One-step synthesis of cubic gauche polymeric nitrogen with high yield just by heating

doi:10.1088/1674-1056/ad9569

Abstract A high-efficient one-step synthesis of cubic gauche polymeric nitrogen was developed just by thermal treatment of KN$_3$ powders. Raman and infrared spectra confirm the formation of cubic gauche polymeric nitrogen. Further thermogravimetric differential scanning calorimeter measurements show that the content of cubic gauche polymeric nitrogen is as high as 1.5 wt% with high thermal stability, which is the highest content value reported so far.

Keywords: cg-N thermal treatment polymeric nitrogen high-energy-density materials KN$_{3}$

Received: 17 November 2024
Revised: 20 November 2024
Accepted manuscript online: 21 November 2024

PACS:

68.35.bt

(Other materials)

Fund: Project supported by the CASHIPS Director’s Fund (Grant Nos. YZJJ202207-CX, YZJJ202308-TS, and YZJJGGZX-2022-01).

Corresponding Authors: Ming Li, Xianlong Wang
E-mail: liming@issp.ac.cn;xlwang@theory.issp.ac.cn

Cite this article:

Liangfei Wu(吴良飞), Yuxuan Xu(徐宇轩), Guo Chen(陈果), Junfeng Ding(丁俊峰), Ming Li(李明), Zhi Zeng(曾雉), and Xianlong Wang(王贤龙) One-step synthesis of cubic gauche polymeric nitrogen with high yield just by heating 2024 Chin. Phys. B 33 126802

[1] Mailhiot C, Yang L H and McMahan A K 1992 Phys. Rev. B 46 14419
[2] Yakub L N 2016 Low Temp. Phys. 42 1
[3] Zhang G, Liu X, Xue Y and Huang J 2014 Chin. J. Energ. Mater. 22 422
[4] Zarko V E 2010 Combust. Explos. Shock Waves 46 121
[5] Eremets M I, Gavriliuk A G, Trojan I A, Dzivenko D A and Boehler R 2004 Nat. Mater. 3 558
[6] Tomasino D, Kim M, Smith J and Yoo C S 2014 Phys. Rev. Lett. 113 205502
[7] Laniel D, Geneste G, Weck G, Mezouar M and Loubeyre P 2019 Phys. Rev. Lett. 122 066001
[8] Liu Y, Su H, Niu C,Wang X, Zhang J, Ge Z and Li Y 2020 Chin. Phys. B 29 106201
[9] Laniel D, Winkler B, Fedotenko T, Pakhomova A, Chariton S, Milman V, Prakapenka V, Dubrovinsky L and Dubrovinskaia N 2020 Phys. Rev. Lett. 124 216001
[10] Ji C, Adebayo A, Yang L X, et al. 2020 Sci. Adv. 6 eaba9206
[11] Benchafia E M, Yao Z, Yuan G, Chou T, Piao H, Wang X and Iqbal Z 2017 Nat. Commun. 8 930
[12] Benchafia E M, Yu C, Sosnowski M, Ravindra N M and Iqbal Z 2014 JOM 66 608
[13] Alzaim S, Wu Z, Benchafia E M, Young J and Wang X 2021 Phys. Chem. Chem. Phys. 23 15713
[14] Zhuang H, Alzaim S, Li S, Benchafia E M, Young J, Ravindra N M, Iqbal Z and Wang X 2022 Chem. Mater. 34 4712
[15] Zhuang H, Huo S, Alzaim S, Iqbal Z, Ravindra N M andWang X 2023 Catal. Today 409 149
[16] Xu Y, Chen G, Du F, et al. 2024 Sci. Adv. 10 eadq5299
[17] Chen G, Niu C, XiaW, Zhang J, Zeng Z andWang X 2023 Chin. Phys. Lett. 40 086102
[18] Caracas R 2007 J. Chem. Phys. 127 144510
[19] Chen R T, Zhang J, Wang Z L, et al. 2024 Sci. Bull.

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One-step synthesis of cubic gauche polymeric nitrogen with high yield just by heating

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