: chrysanthemum-like ZnO nanowire clusters electromagnetic properties hydrothermal method Mn-doping

Received: 28 September 2010
Revised: 07 December 2010
Accepted manuscript online:

PACS:	81.10.Dn	(Growth from solutions)
	81.07.Gf	(Nanowires)
	81.16.Dn	(Self-assembly)
	77.22.Gm	(Dielectric loss and relaxation)

Fund: Project supported by the National Natural Science Foundation of China (Grant No. 60976069), the Natural Science Foundation of Shaanxi Province, China (Grant No. 2010JM6008), and the Xi'an Scientific and Technological Project, China (Grant No. CXY1008).

Cite this article:

Yan Jun-Feng(闫军锋), You Tian-Gui(游天桂), Zhang Zhi-Yong(张志勇), Tian Jiang-Xiao(田江晓), Yun Jiang-Ni(贠江妮), and Zhao Wu(赵武) Effect of Mn-doping on the growth mechanism and electromagnetic properties of chrysanthemum-like ZnO nanowire clusters 2011 Chin. Phys. B 20 048102

[1]	Zhou R F, Qiao L, Feng H T, Chen J T, Yan D, Wu Z G and Yan P X 2008 J. Appl. Phys. 104 094101
[2]	Li G, Hu G, Zhou H, Fan X and Li X 2002 Mater. Chem. Phys. 75 101
[3]	Hatakeyama K and Inui T 1984 IEEE Trans. Magn. 20 1261
[4]	Matsumoto M and Miyata Y 1997 IEEE Trans. Magn. 33 4459
[5]	Liu X G, Geng D Y, Meng H, Shang P J and Zhang Z D 2008 Appl. Phys. Lett. 92 173117
[6]	Zhou Z W, Chu L S and Hu S C 2006 Mater. Sci. Eng. B 126 93
[7]	Chen Y J, Cao M S, Wang T H and Wan Q 2004 Appl. Phys. Lett. 84 3367
[8]	Cao M S, Shi X L, Fang X Y, Jin H B, Hou Z L, Zhou W and Chen Y J 2007 Appl. Phys. Lett. 91 203110
[9]	Shi X L, Yuan J, Zhou W, Rong J L and Cao M S 2007 Chin. Phys. Lett. 24 2994
[10]	Zhou Y, Shi X L, Yuan J, Fang X Y and Cao M S 2007 Chin. Phys. Lett. 24 3264
[11]	Huang Y Q, Yuan J, Song W L, Wen B, Fang X Y and Cao M S 2010 Chin. Phys. Lett. 27 027702
[12]	Cao J W, Huang Y H, Zhang Y, Liao Q L and Deng Z Q 2008 Acta Phys. Sin. 57 3641 (in Chinese)
[13]	Li H F, Huang Y H, Sun G B, Yan X Q, Yang Y, Wang J and Zhang Y 2010 J. Phys. Chem. C 114 10088
[14]	Wang J, Li H F, Huang Y H, Yu H B and Zhang Y 2010 Acta Phys. Sin. 59 1946 (in Chinese)
[15]	Zhou R F, Feng H T, Chen J T, Yan D, Feng J J, Li H J, Geng B S, Cheng S, Xu X Y and Yan P X 2008 J. Phys. Chem. C 112 11767
[16]	Zhou R F, Feng H T, Liang Q, Liu J Z, Chen J T, Yan D, Feng J J, Li H J, Cheng S, Geng B S, Xu X Y, Wang J, Wu Z G, Yan P X and Yue G H 2008 J. Phys. D: Appl. Phys. 41 185405
[17]	Huang Y X, Cao Q X, Li Z M, Jinag H Q, Wang Y P and Li G F 2009 J. Am. Ceram. Soc. 92 2129
[18]	Yan J F, Zhang Z Y, You T G, Zhao W and Yun J N 2009 Chin. Phys. B 18 4019
[19]	Yan J F, Zhang Z Y, You T G, Zhao W, Yun J N and Zhang F C 2009 Chin. Phys. B 18 4552
[20]	Sharma P, Gupta A, Rao K V, Owens F J, Sharma R, Ahuja R, Guillen J M O, Johansson B and Gehring G A 2003 Nature Mater. 2 673

