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Synthesis and electrochemical performance of La2CuO4 as a promising coating material for high voltage Li-rich layered oxide cathodes |
| Fuliang Guo(郭福亮)1,2, Jiaze Lu(卢嘉泽)1, Meihua Su(苏美华)3, Yue Chen(陈约)1, Jieyun Zheng(郑杰允)1, Liang Yin(尹良)1,4,†, and Hong Li(李泓)1,2,3,4,‡ |
1. Beijing Advanced Innovation Center for Materials Genome Engineering, Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2. School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China;
3. Tianmu Lake Institute of Advanced Energy Storage Technologies, Liyang 213300, China;
4. Yangtze River Delta Physics Research Center, Liyang 213300, China |
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Abstract The structural transformations, oxygen releasing and side reactions with electrolytes on the surface are considered as the main causes of the performance degradation of Li-rich layered oxides (LROs) cathodes in Li-ion batteries. Thus, stabilizing the surfaces of LROs is the key to realize their practical application in high energy density Li-ion batteries. Surface coating is regarded as one of the most effective strategies for high voltage cathodes. The ideal coating materials should prevent cathodes from electrolyte corrosion and possess both electronic and Li-ionic conductivities simultaneously. However, commonly reported coating materials are unable to balance these functions well. Herein, a new type of coating material, La2CuO4 was introduced to mitigate the surface issues of LROs for the first time, due to its superb electronic conductivity (26-35 mS·cm-1) and lithium-ionic diffusion coefficient (10-12-10-13 cm2·s-1). After coating with the La2CuO4, the capacity retention of Li1.2Ni0.54Co0.13Mn0.13O2 cathode was increased to 85.9% (compared to 79.3% of uncoated cathode) after 150 cycles in the voltage range of 2.0-4.8 V. In addition, only negligible degradations on the deliverable capacity and rate capability were observed.
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Received: 11 February 2023
Revised: 24 April 2023
Accepted manuscript online: 05 May 2023
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PACS:
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82.47.Aa
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(Lithium-ion batteries)
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82.45.Fk
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(Electrodes)
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| Fund: Project supported by the National Key Research and Development Program of China (Grant No.2019YFE0100200), the National Natural Science Foundation of China (Grant No.U1964205), and the Beijing Municipal Science and Technology Commission (Grant No.Z191100004719001). |
Corresponding Authors:
Liang Yin, Hong Li
E-mail: lyin@iphy.ac.cn;hli@iphy.ac.cn
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Cite this article:
Fuliang Guo(郭福亮), Jiaze Lu(卢嘉泽), Meihua Su(苏美华), Yue Chen(陈约), Jieyun Zheng(郑杰允), Liang Yin(尹良), and Hong Li(李泓) Synthesis and electrochemical performance of La2CuO4 as a promising coating material for high voltage Li-rich layered oxide cathodes 2023 Chin. Phys. B 32 088201
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[1] Lu Z, MacNeil D and Dahn J 2001 Electrochem. Solid-State Lett. 4 A191
[2] Thackeray M M, Johnson C S, Vaughey J T, Li N and Hackney S A 2005 J. Mater. Chem. 15 2257
