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Chinese Physics, 2006, Vol. 15(6): 1310-1314    DOI: 10.1088/1009-1963/15/6/029
CONDENSED MATTER: STRUCTURAL, MECHANICAL, AND THERMAL PROPERTIES Prev   Next  

Nickel-disilicide-assisted excimer laser crystallization of amorphous silicon

Liao Yan-Ping (廖燕平)ab, Shao Xi-Bin (邵喜斌)ac, Gao Feng-Li (郜峰利)d, Luo Wen-Sheng (骆文生)a, Wu Yuan (吴渊)a, Fu Guo-Zhu (付国柱)a, Jing Hai (荆海)ac, Ma Kai (马凯)a
a Chang Chun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, North Liquid Crystal Engineering Research and Development Center, Changchun 130031, China; b Graduate School of Chinese Academy of Sciences, Beijing 100049, China; c Jilin North Cai Jing Digital Electron Limited Corporation, Changchun 130031, China; d College of Electronic Science and Engineering, Jilin University, Changchun 130023, China
Abstract  Polycrystalline silicon (poly-Si) thin film has been prepared by means of nickel-disilicide (NiSi$_{2})$ assisted excimer laser crystallization (ELC). The process to prepare a sample includes two steps. One step consists of the formation of NiSi$_{2}$ precipitates by heat-treating the dehydrogenated amorphous silicon (a-Si) coated with a thin layer of Ni. And the other step consists of the formation of poly-Si grains by means of ELC. According to the test results of scanning electron microscopy (SEM), another grain growth model named two-interface grain growth has been proposed to contrast with the conventional Ni-metal-induced lateral crystallization (Ni-MILC) model and the ELC model. That is, an additional grain growth interface other than that in conventional ELC is formed, which consists of NiSi$_{2}$ precipitates and a-Si. The processes for grain growth according to various excimer laser energy densities delivered to the a-Si film have been discussed. It is discovered that grains with needle shape and most of a uniform orientation are formed which grow up with NiSi$_{2}$ precipitates as seeds. The reason for the formation of such grains which are different from that of Ni-MILC without migration of Ni atoms is not clear. Our model and analysis point out a method to prepare grains with needle shape and mostly of a uniform orientation. If such grains are utilized to make thin-film transistor, its characteristics may be improved.
Keywords:  polycrystalline silicon      excimer laser crystallization      Ni-disilicide      Ni-metal-induced lateral crystallization      two-interface grain growth  
Received:  07 September 2005      Revised:  06 March 2006      Accepted manuscript online: 
PACS:  68.55.A- (Nucleation and growth)  
  68.37.Hk (Scanning electron microscopy (SEM) (including EBIC))  
  68.55.-a (Thin film structure and morphology)  
  78.30.Am (Elemental semiconductors and insulators)  
  81.15.-z (Methods of deposition of films and coatings; film growth and epitaxy)  
Fund: Project supported by the National High Technology Development Program of China (Grant No 2002AA303250) and by the National Natural Science Foundation of China (Grant No 60576056).

Cite this article: 

Liao Yan-Ping (廖燕平), Shao Xi-Bin (邵喜斌), Gao Feng-Li (郜峰利), Luo Wen-Sheng (骆文生), Wu Yuan (吴渊), Fu Guo-Zhu (付国柱), Jing Hai (荆海), Ma Kai (马凯) Nickel-disilicide-assisted excimer laser crystallization of amorphous silicon 2006 Chinese Physics 15 1310

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