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Chinese Physics, 2001, Vol. 10(11): 1021-1027    DOI: 10.1088/1009-1963/10/11/306
ATOMIC AND MOLECULAR PHYSICS Prev   Next  

HIGH-RESOLUTION ANALYSIS OF THE $\nu$2+2$\nu$3 BAND OF HDO

Hu Shui-ming (胡水明), He Sheng-gui (何圣贵), Zheng Jing-jing (郑晶晶), Wang Xiang-huai (王湘淮), Ding Yun (丁昀), Zhu Qing-shi (朱清时)
Open Research Laboratory of Bond-Selective Chemistry, University of Science and Technology of China, Hefei 230026, China
Abstract  The Fourier transform spectrum of the $\nu$2+2$\nu$3 band of the HDO molecule was recorded with a resolution of 0.02 cm-1. The spectrum was rotational analysed and the spectroscopic parameters of the (0,1,2) state were estimated in terms of Watson's effective rotational Hamiltonian model and also the model in the Padé-Borel approximation form. They reproduce the upper energy levels with an accuracy close to the experimental uncertainty of 0.001 cm-1.
Keywords:  ro-vibrational spectrum      Fourier transform spectroscopy      HDO molecule  
Received:  27 May 2001      Revised:  02 July 2001      Accepted manuscript online: 
PACS:  33.20.Vq (Vibration-rotation analysis)  
  33.20.Tp (Vibrational analysis)  
  33.20.Sn (Rotational analysis)  
Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 29892161 and 29903010).

Cite this article: 

Hu Shui-ming (胡水明), He Sheng-gui (何圣贵), Zheng Jing-jing (郑晶晶), Wang Xiang-huai (王湘淮), Ding Yun (丁昀), Zhu Qing-shi (朱清时) HIGH-RESOLUTION ANALYSIS OF THE $\nu$2+2$\nu$3 BAND OF HDO 2001 Chinese Physics 10 1021

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