A new sulfur-doped source and synergistic effect with nitrogen for carbon dots produced from glucose

doi:10.1088/1674-1056/ab5213

Abstract The nitrogen and sulfur co-doped carbon dots (N, S-CDs) with increased luminescence were synthesized by a hydrothermal process in one green pot by using glucose, and a new sulfur-doping source of sodium sulfite was developed. The synergistic effect of the N and S groups was well discussed through the structure analysis of Fourier transform infrared spectra and x-ray photoelectron spectra. The surface states of N, S-CDs embody more complicated functional groups, and S element exists as -SSO₃, -C-SO₃, and SO₄^2- groups due to the introduction of sodium sulfite. The sulfur-containing groups passivate the surface of the CDs, and the relatively high sulfur groups may reduce the non-radiation centers. The fluorescence is affected by the hydroxyl group of the solvent. The quenching of Fe³⁺ ion to fluorescence and the sensitivity of fluorescence to pH were also investigated.

Keywords: carbon dots glucose sodium sulfite nitrogen and sulfur codoping synergistic effect

Received: 15 August 2019
Revised: 29 September 2019
Accepted manuscript online:

PACS:	81.05.U-	(Carbon/carbon-based materials)
	81.07.-b	(Nanoscale materials and structures: fabrication and characterization)
	42.70.-a	(Optical materials)

Fund: Project by the National Natural Science Foundation of China (Grant Nos. 51571085, 11805052, and 61705062), the Research Project for Basic and Forefront Technology of Henan Province, China (Grant No. 162300410219), and the Doctor Foundation of Henan Polytechnic University, China (Grant No. B2014049).

Corresponding Authors: Yuehong Yin, Guohua Cao
E-mail: yuehongyin@126.com;ghcao@hpu.edu.cn

Cite this article:

Lige Fu(付丽歌), Yuehong Yin(殷月红), Guohua Cao(曹国华), Pingping Wu(武苹苹), Jian Wang(汪舰), Lingling Yan(闫玲玲), Baoqing Zhang(张宝庆), Ming Li(李明) A new sulfur-doped source and synergistic effect with nitrogen for carbon dots produced from glucose 2019 Chin. Phys. B 28 128102