[3] Schmuch R, Wagner R, Hörpel G, Placke T and Winter M 2018 Nat. Energy 3 267
[4] Zuo Y, Li B, Jiang N, Chu W, Zhang H, Zou R and Xia D 2018 Adv. Mater. 30 1707255
[5] Lu Z and Dahn J R 2002 J. Electrochem. Soc. 149 A815
[6] Croy J, Kang S-H, Balasubramanian M and Thackeray M 2011 Electrochem. Commun. 13 1063
[7] Croy J R, Gallagher K G, Balasubramanian M, Long B R and Thackeray M M 2014 J. Electrochem. Soc. 161 A318
[8] Yu X, Lyu Y, Gu L, Wu H, Bak S M, Zhou Y, Amine K, Ehrlich S N, Li H and Nam K W 2014 Adv. Energy Mater. 4 1300950
[9] Gent W E, Lim K, Liang Y, Li Q, Barnes T, Ahn S J, Stone K H, McIntire M, Hong J and Song J H 2017 Nat. Commun. 8 1
[10] Armstrong A R, Holzapfel M, Novák P, Johnson C S, Kang S H, Thackeray M M and Bruce P G 2006 J. Am. Chem. Soc. 128 8694
[11] Yin W, Grimaud A, Rousse G, Abakumov A M, Senyshyn A, Zhang L, Trabesinger S, Iadecola A, Foix D and Giaume D 2020 Nat. Commun. 11 1
[12] Gallagher K G, Croy J R, Balasubramanian M, Bettge M, Abraham D P, Burrell A K and Thackeray M M 2013 Electrochem. Commun. 33 96
[13] Xiao Z, Liu J, Fan G, Yu M, Liu J, Gou X, Yuan M and Cheng F 2020 Mater. Chem. Front. 4 1689
[14] Ji X, Xia Q, Xu Y, Feng H, Wang P and Tan Q 2021 J. Power Sources 487 229362
[15] Lan X, Xin Y, Wang L and Hu X 2018 J. Nanopart. Res. 20 1
[16] Grenier J, Wattiaux A, Lagueyte N, Park J, Marquestaut E, Etourneau J and Pouchard M 1991 Physica C 173 139
[17] Grenier J C, Pouchard M and Wattiaux A 1996 Curr. Opin. Solid. ST. M. 1 233
[18] Grant P, Parkin S, Lee V, Engler E, Ramirez M, Vazquez J, Lim G, Jacowitz R and Greene R 1987 Phys. Rev. Lett. 58 2482
[19] Labbe J and Bok J 1987 Europhys. Lett. 3 1225
[20] Cardoso D, Šljukić B, Sousa N, Sequeira C, Figueiredo F and Santos D 2018 Phys. Chem. Chem. Phys. 20 19045
[21] Grenier J, Wattiaux A, Doumerc J, Dordor P, Fournes L, Chaminade J and Pouchard M 1992 J. Solid State Chem. 96 20
[22] Sanchez R, Torresi R, Rettori C, Oseroff S and Fisk Z 1995 Electrochim. Acta 40 209
[23] Bhavaraju S, DiCarlo J, Yazdi I, Jacobson A, Feng H, Li Z and Hor P 1994 Mater. Res. Bull. 29 735
[24] Pouchard M, Demourgues A, Weill F, Villesuzanne A, Wattiaux A and Grenier J 1994 Adv. Mater. Res. 1 11
[25] Delville M H, Barbut D, Wattiaux A, Grenier J C and Etourneau J 2004 J. Electrochem.Soc.151 J69
[26] McKinnon W, Post M, Selwyn L, Pleizier G, Tarascon J, Barboux P, Greene L and Hull G 1988 Phys. Rev. B 38 6543
[27] Kong G, Jones M O, Abell J S, Edwards P P, Lees S T, Gibbons K E, Gameson I and Aindow M 2001 J. Mater. Res. 11 3309
[28] Zhang Z, Chen X, Zhang X, Lin H, Lin H, Zhou Y and Wang X 2013 Catal. Commun. 36 20
[29] Wang X T, Li B, Kong D R, Zhang Z Y, Zhang X F, Deng Z P, Huo L H and Gao S 2022 J. Alloys Compd. 911 165037
[30] Bruce P, Lisowska-Oleksiak A, Saidi M and Vincent C 1992 Solid State Ionics 57 353
[31] Ning F, Li S, Xu B and Ouyang C 2014 Solid State Ionics 263 46
[32] Li X, Su Z and Wang Y 2018 J. Alloys Compd. 735 2182
[33] Wang C, Appleby A J and Little F E 2001 J. Electroanal. Chem. 497 33
[34] Gordon I J, Grugeon S, Takenouti H, Tribollet B, Armand M, Davoisne C, Débart A and Laruelle S 2017 Electrochim. Acta 223 63
[35] Sun X, Zhang X, Liu W, Wang K, Li C, Li Z and Ma Y 2017 Electrochim. Acta 235 158
[36] Zhuang Q, Chen Z, Dong Q, Jiang Y, Huang L and Sun S 2006 Chin. Sci. Bull. 51 1055
[37] Shigang L, Jiaoyang W, Shu Z, Jian G, Shaofei W and Hong Li 2015 Energy Storage Sci. Technolo. 4 83 |
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