Failure analysis with a focus on thermal aspect towards developing safer Na-ion batteries

doi:10.1088/1674-1056/ab7906

Abstract Safety requirements stimulate Na-based batteries to evolve from high-temperature Na-S batteries to room-temperature Na-ion batteries (NIBs). Even so, NIBs may still cause thermal runaway due to the external unexpected accidents and internal high activity of electrodes or electrolytes, which has not been comprehensively summarized yet. In this review, we summarize the significant advances about the failure mechanisms and related strategies to build safer NIBs from the selection of electrodes, electrolytes and the construction of electrode/electrolyte interfaces. Considering the safety risk, the thermal behaviors are emphasized which will deepen the understanding of thermal stability of different NIBs and accelerate the exploitation of safe NIBs.

Keywords: Na-ion batteries safety issue electrodes electrolytes solid electrolyte interphase thermal runaway failure analysis

Received: 20 December 2019
Revised: 22 February 2020
Accepted manuscript online:

PACS:	65.40.-b	(Thermal properties of crystalline solids)
	65.20.-w	(Thermal properties of liquids)
	65.40.gk	(Electrochemical properties)
	88.80.ff	(Batteries)

Fund: Project supported by the National Key Technologies R&D Program, China (Grant No. 2016YFB0901500), the National Natural Science Foundation (NSFC) of China (Grant Nos. 51725206 and 51421002), NSFCUKRI_EPSRC (Grant No. 51861165201), the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA21070500), Beijing Municipal Science and Technology Commission, China (Grant No. Z181100004718008), and Beijing Natural Science Fund-Haidian Original Innovation Joint Fund, China (Grant No. L182056).

Corresponding Authors: Yaxiang Lu, Yong-Sheng Hu
E-mail: yxlu@iphy.ac.cn;yshu@iphy.ac.cn

Cite this article:

Yuqi Li(李钰琦), Yaxiang Lu(陆雅翔), Liquan Chen(陈立泉), Yong-Sheng Hu(胡勇胜) Failure analysis with a focus on thermal aspect towards developing safer Na-ion batteries 2020 Chin. Phys. B 29 048201

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Failure analysis with a focus on thermal aspect towards developing safer Na-ion batteries

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