[34]	Zhan H and Gu Y 2018 Chin. Phys. B 27 38103
[1]	Wang Y and Hu A 2014 J. Mater. Chem. C 2 6921
[35]	Mohammad A, Tooba H and Jamshid L 2014 Spectrochim. Acta A 122 715
[2]	He P, Yuan F, Wang Z, Tan Z and Fan L 2018 Acta Phys.-Chim. Sin. 34 1250
[36]	Wei C, Li J, Xiao X, Yue T and Zhao D 2018 RSC Adv. 8 20016
[3]	Qu D, Zheng M, Zhang L, Zhao H, Xie Z, Jing X, Haddad R E, Fan H and Sun Z 2015 Sci. Rep. 4 5294
[37]	Chen B, Xie H, Wang S, Guo Z, Hu Y and Xie H 2019 J. Nanopart. Res. 21 76
[4]	He G, Shu M, Yang Z and Ma Y 2017 Appl. Surf. Sci. 422 257
[5]	Monoj K B, Bikash J, Santanu B and Amitava P 2014 J. Phy. Chem. C 118 20034
[6]	Guo Y, Wang Z, Shao H and Jiang X 2013 Carbon 52 583
[7]	Baker S N and Baker G A 2010 Angew. Chem. Int. Edit. 49 6726
[8]	Ming H, Ma Z, Liu Y, Pan K, Yu H, Wang F and Kang Z 2012 Dalton Trans. 41 9526
[9]	Zhu J, Bai X, Bai J and Pan J 2018 Nanotechnology 29 085705
[10]	Li Y, Zhao Y, Cheng H, Hu Y, Shi G, Dai L and Qu L 2012 J. Am. Chem. Soc. 134 15
[11]	Zhang D, Lin L Z and Zhu J 2014 Chin. Phys. Lett. 31 28102
[12]	Lan S, Li K and Gao X Y 2017 Acta Phys. Sin. 66 136801 (in Chinese)
[13]	Yang Z, Li X and Wang J 2011 Carbon 49 5207
[14]	Shan X, Chai L, Ma J, Qian Z, Chen J and Feng H 2014 Analyst 139 2322
[15]	Ye Q, Yan F, Shi D, Ye Q, Yan F, Shi D, Zheng T, Wang Y, Zhou X and Chen L 2016 J. Photoch. Photobio. B 162 1
[16]	Yang G, Wan X, Su Y and Zeng X 2016 J. Mater. Chem. A 4 12841
[17]	Yang Z, Wang M, Yong A M, Yang Z, Wang M, Marie A, Zhang X, Tan H, Chang Y, Li X and Wang J 2011 Chem. Commun. 47 11615
[18]	Qian Z, Ma J, Shan X, Feng H, Shao L and Chen J 2014 Chem-Eur. J. 20 2254
[19]	Zhang Y, Ma D, Zhuang Y, Zhang X, Chen W, Hong L, Yan Q, Yu K and Huang S 2012 J. Mater. Chem. 22 16714
[20]	SarithaDevi H V, Swapna M S, Ambadas G and Sankararaman S 2018 Chin. Phys. B 27 107702
[21]	Kasprzyk W, Bednarz S and Bogdal D 2013 Chem. Commun. 49 6445
[22]	Zhai X, Zhang P, Liu C, Bai T, Li W, Dai L and Liu W 2012 Chem. Commun. 48 7955
[23]	Dong Y, Pang H, Yang H B, Guo C, Shao J, Chi Y, Li C M and Yu T 2013 Angew. Chem. Int. Edit. 52 7800
[24]	Zhang Y, Tran R T, Qattan I S, Tsai Y T, Tang L, Liu C and Yang J 2013 Biomaterials 34 4048
[25]	Song Y, Zhu S, Zhang S, Fu Y, Wang L, Zhao X and Yang B 2015 J. Mater. Chem. C 3 5976
[26]	Zhou J, Shan X, Ma J and Gu Y 2014 RSC Adv. 4 5465
[27]	Wang G, Liu J, Dong W, Yan C and Zhang W 2018 Acta Phys. Sin. 67 238103 (in Chinese)
[28]	Wu H, Jiang J, Gu X and Tong C 2017 Microchim Acta. 184 2291
[29]	Luo X, Zhang W, Han Y, Chen X, Zhu L, Tang W, Wang J, Yue T and Li Z 2018 Food Chem. 258 214
[30]	Liu T, Cui Z, Zhou J, Wang Y and Zou Z 2017 Nanoscale Res. Lett. 12 375
[31]	Sun D, Ban R, Zhang P, Wu G, Zhang J and Zhu J 2013 Carbon 64 424
[32]	Ma Z, Ming H, Huang H, Liu Y and Kang Z 2012 New J. Chem. 36 861
[33]	Xu Q, Pu P, Z hao J, Wan X, Zhen S and Huang C 2015 J. Mater. Chem. A 3 542
[34]	Zhan H and Gu Y 2018 Chin. Phys. B 27 38103
[35]	Mohammad A, Tooba H and Jamshid L 2014 Spectrochim. Acta A 122 715
[36]	Wei C, Li J, Xiao X, Yue T and Zhao D 2018 RSC Adv. 8 20016
[37]	Chen B, Xie H, Wang S, Guo Z, Hu Y and Xie H 2019 J. Nanopart. Res. 21 76

