INFLUENCE OF HIGH PRESSURE ON EMISSION SPECTRA AND CRYSTAL FIELD STRENGTH FOR Eu3+ IN GdOBr

doi:10.1088/1004-423X/6/6/005

Abstract

Abstract The emission spectra of the Eu³⁺ion in GdOBr∶Eu³⁺ were measured in the range of pressure from 0 GPa to 12.4 GPa. The energy level schemes establis hed from the spectra show that the splittings of the ⁷F₁,⁷F₃ and ⁵D₁ multiplets decrease obviously with increasing pressure. The crystal-field parameters B^k_q and the crystal-field strength parameter S versus B^k_q were determined at different pressures. With pressurization S reduces and the J-mixings of the state functions for the Eu³⁺ ion decrease, which is in agreement with the decrease of the multiplet splittings. This shows that for Eu³⁺ in REOX∶Eu³⁺ the diminution of the crystal-field strength with pressure, the authenticity of which is under suspicion for several years, is certain.

Received: 27 August 1996
Revised: 19 November 1996
Accepted manuscript online:

PACS:	71.70.Ch	(Crystal and ligand fields)
	78.55.Hx	(Other solid inorganic materials)
	62.50.-p	(High-pressure effects in solids and liquids)

Fund: Project supported by the National Natural Science Foundation of China.

Cite this article:

CHI YUAN-BIN (池元斌), LIU SHEN-XIN (刘慎薪), LI HONG-NIAN (李宏年), ZHAO XU-YI (赵绪义), WANG LI-ZHONG (王立中) INFLUENCE OF HIGH PRESSURE ON EMISSION SPECTRA AND CRYSTAL FIELD STRENGTH FOR Eu³⁺ IN GdOBr 1997 Acta Physica Sinica (Overseas Edition) 6 429