[1]	Adsorption of CO₂ on MgAl layered double hydroxides: Effect of intercalated anion and alkaline etching time Yan-Yan Feng(冯艳艳), Xiao-Di Niu(牛潇迪), Yong-Hui Xu (徐永辉), and Wen Yang(杨文). Chin. Phys. B, 2021, 30(4): 048101.
[2]	LnCu₃(OH)₆Cl₃ (Ln = Gd, Tb, Dy): Heavy lanthanides on spin-1/2 kagome magnets Ying Fu(付盈), Lianglong Huang(黄良龙), Xuefeng Zhou(周雪峰), Jian Chen(陈见), Xinyuan Zhang(张馨元), Pengyun Chen(陈鹏允), Shanmin Wang(王善民), Cai Liu(刘才), Dapeng Yu(俞大鹏), Hai-Feng Li(李海峰), Le Wang(王乐), and Jia-Wei Mei(梅佳伟). Chin. Phys. B, 2021, 30(10): 100601.
[3]	Effect of deposition temperature on SrFe₁₂O₁₉@carbonyl iron core-shell composites as high-performance microwave absorbers Yuan Liu(刘渊), Rong Li(李茸), Ying Jia(贾瑛), Zhen-Xin He(何祯鑫). Chin. Phys. B, 2020, 29(6): 067701.
[4]	Morphological modifications of C₆₀ crystal rods under hydrothermal conditions Ming-Run Du(杜明润), Shi-Xin Liu(刘士鑫), Jia-Jun Dong(董家君), Ze-Peng Li(李泽朋), Ming-Chao Wang (王明超), Tong Wei(魏通), Qing-Jun Zhou(周青军), Xiong Yang(杨雄), and Peng-fei Shen(申鹏飞). Chin. Phys. B, 2020, 29(12): 128102.
[5]	Flexible rGO/Fe₃O₄ NPs/polyurethane film with excellent electromagnetic properties Wei-Qi Yu(余维琪), Yi-Chen Qiu(邱怡宸), Hong-Jun Xiao(肖红君), Hai-Tao Yang(杨海涛), Ge-Ming Wang(王戈明). Chin. Phys. B, 2019, 28(10): 108103.
[6]	Enhancement of thermoelectric properties of SrTiO₃/LaNb-SrTiO₃ composite by different doping levels Ke-Xian Wang(王柯鲜), Jun Wang(王俊), Yan Li(李艳), Tao Zou(邹涛), Xiao-Huan Wang(王晓欢), Jian-Bo Li(李建波), Zheng Cao(曹正), Wen-Jing Shi(师文静), Xinba Yaer(新巴雅尔). Chin. Phys. B, 2018, 27(4): 048401.
[7]	Low-temperature green synthesis of boron carbide using aloe vera H V SarithaDevi, M S Swapna, G Ambadas, S Sankararaman. Chin. Phys. B, 2018, 27(10): 107702.
[8]	A study of transition from n-to p-type based on hexagonal WO₃ nanorods sensor Wu Ya-Qiao (武雅乔), Hu Ming (胡明), Wei Xiao-Ying (韦晓莹). Chin. Phys. B, 2014, 23(4): 040704.
[9]	Hydrothermal synthesis of hexagonal-phase NaYF₄: Er, Yb with different shapes for application as photovoltaic up-converters Wang Dong-Feng (王东丰), Zhang Xiao-Dan (张晓丹), Liu Yong-Juan (刘永娟), Wu Chun-Ya (吴春亚), Zhang Cun-Shan (张存善), Wei Chang-Chun (魏长春), Zhao Ying (赵颖). Chin. Phys. B, 2013, 22(2): 027801.
[10]	Microstructure and optical properties of nitrogen-doped ZnO film Zhao Xian-Wei (赵显伟), Gao Xiao-Yong (郜小勇), Chen Xian-Mei (陈先梅), Chen Chao (陈超), Zhao Meng-Ke (赵孟珂 ). Chin. Phys. B, 2013, 22(2): 024202.
[11]	Growth of monodisperse nanospheres of MnFe₂O₄ with enhanced magnetic and optical properties M. Yasir Rafique, Pan Li-Qing (潘礼庆), Qurat-ul-ain Javed, M. Zubair Iqbal, Qiu Hong-Mei (邱红梅), M. Hassan Farooq, Guo Zhen-Gang (郭振刚), M. Tanveer. Chin. Phys. B, 2013, 22(10): 107101.
[12]	Effect of Sb-doping on the morphology and the dielectric properties of chrysanthemum-like ZnO nanowire clusters Yan Jun-Feng (闫军锋), You Tian-Gui (游天桂), Zhang Zhi-Yong (张志勇), Tian Jiang-Xiao (田江晓), Yun Jiang-Ni (贠江妮), Zhao Wu (赵武). Chin. Phys. B, 2012, 21(9): 098001.
[13]	Ag-doped ZnO nanorods synthesized by two-step method Chen Xian-Mei (陈先梅), Ji Yong (冀勇), Gao Xiao-Yong (郜小勇), Zhao Xian-Wei (赵显伟 ). Chin. Phys. B, 2012, 21(11): 116801.
[14]	Hydrothermal synthesis and chromic properties of hexagonal WO₃ nanowires Yuan Hua-Jun(袁华军), Chen Ya-Qi(陈亚琦), Yu Fang(余芳), Peng Yue-Hua(彭跃华), He Xiong-Wu(何熊武), Zhao Ding(赵丁), and Tang Dong-Sheng(唐东升). Chin. Phys. B, 2011, 20(3): 036103.
[15]	Microstructural and electromagnetic properties of MnO₂ coated nickel particles with submicron size Tang Bao-Lin(唐葆霖), He Jun(何峻), Ji Tian-Hao(嵇天浩), and Wang Xin-Lin(王新林). Chin. Phys. B, 2009, 18(6): 2571-2575.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Metrics
Related Articles

Effect of Mn-doping on the growth mechanism and electromagnetic properties of chrysanthemum-like ZnO nanowire clusters

Cite this article:

Online attention