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Chin. Phys. B, 2015, Vol. 24(5): 053102    DOI: 10.1088/1674-1056/24/5/053102
Special Issue: TOPICAL REVIEW — Precision measurement and cold matters
TOPICAL REVIEW—Precision measurement and cold matters Prev   Next  

High-precision spectroscopy of hydrogen molecular ions

Zhong Zhen-Xiang (钟振祥)a, Tong Xin (童昕)a, Yan Zong-Chao (严宗朝)a b c, Shi Ting-Yun (史庭云)a b
a State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, China;
b Center for Cold Atom Physics, Chinese Academy of Sciences, Wuhan 430071, China;
c Department of Physics, University of New Brunswick, Fredericton, New Brunswick, Canada E3B 5A3
Abstract  In this paper, we overview recent advances in high-precision structure calculations of the hydrogen molecular ions (H2+ and HD+), including nonrelativistic energy eigenvalues and relativistic and quantum electrodynamic corrections. In combination with high-precision measurements, it is feasible to precisely determine a molecular-based value of the proton-to-electron mass ratio. An experimental scheme is presented for measuring the rovibrational transition frequency (v,L):(0,0)→(6,1) in HD+, which is currently underway at the Wuhan Institute of Physics and Mathematics.
Keywords:  hydrogen molecular ion      rovibrational transition      proton-to-electron mass ratio      relativistic and QED corrections  
Received:  16 November 2014      Revised:  04 December 2014      Accepted manuscript online: 
PACS:  31.15.ac (High-precision calculations for few-electron (or few-body) atomic systems)  
  31.30.J- (Relativistic and quantum electrodynamic (QED) effects in atoms, molecules, and ions)  
  33.20.-t (Molecular spectra)  
  33.80.-b (Photon interactions with molecules)  
Corresponding Authors:  Yan Zong-Chao, Shi Ting-Yun     E-mail:  zyan@unb.ca;tyshi@wipm.ac.cn
About author:  31.15.ac; 31.30.J-; 33.20.-t; 33.80.-b

Cite this article: 

Zhong Zhen-Xiang (钟振祥), Tong Xin (童昕), Yan Zong-Chao (严宗朝), Shi Ting-Yun (史庭云) High-precision spectroscopy of hydrogen molecular ions 2015 Chin. Phys. B 24 053102

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