| ELECTROMAGNETISM, OPTICS, ACOUSTICS, HEAT TRANSFER, CLASSICAL MECHANICS, AND FLUID DYNAMICS |
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Optical nonlinearities of tetracarbonyl-chromium triphenyl phosphine complex |
| M D Zidan1, A W Allaf2, A Allahham1, A AL-Zier2 |
1 Department of Physics, Atomic Energy Commission, P. O. Box 6091, Damascus, Syria;
2 Department of Chemistry, Atomic Energy Commission, P. O. Box 6091, Damascus, Syria |
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Abstract The new tetracarbonyl–chromium-triphenyl phosphine complex was synthesized and characterized using ultraviolet (UV)-visible, Fourier transform infrared (FTIR), and nuclear magnetic resonance (NMR) techniques. The characterization results confirm the molecular structure of the new complex. The z-scan measurements were done by diode laser [continuous wave (CW)] to estimate the nonlinear optical parameter (χ3). The results led to calculate three parameters: the ground-state cross sections (σg), the excited-state cross sections (σex), and thermo-optic coefficient of the new complex. This study indicated that our complex is a suitable for photonic applications.
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Received: 28 November 2016
Revised: 22 January 2017
Accepted manuscript online:
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PACS:
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42.65.-k
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(Nonlinear optics)
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42.70.Nq
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(Other nonlinear optical materials; photorefractive and semiconductor materials)
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31.15.ap
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(Polarizabilities and other atomic and molecular properties)
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42.70.Jk
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(Polymers and organics)
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Corresponding Authors:
M D Zidan
E-mail: pscientific2@aec.org.sy
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Cite this article:
M D Zidan, A W Allaf, A Allahham, A AL-Zier Optical nonlinearities of tetracarbonyl-chromium triphenyl phosphine complex 2017 Chin. Phys. B 26 044205
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