1 Key Laboratory of Artificial Micro and Nanostructures of Ministry of Education and Hubei Key Laboratory of Nuclear Solid Physics, School of Physics and Technology, Wuhan University, Wuhan 430072, China; 2 Shenzhen Institute of Wuhan University, Shenzhen 518057, China; 3 Zhuhai Tsinghua University Research Institute Innovation Center, Zhuhai 519000, China; 4 School of Physics and Technology, Lingnan Normal University, Zhanjiang 524048, China; 5 Utkin Ryazan State Radio Engineering University, Ryazan 390005, Russian Federation
Abstract Copper ion conducting solid electrolyte RbCuICl was prepared by means of mechano-chemical method. The structure and morphology of the powder was investigated by x-ray diffraction and scanning electron microscopy. The grain size was estimated to be 0.2-0.9 μm and the ionic conductivity at room temperature was approximately 0.206 S/cm. The solid electrolyte RbCuICl was exploited for copper ion beam generation. The copper ion emission current of several nA was successfully obtained at acceleration voltages of 15 kV and temperature of 197 C in vacuum of 2.1 Pa. A good linear correlation between the logarithmic ion current and the square root of the acceleration voltage () at high voltage range was obtained, suggesting the Schottky emission mechanism in the process of copper ion beam generation.
Fund: This work was supported by Shenzhen Municipal Science and Technology Innovation Commission (Grant Nos. JCYJ20170818112901473 and GJHZ20200731095604015) and the Department of Science and Technology of Guangdong Province, China (Grant Nos. 2020A0505100059, 2020A1515011531, and 2020A1515011451). One of the authors (Alexander Tolstoguzov) is grateful to the support of this research by the Ministry of Education and Science of the Russian Federation in the frame of the state assignment (Grant No. FSSN-2020-0003).
Corresponding Authors:
Dejun Fu
E-mail: djfu@whu.edu.cn
Cite this article:
Tushagu Abudouwufu(吐沙姑·阿不都吾甫), Xiangyu Zhang (张翔宇), Wenbin Zuo (左文彬), Jinbao Luo(罗进宝), Yueqiang Lan(兰越强), Canxin Tian (田灿鑫), Changwei Zou(邹长伟), Alexander Tolstoguzov, and Dejun Fu(付德君) Copper ion beam emission in solid electrolyte Rb4Cu16I6.5Cl13.5 2022 Chin. Phys. B 31 040704
[1] He S N, Xu Y L, Chen Y J and Ma X N 2020 J. Mater. Chem. A8 12594 [2] Kanno R, Takeda Y, Imura M and Yamamoto O 1982 J. Appl. Electrochem. 12 681 [3] Gombotz M, Hanghofer I, Eisbacher-Lubensky S and Wilkening H M R 2021 Solid State Sci. 118 106680 [4] Liu H C, Huang J, Cao L X, Su Y, Gao Z Y, Ma P F, Xia S Q, Ge W, Liu Q Y, Zhao S, Wang Y G, Huang J C, Zhou Z H, Zheng P F and Wang C X 2021 Chin. Phys. B30 086106 [5] Agrawal R C and Gupta R K 1999 J. Mater. Sci. 34 1131 [6] Reuter B and Hardel K 1965 Z. Anorg. Allg. Chem. 340 158 [7] Boolchand P and Bresser W J 2001 Nature410 1070 [8] Kavun V Y, Gerasimenko A V, Uvarov N F, Polyantsev M M and Zemnukhova L A 2016 J. Solid State Chem. 241 9 [9] Li Q X, Hayashi K, Nishioka M, Kashiwagi H, Hirano M, Torimoto Y, Hosono H and Sadakata M 2002 Appl. Phys. Lett. 80 4259 [10] Creus R, Sarradin J, Astier R, Pradel A and Ribes M 1989 Mater. Sci. Eng. B3 109 [11] Daiko Y, Yamada T, Yamanishi S, Mineshige A and Yazawa T 2014 Electrochem. 82 901 [12] Daiko Y, Yanagida H, Honda S and Iwamoto Y 2020 Solid State Ionics353 115400 [13] Yan Z, Pan H Y, Wang J Y, Chen R S, Luo F, Yu X Q and Li H 2020 Chin. Phys. B29 088201 [14] Owens B B and Argue G R 1967 Science157 308 [15] Whittingham M S and Huggins R A 1971 J. Chem. Phys. 54 414 [16] Ling S G, Peng J Y, Yang Q, Qiu J L, Lu J Z and Li H 2018 Chin. Phys. B27 038201 [17] Fujiwara Y, Sakai T, Kaimai A, Yashiro K, Kawada T and Mizusaki J 2006 J. Vac. Sci. Technol. A24 1818 [18] Berastegui P and Hull S 2002 Solid State Ionics154-155 605 [19] Mellors G W and Louzos D V 1971 J. Electrochem. Soc. 118 846 [20] Escher C, Thomann S, Andreoli C, Fink H W, Toquant J and Pohl D W 2006 Appl. Phys. Lett. 89 053513 [21] Tolstoguzov A B, Aguas H, Ayouchi R, Belykh S F, Fernandes F, Gololobov G P, Moutinho A M C, Schwarz R, Suvorov D V and Teodoro O M N D 2016 Vacuum131 252 [22] Chen J L, Zuo W B, Ke X W, Tolstoguzov A B, Tian C X, Devi N, Jha R, Panin G N and Fu D J 2019 Chin. Phys. B28 060705 [23] Zuo W B, Pelenovich V O, Tolstoguzov A B, Zeng X M, Wang Z G, Song X Q, Gusev S I, Tian C X and Fu D J 2019 J. Alloys Compd. 790 109 [24] Abudouwufu T, Zuo W B, Pelenovich V O, Zhang X Y, Zeng X M, Tolstoguzov A B, Zou C W, Tian C X and Fu D J 2021 Solid State Ionics364 115634 [25] Takahashi T, Yamamoto O, Yamoda S and Hayashi S 1979 J. Electrochem. Soc. 126 1654 [26] Takahashi T, Kanno R, Takeda Y and Yamamoto O 1981 Solid State ionics34 283 [27] Masaru A, Haruhito S and Eita H 2021 Crystals11 1008 [28] Kanno R, Ohno K, Kawamoto Y, Takeda Y, Yamamoto O, Kamiyama T, Asano H, Izumi F and Kondo S 1993 J. Solid State Chem. 102 79 [29] Gao J, Zhao Y S, Shi S Q and Li H 2016 Chin. Phys. B25 018211 [30] Owens B B 2000 J. Power Sources90 2 [31] Takehiko T, Osamu Y, Shuji Y and Hoyoshi S 1979 J. Electrochem. Soc. 126 1654 [32] Zuo W B, Pelenovich V O, Tolstogouzov A B, Ieshkin A E, Zeng X M, Wang Z G, Gololobov G, Suvorov D, Liu C S, Fu D J and Hu D H 2019 Vacuum167 382 [33] Kiziroglou M E, Li X, Zhukov A A, de Groot P A J and de Groot C H 2008 Solid-State Electron. 52 1032 [34] Benilov M S 2009 Plasma Sources Sci. Technol. 18 014005
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