Large elastocaloric effect in Ti-Ni shape memory alloy below austenite finish temperature

doi:10.1088/1674-1056/26/3/036501

Abstract

Solid refrigeration technology based on the elastocaloric effect has a great potential alternative to the conventional vapor compression cooling. Here we report the large elastocaloric effect in Ti-Ni (50 at%) shape memory alloy below its austenite finish temperature A_f under different strain. Both Maxwell's and Clausius-Clapeyron equations are used to estimate the entropy change. The strain-induced entropy change increases with raising the strain and gets a maximum value at a few kelvins below A_f. The maximum entropy changes ΔS_max are -20.44 and -53.70 J/kg·K, respectively for 1% and 2% strain changes. Large entropy change may be obtained down to 20 K below A_f. The temperature of the maximum entropy change remains unchanged before the plastic deformation appears but moves towards low temperature when the plastic deformation happens.

Keywords: elastocaloric effect martensitic transformation shape memory alloys

Received: 24 October 2016
Revised: 10 December 2016
Accepted manuscript online:

PACS:	65.40.De	(Thermal expansion; thermomechanical effects)
	46.25.Hf	(Thermoelasticity and electromagnetic elasticity (electroelasticity, magnetoelasticity))
	62.20.fg	(Shape-memory effect; yield stress; superelasticity)

Fund:

Project supported by the National Natural Science Foundation of China (Grant Nos. 51671192 and 51531008) and the Chinese Academy of Sciences (Grant No. KJZD-EW-M05).

Corresponding Authors: Wei-Jun Ren
E-mail: wjren@lmr.ac.cn

Cite this article:

Xiao-Hua Luo(罗小华), Wei-Jun Ren(任卫军), Wei Jin(金伟), Zhi-Dong Zhang(张志东) Large elastocaloric effect in Ti-Ni shape memory alloy below austenite finish temperature 2017 Chin. Phys. B 26 036501

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Large elastocaloric effect in Ti-Ni shape memory alloy below austenite finish temperature

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