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TOPICAL REVIEW — Celebrating 30 Years of Chinese Physics B
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| TOPICAL REVIEW—Celebrating 30 Years of
Chinese Physics B |
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Anionic redox reaction mechanism in Na-ion batteries |
| Xueyan Hou(侯雪妍)1, Xiaohui Rong(容晓晖)1,†, Yaxiang Lu(陆雅翔)1, and Yong-Sheng Hu(胡勇胜)1,2,‡ |
1 Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2 Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100190, China |
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Abstract Na-ion batteries (NIBs), as one of the next-generation rechargeable battery systems, hold great potential in large-scale energy storage applications owing to the abundance and costeffectiveness of sodium resources. Despite the extensive exploration of electrode materials, the relatively low attainable capacity of NIBs hinders their practical application. In recent years, the anionic redox reaction (ARR) in NIBs has been emerging as a new paradigm to deliver extra capacity and thus offers an opportunity to break through the intrinsic energy density limit. In this review, the fundamental investigation of the ARR mechanism and the latest exploration of cathode materials are summarized, in order to highlight the significance of reversible anionic redox and suggest prospective developing directions.
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Received: 23 April 2022
Revised: 12 July 2022
Accepted manuscript online: 18 July 2022
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PACS:
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88.80.ff
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(Batteries)
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82.47.Aa
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(Lithium-ion batteries)
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71.20.-b
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(Electron density of states and band structure of crystalline solids)
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68.55.Nq
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(Composition and phase identification)
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| Fund: Project supported by the National Natural Science Foundation of China (Grant Nos. 51725206 and 52002394) and the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA21070500). |
Corresponding Authors:
Xiaohui Rong, Yong-Sheng Hu
E-mail: rong@iphy.ac.cn;yshu@iphy.ac.cn
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Cite this article:
Xueyan Hou(侯雪妍), Xiaohui Rong(容晓晖), Yaxiang Lu(陆雅翔), and Yong-Sheng Hu(胡勇胜) Anionic redox reaction mechanism in Na-ion batteries 2022 Chin. Phys. B 31 098801
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