Energy and fine structure of 1s2np(n≤9) states for lithium-like systems from Z=11 to 20
Hu Mu-Hong (胡木宏), Wang Zhi-Wen (王治文)
Physics Department, Liaoning Normal University, Dalian 116029, China; Institute of Atomic and Molecular Physics, Jilin University, Changchun 130012, China
Abstract A new variation method is extended to study the atomic systems with higher nuclear charges and in more highly excited states. The non-relativistic energies of 1s2np (n≤9) states for the lithium-like systems from Z=11 to 20 are calculated using a full-core-plus-correlation method with multi-configuration interaction wavefunctions. Relativistic and mass-polarization effects on the energy are calculated as the first-order perturbation corrections. The fine structures are determined from the expectation values of spin-orbit and spin-other-orbit interaction operators in the Pauli-Breit approximation. The quantum-electrodynamics correction is also included. Our results are compared with experimental data in the literature.
Received: 01 August 2003
Revised: 15 October 2003
Accepted manuscript online:
Fund: Project supported by the National Natural Science Foundation of China (Grant No 10174029).
Cite this article:
Hu Mu-Hong (胡木宏), Wang Zhi-Wen (王治文) Energy and fine structure of 1s2np(n≤9) states for lithium-like systems from Z=11 to 20 2004 Chinese Physics 13 662
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