[1]	Radiation effects of 50-MeV protons on PNP bipolar junction transistors Yuan-Ting Huang(黄垣婷), Xiu-Hai Cui(崔秀海), Jian-Qun Yang(杨剑群), Tao Ying(应涛), Xue-Qiang Yu(余雪强), Lei Dong(董磊), Wei-Qi Li(李伟奇), and Xing-Ji Li(李兴冀). Chin. Phys. B, 2022, 31(2): 028502.
[2]	Influence of sulfur doping on the molecular fluorophore and synergistic effect for citric acid carbon dots Guohua Cao(曹国华), Zhifei Wei(魏志飞), Yuehong Yin(殷月红), Lige Fu(付丽歌), Yukun Liu(刘玉坤), Shengli Qiu(邱胜利), and Baoqing Zhang(张宝庆). Chin. Phys. B, 2021, 30(9): 097802.
[3]	Helium-hydrogen synergistic effects on swelling in in-situ multiple-ion beams irradiated steels Haocheng Liu(刘昊成), Jia Huang(黄嘉), Liuxuan Cao(曹留煊), Yue Su(苏悦), Zhiying Gao(高智颖), Pengfei Ma(马鹏飞), Songqin Xia(夏松钦), Wei Ge(葛伟), Qingyuan Liu(刘清元), Shuang Zhao(赵双), Yugang Wang(王宇钢), Jinchi Huang(黄金池), Zhehui Zhou(周哲辉), Pengfei Zheng(郑鹏飞), and Chenxu Wang(王晨旭). Chin. Phys. B, 2021, 30(8): 086106.
[4]	Sensitivity enhancement of WS₂-coated SPR-based optical fiber biosensor for detecting glucose concentration Yun Cai(蔡云), Wei Li(李卫), Ye Feng(冯烨), Jian-Sheng Zhao(赵建胜), Gang Bai(白刚), Jie Xu(许杰), and Jin-Ze Li(李金泽)$. Chin. Phys. B, 2020, 29(11): 110701.
[5]	Influences of total ionizing dose on single event effect sensitivity in floating gate cells Ya-Nan Yin(殷亚楠), Jie Liu(刘杰), Qing-Gang Ji(姬庆刚), Pei-Xiong Zhao(赵培雄), Tian-Qi Liu(刘天奇), Bing Ye(叶兵), Jie Luo(罗捷), You-Mei Sun(孙友梅), Ming-Dong Hou(侯明东). Chin. Phys. B, 2018, 27(8): 086103.
[6]	Strategies for optimizing the thermoelectricity of PbTe alloys Jinze Zhai(翟近泽), Teng Wang(王腾), Hongchao Wang(王洪超), Wenbin Su(苏文斌), Xue Wang(王雪), Tingting Chen(陈婷婷), Chunlei Wang(王春雷). Chin. Phys. B, 2018, 27(4): 047306.
[7]	Synergistic effect of total ionizing dose on single event effect induced by pulsed laser microbeam on SiGe heterojunction bipolar transistor Jin-Xin Zhang(张晋新), Hong-Xia Guo(郭红霞), Xiao-Yu Pan(潘霄宇), Qi Guo(郭旗), Feng-Qi Zhang(张凤祁), Juan Feng(冯娟), Xin Wang(王信), Yin Wei(魏莹), Xian-Xiang Wu(吴宪祥). Chin. Phys. B, 2018, 27(10): 108501.
[8]	Optimized calculation of the synergy conditions between electron cyclotron current drive and lower hybrid current drive on EAST Wei Wei(韦维), Bo-Jiang Ding(丁伯江), Y Peysson, J Decker, Miao-Hui Li(李妙辉),Xin-Jun Zhang(张新军), Xiao-Jie Wang(王晓洁), Lei Zhang(张磊). Chin. Phys. B, 2016, 25(1): 015201.
[9]	Synergistic effects of neutron and gamma ray irradiation of commercial CHMOS microcontroller Jin Xiao-Ming(金晓明), Fan Ru-Yu(范如玉), Chen Wei(陈伟),Lin Dong-Sheng(林东生), Yang Shan-Chao(杨善潮), Bai Xiao-Yan(白小燕), Liu Yan(刘岩),Guo Xiao-Qiang(郭晓强), and Wang Gui-Zhen(王桂珍). Chin. Phys. B, 2010, 19(6): 066104.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Metrics
Related Articles

A new sulfur-doped source and synergistic effect with nitrogen for carbon dots produced from glucose

Cite this article:

Online attention