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New layered metal oxides as positive electrode materials for room-temperature sodium-ion batteries |
| Mu Lin-Qin (穆林沁), Hu Yong-Sheng (胡勇胜), Chen Li-Quan (陈立泉) |
| Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China |
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Abstract In order to achieve better Na storage performance, most layered oxide positive electrode materials contain toxic and expensive transition metals Ni and/or Co, which are also widely used for lithium-ion batteries. Here we report a new quaternary layered oxide consisting of Cu, Fe, Mn, and Ti transition metals with O3-type oxygen stacking as a positive electrode for room-temperature sodium-ion batteries. The material can be simply prepared by a high-temperature solidstate reaction route and delivers a reversible capacity of 94 mAh/g with an average storage voltage of 3.2 V. This paves the way for cheaper and non-toxic batteries with high Na storage performance.
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Received: 26 December 2014
Revised: 30 January 2015
Accepted manuscript online:
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PACS:
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82.45.Yz
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(Nanostructured materials in electrochemistry)
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82.47.Aa
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(Lithium-ion batteries)
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82.47.Cb
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(Lead-acid, nickel-metal hydride and other batteries)
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84.60.&ndash
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h
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Corresponding Authors:
Hu Yong-Sheng
E-mail: yshu@aphy.iphy.ac.cn
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Cite this article:
Mu Lin-Qin (穆林沁), Hu Yong-Sheng (胡勇胜), Chen Li-Quan (陈立泉) New layered metal oxides as positive electrode materials for room-temperature sodium-ion batteries 2015 Chin. Phys. B 24 038202
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