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Synthesis mechanism of heterovalent Sn2O3 nanosheets in oxidation annealing process |
Zhao Jun-Hua (赵俊华)a, Tan Rui-Qin (谭瑞琴)b, Yang Ye (杨晔)c, Xu Wei (许炜)c, Li Jia (李佳)c, Shen Wen-Feng (沈文峰)c, Wu Guo-Qiang (吾国强)a, Yang Xu-Feng (杨旭峰)a, Song Wei-Jie (宋伟杰)c |
a College of Chemical and Material Engineering, Quzhou University, Quzhou 324000, China; b Faculty of Information Science and Engineering, Ningbo University, Ningbo 315211, China; c Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China |
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Abstract Heterovalent Sn2O3 nanosheets were fabricated via an oxidation annealing process and the formation mechanism was investigated. The temperature required to complete the phase transformation from Sn3O4 to Sn2O3 was considered. Two contrasting experiments showed that both oxygen and heating were not necessary conditions for the phase transition. Sn2O3 was formed under an argon protective atmosphere by annealing and could also be obtained at room temperature by exposing Sn3O4 in atmosphere or dispersing in ethanol. The synthesis mechanism was proposed and discussed. This fundamental research is important for the technological applications of intermediate tin oxide materials.
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Received: 27 November 2014
Revised: 05 May 2015
Accepted manuscript online:
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PACS:
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05.70.Fh
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(Phase transitions: general studies)
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64.60.My
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(Metastable phases)
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62.23.Kn
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(Nanosheets)
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Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 21377063, 51102250, 21203226, and 21205127) and the Personnel Training Foundation of Quzhou University, China (Grant No. BSYJ201412). |
Corresponding Authors:
Zhao Jun-Hua
E-mail: Zhaojh1018@163.com
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Cite this article:
Zhao Jun-Hua (赵俊华), Tan Rui-Qin (谭瑞琴), Yang Ye (杨晔), Xu Wei (许炜), Li Jia (李佳), Shen Wen-Feng (沈文峰), Wu Guo-Qiang (吾国强), Yang Xu-Feng (杨旭峰), Song Wei-Jie (宋伟杰) Synthesis mechanism of heterovalent Sn2O3 nanosheets in oxidation annealing process 2015 Chin. Phys. B 24 070505
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[1] |
Hu Y, Li J C, Shen M W and Shi X Y 2014 Chin. Phys. B 23 78704
|
[2] |
He J H, Wu T H, Hsin C L, Li K M, Chen L J, Chueh Y L, Chou L J and Wang Z L 2006 Small 2 116
|
[3] |
Li X Q, Zheng L and Wang X F 2014 Chin. Phys. Lett. 31 024701
|
[4] |
Stankiewiez J, Villuendas F and Bartolomé J 2007 Phys. Rev. B 75 235308
|
[5] |
Wang G X, Takeguchi T, Yamanaka T, Muhamad E N, Mastuda M and Ueda W 2010 Appl. Catal. B: Environ. 98 86
|
[6] |
Heo J, Hock A S and Gordon R G 2010 Chem. Mater. 22 4964
|
[7] |
Lawson F 1967 Nature 215 955
|
[8] |
White T A, Moreno M S and Midgley P A 2010 Z. Kristallogr. 225 56
|
[9] |
Berengue O M, Simon R A, Chiquito A J, Dalmaschio C J, Leite E R, uerreiro G H A and Guimaraes F E G 2010 J. Appl. Phys. 107 033717
|
[10] |
Murken G and Tromel M 1973 Z. Anorg. Allg. Chem. 397 117
|
[11] |
Hasselbach K, Murken G and Tromel M 1973 Z. Anorg. Allg. Chem. 397 127
|
[12] |
Choi W K, Sung H, Kim K H, Cho J S, Choi S C, Jung H J, Koh S K, Lee C M and Jeong K 1997 J. Mater. Sci. Lett. 16 1551
|
[13] |
Beisenkhanov 2011 Phys. Solid State 53 390
|
[14] |
Chen T S, Huang K L and Pan Y C 2012 Int. J. Electrochem. Sci. 7 11191
|
[15] |
O'Brien S, Brus L and Murray C B 2001 J. Am. Chem. Soc. 123 12085
|
[16] |
Cao M H, Hu C W, Peng G, Qi Y J and Wang E B 2003 J. Am. Chem. Soc. 125 4982
|
[17] |
Zhao J H, Tan R Q, Shen W F, Yang Y, Guo Y Q, Li J, Zhou Z, Jian J W and Song W J 2012 Mater. Lett. 84 94
|
[18] |
Xu W, Li M, Chen X B, Zhao J H, Tan R Q, Li R, Li J and Song W J 2014 Mater. Lett. 120 140
|
[19] |
Li M, Tan R Q, Li Rong, Song W J and Xu W 2014 Ceram. Int. 40 11381
|
[20] |
Zenkyu R, Tajima D and Yuhara J 2012 J. Appl. Phys. 111 064907
|
[21] |
Themlin J M, Chtaib M, Henrard L, Lambin P, Darville J and Gilles J M 1992 Phys. Rev. B 46 2460
|
[22] |
Rusu C N and Yates J T 1997 Langmuir 13 4311
|
[23] |
Seko A, Togo A, Oba F and Tanaka I 2008 Phys. Rev. Lett. 100 045702
|
[24] |
Wang L, Wang D, Dong Z H, Zhang F X and Jin J 2014 Small 10 998
|
[25] |
Zhao J H, Tan R Q, Zhang Y L, Yang Y, Guo Y Q, Zhang X P, Wang W Y and Song W J 2011 J. Am. Ceram. Soc. 94 725
|
[26] |
Andrews L and Smardzewski R R 1973 J. Chem. Phys. 58 2258
|
[27] |
Popescu D A, Herrmann J M, Ensuque A and Verduraz F B 2001 Phys. Chem. Chem. Phys. 3 2522
|
[28] |
Röder H, Zang J and Bishop A R 1996 Phys. Rev. Lett. 76 1356
|
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