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Chinese Physics, 2000, Vol. 9(7): 550-553    DOI: 10.1088/1009-1963/9/7/016
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES Prev  

GREAT MAGNETIC ENTROPY CHANGE IN La(Fe, M)13 (M=Si, Al) WITH Co DOPING

Hu Feng-xia (胡凤霞)ab, Shen Bao-gen (沈保根)a, Sun Ji-rong (孙继荣)a, Zhang Xi-xiang (张西祥)c
a State Key Laboratory of Magnetism, Institute of Physics & Center of Condensed Matter Physics, Chinese Academy of Sciences, Beijing 100080, China; b Department of Physics, Capital Normal University, Beijing 100037, China; c Physics Department, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China
Abstract  Very large magnetic entropy change $\Delta$SM, which originates from a fully reversible second-order transition at Curie temperature TC, has been discovered in compounds La(Fe, Si)13, La(Fe, Al)13 and those with Co doping. The maximum change $\Delta$SM $\approx$ 19 J·kg-1·K-1, achieved in LaFe11.4Si1.6 at 209K upon a 5T magnetic field change, exceedsthat of Gd by more than a factor of 2. The TC of the Co-doped compounds shifts to higher temperatures. $\Delta$SM still has a considerable large magnitude near room temperature. The phenomena of very large $\Delta$SM, convenience of adjustment of TC, and also thesuperiority of low cost, strongly suggest that the compounds La(Fe,M)13(M=Si, Al) with Co doping are suitable candidates for magnetic refrigerants at high temperatures.
Keywords:  NaZn13-type compounds      magnetic entropy change  
Received:  16 May 2000      Accepted manuscript online: 
PACS:  61.72.S- (Impurities in crystals)  
  65.40.G- (Other thermodynamical quantities)  
  75.30.Kz (Magnetic phase boundaries (including classical and quantum magnetic transitions, metamagnetism, etc.))  
  75.60.Ej (Magnetization curves, hysteresis, Barkhausen and related effects)  
Fund: Project supported by the State Key Project of Fundamental Research (Grant No. G1998061305) and by the National Natural Science Foundation of China (Grant No. 59525101).

Cite this article: 

Hu Feng-xia (胡凤霞), Shen Bao-gen (沈保根), Sun Ji-rong (孙继荣), Zhang Xi-xiang (张西祥) GREAT MAGNETIC ENTROPY CHANGE IN La(Fe, M)13 (M=Si, Al) WITH Co DOPING 2000 Chinese Physics 9 550

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