Vibrational effects on electron momentum distributionsof outer valence orbitals of benzene

doi:10.1088/1674-1056/ab671b

Abstract The outer valence electron momentum distributions of benzene are reinvestigated with theoretical calculations involving the vibrational effects. The results are compared with recent experimental measurements [Phys. Rev. A 98 042705 (2018)]. The significant discrepancies between theories and experiments in previous works have now been interpreted quantitatively, indicating that the vibrational motion in benzene molecule has noticeable influence on its electron momentum distributions.

Keywords: electron momentum spectroscopy benzene outer valence orbitals vibrational effects

Received: 22 October 2019
Accepted manuscript online:

PACS:	34.80.Gs	(Molecular excitation and ionization)
	31.15.aj	(Relativistic corrections, spin-orbit effects, fine structure; hyperfine structure)

Fund: Project supported by the National Key Research and Development Program of China (Grant No. 2017YFA0402300).

Corresponding Authors: Yu Zhang
E-mail: joeyyu@mail.ustc.edu.cn

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Yu Zhang(张钰), Shanshan Niu(牛珊珊), Yaguo Tang(唐亚国), Yichun Wang(王忆纯), Xu Shan(单旭), Xiangjun Chen(陈向军) Vibrational effects on electron momentum distributionsof outer valence orbitals of benzene 2020 Chin. Phys. B 29 023402

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Vibrational effects on electron momentum distributionsof outer valence orbitals of benzene

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