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Chin. Phys. B, 2015, Vol. 24(3): 038202    DOI: 10.1088/1674-1056/24/3/038202
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New layered metal oxides as positive electrode materials for room-temperature sodium-ion batteries

Mu Lin-Qin, Hu Yong-Sheng, Chen Li-Quan
Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
Abstract  

In order to achieve better Na storage performance, most layered oxide positive electrode materials contain toxic and expensive transition metals Ni and/or Co, which are also widely used for lithium-ion batteries. Here we report a new quaternary layered oxide consisting of Cu, Fe, Mn, and Ti transition metals with O3-type oxygen stacking as a positive electrode for room-temperature sodium-ion batteries. The material can be simply prepared by a high-temperature solidstate reaction route and delivers a reversible capacity of 94 mAh/g with an average storage voltage of 3.2 V. This paves the way for cheaper and non-toxic batteries with high Na storage performance.

Keywords:  layered oxides      positive electrode      sodium-ion battery      energy storage  
Received:  26 December 2014      Revised:  30 January 2015      Accepted manuscript online: 
PACS:  82.45.Yz (Nanostructured materials in electrochemistry)  
  82.47.Aa (Lithium-ion batteries)  
  82.47.Cb (Lead-acid, nickel-metal hydride and other batteries)  
  84.60.&ndash  
  h  
Corresponding Authors:  Hu Yong-Sheng     E-mail:  yshu@aphy.iphy.ac.cn

Cite this article: 

Mu Lin-Qin, Hu Yong-Sheng, Chen Li-Quan New layered metal oxides as positive electrode materials for room-temperature sodium-ion batteries 2015 Chin. Phys. B 24 038202

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