[1]	Effect of O-O bonds on p-type conductivity in Ag-doped ZnO twin grain boundaries Jingjing Wu(吴静静), Xin Tang(唐鑫), Fei Long(龙飞), Biyu Tang(唐壁玉). Chin. Phys. B, 2018, 27(5): 057701.
[2]	Zero-field splitting parameters and local structures for tetragonal Cr²⁺ centers in Cr²⁺-doped ZnSe semiconductors Lu Ting-Ting (卢婷婷), Kuang Xiao-Yu (邝小渝), Li Hui (李辉), Li Hong-Hong (李洪洪), Wu Zhi-Yan (武志燕), Mao Ai-Jie (毛爱杰). Chin. Phys. B, 2014, 23(11): 117104.
[3]	Calculating Hamiltonian parameters for Yb³⁺ in a low-symmetry lattice site, and fitting the structure and levels of Yb³⁺:RETaO₄ (RE=Gd, Y, and Sc) Zhang Qing-Li (张庆礼), Ning Kai-Jie (宁凯杰), Ding Li-Hua (丁丽华), Liu Wen-Peng (刘文鹏), Sun Dun-Lu (孙敦陆), Jiang Hai-He (江海河), Yin Shao-Tang (殷绍唐). Chin. Phys. B, 2013, 22(6): 067105.
[4]	Structural analysis and crystal-field calculations of Nd³⁺ in Gd_xLu_1-xTaO₄ (x=0.85) polycrytalline Gao Jin-Yun (高进云), Zhang Qing-Li (张庆礼), Yang Hua-Jun (杨华军), Zhou Peng-Yu (周鹏宇), Sun Dun-Lu (孙敦陆), Yin Shao-Tang (殷绍唐), He Ye (何晔). Chin. Phys. B, 2012, 21(10): 106103.
[5]	Local structure distortion and spin Hamiltonian parameters for Cr³⁺–V_Zn tetragonal defect centre in Cr³⁺ doped KZnF₃ crystal Yang Zi-Yuan(杨子元) . Chin. Phys. B, 2011, 20(9): 097601.
[6]	Influence of Si⁴⁺ substitution on the temperature-dependent characteristics of Y₃Al₅O₁₂:Ce Xu Sheng-Yan(徐生艳), Zhang Xiao-Song(张晓松), Zhou Yong-Liang(周永亮), Xi Qun(奚群), and Li Lan(李岚). Chin. Phys. B, 2011, 20(3): 037804.
[7]	Structures and luminescence properties of Yb³⁺ in the double perovskites Ba₂YB'O₆ (B'=Ta⁵⁺, Nb⁵⁺) phosphors Zhou Wen-Long(周文龙), Zhang Qing-Li(张庆礼), Gao Jin-Yun(高进云), Liu Wen-Peng(刘文鹏), Ding Li-Hua(丁丽华), and Yin Shao-Tang(殷绍唐). Chin. Phys. B, 2011, 20(1): 016101.
[8]	Luminescence of Ce³⁺ in lanthanum silicon oxynitride Hu Long(胡龙),Xu Xue-Wen(徐学文),Lu Zun-Ming(卢遵铭),Fan Ying(范英), Li Yang-Xian(李养贤), and Tang Cheng-Chun(唐成春). Chin. Phys. B, 2010, 19(12): 127807.
[9]	Method for fitting crystal field parameters and the energy level fitting for Yb³⁺ in crystal Sc₂O₃ Zhang Qing-Li(张庆礼),Ning Kai-Jie(宁凯杰), Xiao Jin(肖进), Ding Li-Hua(丁丽华),Zhou Wen-Long(周文龙),Liu Wen-Peng(刘文鹏),Yin Shao-Tang(殷绍唐), and Jiang Hai-He(江海河). Chin. Phys. B, 2010, 19(8): 087501.
[10]	Theoretical investigations of the local distortion and electron paramagnetic resonance parameter for CdCl₂:V²⁺ and CsMgX₃:V²⁺ (X=Cl, Br) systems Li Cheng-Gang(李成刚), Kuang Xiao-Yu(邝小渝), Duan Mei-Ling(段美玲), Zhang Cai-Xia(张彩霞), and Chai Rui-Peng(柴瑞鹏). Chin. Phys. B, 2010, 19(6): 067103.
[11]	Structure and luminescence of Ca₂Si₅N₈:Eu²⁺ phosphor for warm white light-emitting diodes Wei Xiao-Dan(魏小丹), Cai Li-Yan(蔡丽艳), Lu Fa-Chun(鲁法春), Chen Xiao-Long(陈小龙), Chen Xue-Yuan(陈学元), and Liu Quan-Lin(刘泉林). Chin. Phys. B, 2009, 18(8): 3555-3562.
[12]	Effect of local structure on electron paramagnetic resonance spectra for trigonal [Cr(H₂O)₆]³⁺coordination complex in the sulfate alums series: a ligand field theory study Li Yan-Fang(李艳芳), Kuang Xiao-Yu(邝小渝), Gao Ming-Liang(高明亮), Zhao Ya-Ru(赵亚儒), and Wang Huai-Qian(王怀谦). Chin. Phys. B, 2009, 18(7): 2967-2974.
[13]	X-ray absorption near the edge structure and x-ray photoelectron spectroscopy studies on pyrite prepared by thermally sulfurizing iron films Zhang Hui(张辉), Liu Ying-Shu(刘应书), Wang Bao-Yi(王宝义), Wei Long(魏龙), Kui Re-Xi(奎热西), and Qian Hai-Jie(钱海杰). Chin. Phys. B, 2009, 18(7): 2734-2738.
[14]	4f^N-15d energy levels of lanthanides: a quasi-angular-momentum approach and its application to Cs₂NaYF₆:Er³⁺ Ma Chong-Geng(马崇庚), Jiang Sha(江莎), Duan Chang-Kui(段昌奎), Yin Min(尹民), and Xia Shang-Da(夏上达). Chin. Phys. B, 2009, 18(5): 1961-1967.
[15]	New expressions for g-factors of the mixed ground state of 3d⁹ ions with a compressional tetragonal symmetry and its application to NaCl:Ni⁺(I) Li Fu-Zhen (李福珍), Li Zhao-Min (李兆民). Chin. Phys. B, 2002, 11(9): 940-943.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Metrics
Related Articles

INFLUENCE OF HIGH PRESSURE ON EMISSION SPECTRA AND CRYSTAL FIELD STRENGTH FOR Eu3+ IN GdOBr

Cite this article:

Online attention

INFLUENCE OF HIGH PRESSURE ON EMISSION SPECTRA AND CRYSTAL FIELD STRENGTH FOR Eu³⁺ IN GdOBr